Registration Dossier

Administrative data

First-aid measures

Eye contact : Get medical attention immediately. Call a poison center or physician. Immediatelyflush eyes with plenty of water, occasionally lifting the upper and lower eyelids.Check for and remove any contact lenses. Continue to rinse for at least 10 minutes.Chemical burns must be treated promptly by a physicianInhalation : Get medical attention immediately. Call a poison center or physician. Removevictim to fresh air and keep at rest in a position comfortable for breathing. If it issuspected that fumes are still present, the rescuer should wear an appropriate maskor self-contained breathing apparatus. If not breathing, if breathing is irregular or ifrespiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.It may be dangerous to the person providing aid to give mouth-to-mouthresuscitation. If unconscious, place in recovery position and get medical attentionimmediately. Maintain an open airway. Loosen tight clothing such as a collar, tie,belt or waistband. In case of inhalation of decomposition products in a fire,symptoms may be delayed. The exposed person may need to be kept undermedical surveillance for 48 hoursskin contact : Get medical attention immediately. Call a poison center or physician. Flushcontaminated skin with plenty of water. Remove contaminated clothing and shoes.Wash contaminated clothing thoroughly with water before removing it, or weargloves. Continue to rinse for at least 10 minutes. Chemical burns must be treatedpromptly by a physician. Wash clothing before reuse. Clean shoes thoroughlybefore reuse.ingestion : Get medical attention immediately. Call a poison center or physician. Wash outmouth with water. Remove dentures if any. Remove victim to fresh air and keep atrest in a position comfortable for breathing. If material has been swallowed and theexposed person is conscious, give small quantities of water to drink. Stop if theexposed person feels sick as vomiting may be dangerous. Do not induce vomitingunless directed to do so by medical personnel. If vomiting occurs, the head shouldbe kept low so that vomit does not enter the lungs. Chemical burns must be treatedpromptly by a physician. Never give anything by mouth to an unconscious person.If unconscious, place in recovery position and get medical attention immediately.Maintain an open airway. Loosen tight clothing such as a collar, tie, belt orwaistband.protection of 1st aiders : No action shall be taken involving any personal risk or without suitable training. If itis suspected that fumes are still present, the rescuer should wear an appropriatemask or self-contained breathing apparatus. It may be dangerous to the personproviding aid to give mouth-to-mouth resuscitation. Wash contaminated clothingthoroughly with water before removing it, or wear gloves.Eye contact : Causes serious eye damage.inhalation : May give off gas, vapor or dust that is very irritating or corrosive to the respiratorysystem. Exposure to decomposition products may cause a health hazard. Seriouseffects may be delayed following exposure.Skin contact : Causes severe burns.ingestion : May cause burns to mouth, throat and stomach.Over-exposure signs/symptoms : eye contact : Adverse symptoms may include the following: pain watering rednessInhalation No specific data.Skin contact : Adverse symptoms may include the following:pain or irritationrednessblistering may occuringestion : Adverse symptoms may include the following:stomach painsIndication of any immediate medical attention and special treatment neededNote to physisian : In case of inhalation of decomposition products in a fire, symptoms may be delayed.The exposed person may need to be kept under medical surveillance for 48 hours.Specific treatments : Symptomatic treatment and supportive therapy as indicated. Following severeexposure the patient should be kept under medical review for at least 48 hours.

Fire-fighting measures

Suitable extinguishing media : Use an extinguishing agent suitable for the surrounding fire.Unsuitable extinguishing media : None known.Special hazards arising from the substance or mixture : Hazards from the substance or mixture : In a fire or if heated, a pressure increase will occur and the container may burst.Hazardous thermal decomposition products : Decomposition products may include the following materials:carbon dioxidecarbon monoxidenitrogen oxidesAdvice for firefightersSpecial precautions for fire-fighters : Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or withoutsuitable training.Special protective equipment for fire-fighters : Fire-fighters should wear appropriate protective equipment and self-containedbreathing apparatus (SCBA) with a full face-piece operated in positive pressuremode. Clothing for fire-fighters (including helmets, protective boots and gloves)conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

Accidental release measures

Personal precautions, protective equipment and emergency proceduresFor non-emergency personnel : No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilt material. Do not breathe vapour or mist.Provide adequate ventilation. Wear appropriate respirator when ventilation isinadequate. Put on appropriate personal protective equipment.For emergency responders : If specialised clothing is required to deal with the spillage, take note of anyinformation in Section 8 on suitable and unsuitable materials. See also theinformation in "For non-emergency personnel".Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air).Methods and material for containment and cleaning up : Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mopup if water-soluble. Alternatively, or if water-insoluble, absorb with an inert drymaterial and place in an appropriate waste disposal container. Dispose of via alicensed waste disposal contractor.Large spill : Stop leak if without risk. Move containers from spill area. Approach the releasefrom upwind. Prevent entry into sewers, water courses, basements or confinedareas. Wash spillages into an effluent treatment plant or proceed as follows.Contain and collect spillage with non-combustible, absorbent material e.g. sand,earth, vermiculite or diatomaceous earth and place in container for disposalaccording to local regulations. Dispose of via a licensed waste disposal contractor.Contaminated absorbent material may pose the same hazard as the spilt product.See Section 1 for emergency contact information.See Section 8 for information on appropriate personal protective equipment.See Section 13 for additional waste treatment information.

Handling and storage

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should beconsulted for any available use-specific information provided in the Exposure Scenario(s).7.1 Precautions for safe handlingProtective measures :Put on appropriate personal protective equipment (see Section 8). Do not get ineyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. If duringnormal use the material presents a respiratory hazard, use only with adequateventilation or wear appropriate respirator. Keep in the original container or anapproved alternative made from a compatible material, kept tightly closed when notin use. Empty containers retain product residue and can be hazardous. Do notreuse container.Advice on generaloccupational hygieneEating, drinking and smoking should be prohibited in areas where this material ishandled, stored and processed. Workers should wash hands and face beforeeating, drinking and smoking. Remove contaminated clothing and protectiveequipment before entering eating areas. See also Section 8 for additionalinformation on hygiene measures.7.2 Conditions for safestorage, including anyincompatibilities : Store in accordance with local regulations. Store in original container protectedfrom direct sunlight in a dry, cool and well-ventilated area, away from incompatiblematerials (see Section 10) and food and drink. Store locked up. Keep containertightly closed and sealed until ready for use. Containers that have been openedmust be carefully resealed and kept upright to prevent leakage. Do not store inunlabelled containers. Use appropriate containment to avoid environmentalcontamination.Storage class 8, Corrosive substances7.3 Specific end use(s) Recommendations : not available Industrial sector specific solutions : not available

Transport information

Land transport (ADR/RID)

UN number:
UN3055
Shippingopen allclose all
Class:
8
Classification code:
Hazard identification number 80Tunnel code E
Packaging group:
III
Labels:
8
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN3055
Shippingopen allclose all
Class:
8
Packaging group:
III
Labels:
8
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN3055
Class:
8
Packaging group:
III
EmS code:
Emergency schedules (EmS)F-A S-B
Labels:
8
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN 3055
Class:
Passenger and Cargo Aircraft Quantity limitation: 5 L Packaging instructions: 852 Cargo Aircraft OnlyQuantity limitation: 60 LPackaging instructions: 856
Packaging group:
Packaginginstructions: 856
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Stability and reactivity

Disposal considerations