Registration Dossier

Administrative data

First-aid measures

Description of first aid measures
General information:
In case of accident or if you feel unwell seek medical advice (show label or SDS where possible).
After contact with the eyes:
Rinse immediately with plenty of water. Seek medical advice in case of continuous irritation.
After contact with the skin:
Wash with plenty of water or water and soap. In the event of a visible skin change or other complaints, seek medical advice (show
label or SDS where possible).
After inhalation:
Provide fresh air.
After swallowing:
Give several small portions of water to drink. Do not induce vomiting.

Most important symptoms and effects, both acute and delayed
Any relevant information can be found in other parts of this section.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media:
water mist , extinguishing powder , alcohol-resistant foam , carbon dioxide , sand .
Extinguishing media which must not be used for safety reasons:
water jet .

Special hazards arising from the substance or mixture
Risk of hazardous gasses or fumes in the event of fire. Exposure to combustion products may be a health hazard! Hazardous
combustion products: carbon oxides , silicon oxides , incompletely burnt hydrocarbons , toxic and very toxic fumes .

Advice for firefighters
Special protective equipment for fire fighting:
Use respiratory protection independent of recirculated air. Keep unprotected persons away.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Secure the area. Wear personal protection equipment (see section Exposure controls/personal protection). Keep unprotected persons away. Avoid contact with eyes
and skin. Do not inhale gases/vapours/aerosols. If material is released indicate risk of slipping. Do not walk through spilled
material.

Environmental precautions
Prevent material from entering surface waters, drains or sewers and soil. Close leak if possible without risk. Contain any fluid that
runs out using suitable material (e.g. earth). Retain contaminated water/extinguishing water. Dispose of in prescribed marked
containers. Inform authorities if substance leaks into surface waters, sewerage or ground.

Methods and material for containment and cleaning up
Take up mechanically and dispose of according to local/state/federal regulations. Do not flush away with water. For small
amounts: Absorb with a neutral (non-acidic / non-basic) liquid binding material such as diatomaceous earth and dispose of
according to government regulations. For large amounts: Liquids may be recovered using suction devices or pumps. If flammable,
only air driven or properly rated electrical equipment should be used. Clean any slippery coating that remains using a detergent /
soap solution or another biodegradable cleaner. Silicone fluids are slippery; spills are a safety hazard. Apply sand or other inert
granular material to improve traction.

Further information:
Exhaust vapours. Eliminate all sources of ignition. Consider explosion protection. Observe notes under section Handling and storage.

Reference to other sections
Relevant information in other sections has to be considered. This applies in particular for information given on personal protective
equipment and on disposal.

Handling and storage

Precautions for safe handling
General information:
Avoid exposure by technical measures or personal protective equipment.
Precautions for safe handling:
Ensure adequate ventilation. Must be syphoned off in situ. Spilled substance increases risk of slipping. Avoid formation of
aerosols. In case of aerosol formation special protective measures are required (exhausting by suction, respiratory protection).
Observe information in section Exposure controls/personal protection. Keep away from incompatible substances in accordance with section Stability and reactivity.
Precautions against fire and explosion:
Product can separate methanol. Flammable vapors may accumulate and form explosive mixtures with air in containers, process
vessels, including partial, empty and uncleaned containers and vessels, or other enclosed spaces. Keep away from sources of
ignition and do not smoke. Take precautionary measures against electrostatic charging. Cool endangered containers with water.

Conditions for safe storage, including any incompatibilities
Conditions for storage rooms and vessels:
Protect against light. Observe local/state/federal regulations.
Advice for storage of incompatible materials:
Observe local/state/federal regulations.
Further information for storage:
Store in a dry and cool place. Protect against moisture. Store container in a well ventilated place. Store in the dark. The effect of
direct sunlight or UV radiation must be completely ruled out, even during transit. In the product and in the gas space of the
container, a small quantity of oxygen must be present for stabilisation.

Transport information

Land transport (ADR/RID)

UN number:
Not regulated for transport
Shippingopen allclose all
Remarks:
Not regulated for transport

Inland waterway transport (ADN(R))

UN number:
Not regulated for transport
Shippingopen allclose all
Remarks
Not regulated for transport

Marine transport (IMDG)

UN number:
Not regulated for transport
Remarks
Not regulated for transport

Air transport ICAO/IATA

UN number:
Not regulated for transport
Remarks
Not regulated for transport
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Exposure controls
Exposure in the work place limited and controlled
General protection and hygiene measures:
Avoid contact with eyes and skin. Do not inhale gases/vapours/aerosols. Do not eat, drink or smoke when handling.
Personal protection equipment:

Respiratory protection:
If inhalative exposure above the occupational exposure limit cannot be excluded, adequate respiratory protection equipment must
be used. Suitable respiratory equipment: Respirator with a full face mask, according to acknowledged standards such as EN 136.
Recommended Filter type: Gas filter type ABEK (certain inorganic, organic and acidic gases and vapors; ammonia/amines),
according to acknowledged standards such as EN 14387
In case of mist, spray or aerosol exposure wear suitable personal respiratory protection and protective suit. Suitable respiratory
equipment: Respirator with a full face mask, according to acknowledged standards such as EN 136.
Recommended Filter type: Combined filter type ABEK-P2 (certain inorganic, organic and acidic gases and vapors;
ammonia/amines; particles), according to acknowledged standards such as EN 14387
Observe the equipment manufacturer's information and wear time limits for respirators.

Eye protection:
tight fitting protective goggles .

Hand protection:
Gloves are required at all times when handling the material.
Recommended glove types: Protective gloves made of butyl rubber
thickness of the material: > 0,3 mm
Breakthrough time: > 480 min
Recommended glove types: Protective gloves made of nitrile rubber
thickness of the material: > 0,4 mm
Breakthrough time: 10 - 30 min
Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves.
Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion,
and the contact time. Note that, due to the numerous external influences (such as temperature), a chemically resistant protective
glove in daily use may have a service life that is considerably shorter than the measured break through time.

Skin protection:
In open handling: Chemical protective clothing, full-body liquid-tight protection if necessary. Please observe the instructions
regarding permeability time which are provided by the supplier.

Exposure to the environment limited and controlled
Prevent material from entering surface waters, drains or sewers and soil.

Further information for system design and engineering measures
Observe information in section Handling and Storage.

Stability and reactivity

If stored and handled in accordance with standard industrial practices no hazardous reactions are known.
Relevant information can possibly be found in other parts of this section.

Conditions to avoid
moisture . Possibility of spontaneous polymerization of unstabilized product by ambient temperature.

Incompatible materials
Radical initiators (peroxid, light, heat, heavy metal compounds) may cause polymerization. Reacts with: water , basic substances
or acids . Reaction causes the formation of: methanol .

Hazardous decomposition products
Under the effect of humidity, water and protic agents: methanol .

Further information:
Product contains polymerization inhibitor.

Disposal considerations

Waste treatment methods

Material
Recommendation:
Material that cannot be used, reprocessed or recycled should be disposed of in accordance with Federal, State, and local
regulations at an approved facility. Depending on the regulations, waste treatment methods may include, e.g., landfill or
incineration.

Uncleaned packaging
Recommendation:
Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used.
Observe local/state/federal regulations. Uncleaned packaging should be treated with the same precautions as the material.

Waste Disposal Legislation Ref.No.(EC)
It is not possible to determine a waste code for this product in accordance with the European Waste Catalogue (EWC) since it is
only possible to classify it according to how it is used by the customer. The waste code is to be determined within the EU in liaison
with the waste-disposal operator.