Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

General information
Remove soiled or soaked clothing immediately
After inhalation
When inhaled remove to fresh air and seek medical aid.
After contact with skin
In case of contact with skin wash off immediately with soap and water
Summon a doctor immediately.
After contact with eyes
In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice
After ingestion
Summon a doctor immediately.
Advice to doctor
Treatment
Rinse the affected eye with edible vegetable oil.
Wash the affected skin alternately with edible vegetable oil and with soap.

Fire-fighting measures

Suitable extinguishing media
foam
water spray jet
carbon dioxide
dry powder
Extinguishing media that must not be used for safety reasons
strong water jet
Special hazards from the substance itself, its combustion products or from its vapours
In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO)
Nitrous gases (NOx)
Special protective equipment for firefighting
Use self-contained breathing apparatus

Accidental release measures

Personal precautions
Wear suitable personal protective equipment.
Environmental precautions
Do not allow to enter drains or waterways
Methods for cleaning up/taking up
Pick up with binding agent (eg sand, sawdust). Rinse away rest with plenty of water or dilute
acetic acid
Do not use chemical binders containing acids

Handling and storage

Handling and storage
Advice on safe handling
Open and handle container with care.
Use only in well ventilated areas.
Advice on storage compatibility
Do not store with acids
Further information on storage conditions
Keep container tightly closed in a cool, well-ventilated place, open and handle carefully. - frost-sensitive - if the product becomes turbid as a result of exposure to low temperatures, warm it slowly to approx. 50°C and stir it. Before using the product, ensure that is is completely homogeneous.

Transport information

Land transport (ADR/RID)

UN number:
UN 2735
Proper shipping name and description:
Amines, liquid, corrosive, n.o.s.
Chemical name:
C16-18-(even numbered, saturated and unsaturated)-alkylamines
Language:
English
Class:
8
Classification code:
C7
Packaging group:
II
Labels:
C, N
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN 2735
Proper shipping name and description:
Amines, liquid, corrosive, n.o.s.
Chemical name:
C16-18-(even numbered, saturated and unsaturated)-alkylamines
Language:
English
Class:
8
Classification code:
C7
Packaging group:
II
Labels:
C, N
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN 2735
Proper shipping name and description:
Amines, liquid, corrosive, n.o.s.
Chemical name:
C16-18-(even numbered, saturated and unsaturated)-alkylamines
Class:
8
Packaging group:
II
EmS code:
F-A S-B
Labels:
C, N
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN 2735
Proper shipping name and description:
Amines, liquid, corrosive, n.o.s.
Chemical name:
C16-18-(even numbered, saturated and unsaturated)-alkylamines
Class:
8
Packaging group:
II
Labels:
C, N
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Occupational exposure controls

General protective measures
Avoid contact with eyes and skin

Hygiene measures
Observe the usual precautions when handling chemicals.

Respiratory protection :

Use respiratory protection in case of insufficient exhaust ventilation or prolonged exposure Full mask to standard DIN EN 136
Filter A (organic gases and vapours) to standard DIN EN 141 The use of filter apparatus presupposes that the environment atmosphere contains at least 17% oxygen by volume, and does not exceed the maximum gas concentration, usually 0.5% by volume. Relevant guidelines to be considered include EN 136/141/143/371/372 as well as other national regulations.
Observe applicable relevant national regulations,(e.g. TRGS 900 and BGR 190 in Germany).Take note of the recommendedations regarding the duration for which Respiratory Protective Equipment may be worn, according to chapter 19 Abs. 5 GefStoffV in conjunction with the rules of wearing such equipment.

Hand protection:
For long-term exposure:
Butyl rubber gloves.
Minimum thickness (glove): not determined
Chemical resistant gloves according to category III of DIN EN 374

With solid dry substances permeation is not to be expected,
therefore the breakthrough-time for this protective glove has
not been measured.

For short-term exposure (splash protection):
Nitrile rubber gloves.
Minimum thickness (glove): not determined
With solid dry substances permeation is not to be expected, therefore the breakthrough-time for this protective glove has not been measured. These types of protective gloves are offered by various manufacturers. Please note the manufacturers´ detailed statements, especially about the minimum thickness and the minimum breakthrough time. Consider also the particular working conditions under which the gloves are being used.

Eye protection:
Depending on the risk, wear sufficient eye protection (safety glasses with side protection or goggles, and if necessary, face shield.)

Body protection : For details, see the BG-Information number 595.

Stability and reactivity

Thermal decomposition : (Heating rate : 3 K/min)
Method : DTA
Source : Analogy
No decomposition upto 400 °C.
Hazardous reactions
Reactions with acids.
Hazardous decomposition products
Nitrous oxides (NOx)
Conditions to avoid
Avoid contact with strong acids.

Disposal considerations

Product
In accordance with local authority regulations, take to special waste incineration or chemical/physical treatment plant