Registration Dossier

Administrative data

First-aid measures

After inhalation: Supply fresh air and seek medical attention. Risk of delayed lung edema.
After skin contact: Remove contaminated clothing. Wash affected area with plenty water. Obtain medical attention when corrosion occurs. Rub skin
with cream.
After eye contact: Immediately flush affected eye(s) with water and continue flushing for at least 15 min. Obtain medical attention and continue
to flush during transport. Risk of permanent eye damage.
After ingestion: Flush mouth with water and drink plenty of water or milk. Do not try to induce vomiting. Do not give unconscious patients anything to drink. Obtain medical attention.

Fire-fighting measures

Suitable extinguishing agents: Powder, dry sand or chalk.
Formation of toxic and corrosive gasses is possible. Avoid inhalation of fumes.

Accidental release measures

Evacuate area. Cover up drains. Eliminate sources of ignition.
Absorb spillage in absorbing material and transfer to suitable container. Wash the spillage area with plenty of water, and prevent entry into drains.

Handling and storage

Persons who handle this material should be familiar with the hazards of the material and the necessary safety precautions.
Pregnant and breastfeeding women should not be exposed to the substance.
Avoid inhalation of vapours.
Immediately remove contaminated clothes.
The substance should preferable be used in closed systems and be handled in well-ventialted systems.

Transport information

Land transport (ADR/RID)

UN number:
3399
Proper shipping name and description:
ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE FLAMMABLE
Chemical name:
Phenylmagnesiumbromide in THF
Language:
English
Class:
4.3 Substances which, in contact with water, emit flammable gases.
Classification code:
4.3
Packaging group:
I
Labels:
4.3+3
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3399
Proper shipping name and description:
ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE FLAMMABLE
Chemical name:
Phenylmagnesiumbromide in THF
Language:
English
Class:
4.3 Substances which, in contact with water, emit flammable gases.
Classification code:
4.3
Packaging group:
I
Labels:
4.3+3
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3399
Proper shipping name and description:
ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE FLAMMABLE
Chemical name:
Phenylmagnesiumbromide in THF
Class:
4.3 Substances which, in contact with water, emit flammable gases.
Packaging group:
I
EmS code:
F-G, S-N
Labels:
4.3+3
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3399
Proper shipping name and description:
ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE FLAMMABLE
Chemical name:
Phenylmagnesiumbromide in THF
Class:
4.3 Substances which, in contact with water, emit flammable gases.
Packaging group:
I
Labels:
4.3+3
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

In case of insufficient ventilation, use a self-contained breathing apparatus or mask.
Use tightly sealed goggles.
Use protective gloves (FKM).

Stability and reactivity

Stable at normal temperaure and pressure.
The product is a flammable liquid and and vapours may form explosive mixtures with air.
The product should be disposed of according to local regulations.

Disposal considerations

Disposal in closed cycle incinerator is recommended.