Registration Dossier

Administrative data

First-aid measures

General information
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). Remove contaminated, saturated clothing immediately. Wash thoroughly the body (shower or bath). Remove affected person from the danger area and lay down. Transport affected person in flat position. Put victim at rest, cover with a blanket and keep warm. Do not leave affected person unattended.

Following inhalation: Remove casualty to fresh air and keep warm and at rest. If breathing is irregular or stopped, administer artificial respiration. Call a physician immediately.

In case of skin contact: After contact with skin, wash immediately with plenty of water and soap. In case of skin reactions, consult a physician. Immediate medical treatment required because corrosive injuries that are not treated are hard to cure. In case of skin irritation, consult a physician.

After eye contact: In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist. Remove contact lenses, if present and easy to do. Continue rinsing. Protect uninjured eye.

After ingestion: If accidentally swallowed rinse the mouth with plenty of water (only if the person is conscious) and obtain immediate medical attention. Do NOT induce vomiting. Self-protection of the first aider First aider: Pay attention to self-protection!

Most important symptoms and effects, both acute and delayed :

Following inhalation Irritation to respiratory tract Pulmonary irritation Following skin contact Causes severe burns. erythema (redness) May cause an allergic skin reaction. After eye contact Causes serious eye damage. After ingestion Causes severe burns. Gastrointestinal complaints Abdominal pain If swallowed danger of perforation of the esophagus and the stomach (strong corrosive effects).

Indication of any immediate medical attention and special treatment needed:
Treat symptomatically. First Aid, decontamination, treatment of symptoms. Subsequent observance for pneumonia and lung oedema.

Fire-fighting measures

Extinguishing media

Suitable extinguishing media: Carbon dioxide (CO2) Extinguishing powder alcohol resistant foam Water spray Water
Unsuitable extinguishing media Strong water jet

Special hazards arising from the substance or mixture: In case of fire may be liberated: Nitrogen oxides (NOx) Carbon monoxide. Carbon dioxide (CO2) Ammonia (NH3)

Advice for firefighters

Special protective equipment for firefighters
Wear a self-contained breathing apparatus and chemical protective clothing. Move undamaged containers from immediate hazard area if it can be done safely. Use water spray jet to protect personnel and to cool endangered containers. Do not allow run-off from fire-fighting to enter drains or water courses. Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.

Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

For non-emergency personnel: Use personal protection equipment.
For emergency responders Use personal protection equipment. Provide adequate ventilation. Remove persons to safety.

Environmental precautions Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil.

Methods and material for containment and cleaning up:
For containment: Cover drains. Stop leak if safe to do so. Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Take up mechanically, placing in appropriate containers for disposal.

For cleaning up: Collect in closed and suitable containers for disposal. Clean contaminated objects and areas thoroughly observing environmental regulations.

Handling and storage

Protective measures:

It is recommended to design all work processes always so that the following is excluded: Inhalation of vapours or spray/mists Skin contact Eye contact Wear personal protection equipment.
If local exhaust ventilation is not possible or not sufficient, the entire working area should be ventilated by technical means.

Measures to prevent fire: Keep away from sources of ignition. - No smoking. Keep away from sources of heat (e.g. hot surfaces), sparks and open flames.

Environmental precautions: Shafts and sewers must be protected from entry of the product. Provide for retaining containers, eg. floor pan without outflow.

Advices on general occupational hygiene: Working places should be designed to allow cleaning at any time. Floors, walls and other surfaces in the hazard area must be cleaned regularly. After use replace the closing cap immediately. Wash hands and face before breaks and after work and take a shower if necessary. Wash hands before eating, drinking or smoking. Remove contaminated, saturated clothing immediately. Wash contaminated clothing prior to re-use.

Conditions for safe storage, including any incompatibilities:

Technical measures and storage conditions: Only use containers specifically approved for the substance/product. Protect containers against damage. Keep container tightly closed and in a well-ventilated place.

Packaging materials: Unsuitable container/equipment material: Copper Alloy, containing copper

Hints on joint storage: Storage class : 8A Storage class (TRGS 510) : 8A

Keep away from: Acid Oxidising agent Keep away from food, drink and animal feedingstuffs.

Transport information

Land transport (ADR/RID)

UN number:
UN 3267
Proper shipping name and description:
CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. ( 2-PROPENENITRILE, REACTION PRODUCTS WITH 1,3BENZENEDIMETHANAMINE )
Chemical name:
2-PROPENENITRILE, REACTION PRODUCTS WITH 1,3BENZENEDIMETHANAMINE
Language:
English
Class:
8
Classification code:
C7
Packaging group:
na
Labels:
8
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Inland waterway transport (ADN(R))

UN number:
UN 3267
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Marine transport (IMDG)

UN number:
UN 3267
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Air transport ICAO/IATA

UN number:
UN 3267
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Exposure controls / personal protection

Appropriate engineering controls Provide for sufficient ventilation. If technical exhaust or ventilation measures are not possible or insufficient, respiratory protection must be worn. Technical measures and the application of suitable work processes have priority over personal protection equipment.

Personal protection equipment

Eye/face protection:
Suitable eye protection Eye glasses with side protection DIN-/EN-Norms : DIN EN 166 Provide eye shower and label its location conspicuously Skin protection:
Hand protection Suitable gloves type : Gloves with long cuffs Suitable material : PVC (Polyvinyl chloride) CR (polychloroprene, chloroprene rubber) Butyl caoutchouc (butyl rubber) PVA (Polyvinyl alcohol) FKM (fluoro rubber) Wearing time with occasional contact (splashes) : > 60 min Wearing time with permanent contact : > 480 min

Remark : When handling with chemical substances, protective gloves must be worn with the CE-label including the four control digits. Breakthrough times and swelling properties of the material must be taken into consideration. Tested protective gloves must be worn The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. DIN-/EN-Norms : DIN EN 374 Body protection Suitable protective clothing

Stability and reactivity

The product is stable under storage at normal ambient temperatures.

Chemical stability: The product is chemically stable under recommended conditions of storage, use and temperature.

Possibility of hazardous reactions: Violent reaction with: Oxidising agent, strong. Strong acid

Conditions to avoid: Keep away from heat.

Incompatible materials: Oxidising agent, strong. Strong acid

Hazardous decomposition products: Does not decompose when used for intended uses.

Disposal considerations

Dispose of waste according to applicable legislation. The allocation of waste identity numbers/waste descriptions must be carried out according to the EEC, specific to the industry and process.

Collect the waste separately. Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point.

Handle contaminated packages in the same way as the substance itself.