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Diss Factsheets

Physical & Chemical properties

Melting point / freezing point

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Administrative data

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Endpoint:
melting point/freezing point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2010-01-06
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
test procedure in accordance with national standard methods with acceptable restrictions
Remarks:
Test procedure in accordance with national standard methods (ASTM) without GLP.
Qualifier:
according to guideline
Guideline:
other: ASTM-D97
Deviations:
no
GLP compliance:
no
Type of method:
pour point
Key result
Melting / freezing pt.:
57 °C
Atm. press.:
ca. 1 atm
Decomposition:
no
Sublimation:
no

Measurement

(repeat determination)

Pour Point:57°C / 57°C

Conclusions:
A pour point value of 57°C at atmospheric pressure was determined for the substance using a relevant test method. The result is considered to be reliable.
Executive summary:

The pour point of Octadecan-1 -ol was assessed according to ASTM-D97. The pour point was dertermined to be 57 °C at atmospheric pressure.

Endpoint:
melting point/freezing point
Type of information:
other: Data obtained from a handbook
Adequacy of study:
supporting study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
data from handbook or collection of data
Principles of method if other than guideline:
No information available regarding guideline or methodology. The value is rounded to the nearest 0.1ºC.
GLP compliance:
not specified
Melting / freezing pt.:
59.5 °C
Remarks on result:
other: The atmospheric pressure at which this result was determined is not stated but it is consistent with expected properties at standard pressure.
Melting / freezing pt.:
59 - 60 °C
Remarks on result:
other: The pressure conditions for the measurement are not stated. This value is taken from an older edition of the Handbook (1990)
Conclusions:
A melting point value of 59-60ºC was reported in a handbook or collection of reliable data which has been subject to peer-review and in which the original data sources are traceable. The result is considered to be reliable.
Endpoint:
melting point/freezing point
Type of information:
other: Data obtained from a secondary source
Adequacy of study:
supporting study
Reliability:
4 (not assignable)
Rationale for reliability incl. deficiencies:
secondary literature
Melting / freezing pt.:
58 °C
Conclusions:
A melting point value of 58°C was reported for the substance in a secondary source to which reliability could not be assigned.
Endpoint:
melting point/freezing point
Type of information:
other: Data obtained from a secondary source
Adequacy of study:
supporting study
Reliability:
4 (not assignable)
Rationale for reliability incl. deficiencies:
secondary literature
Melting / freezing pt.:
59.5 °C
Conclusions:
A melting point value of 59.5°C was reported for the substance in a secondary source to which reliability could not be assigned.

Description of key information

The pour point of octadecan-1-ol is 57°C at 1013 hPa.

Key value for chemical safety assessment

Melting / freezing point at 101 325 Pa:
57 °C

Additional information

A measured pour point value of 57°C at 1013 hPa was determined in accordance with ASTM-D97 test method.The result is considered to be reliable and is selected as key study.

It is supported by a value of 59-60°C taken from a reliable handbook, and various consistent results from other secondary sources.

Discussion of trends in the Category of C6-24 linear and essentially-linear aliphatic alcohols:

As the chain length increases, melting point increases. This is because molecular weight is higher and intermolecular forces in the substance are all higher.