Registration Dossier
Registration Dossier
Data platform availability banner - registered substances factsheets
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Diss Factsheets
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 939-603-7 | CAS number: 1471316-72-9
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Skin sensitisation
Administrative data
- Endpoint:
- skin sensitisation: in vivo (non-LLNA)
- Type of information:
- migrated information: read-across from supporting substance (structural analogue or surrogate)
- Adequacy of study:
- key study
- Study period:
- Between 07 May 1992 and 02 July 1992
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- other: see 'Remark'
- Remarks:
- Study conducted in compliance with agreed protocols, with no or minor deviations from standard test guidelines and/or minor methodological deficiencies, which do not affect the quality of the relevant results. However, as this study is used in a read-across approach Klimisch 2 is assigned.
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 1 993
- Report date:
- 1993
Materials and methods
Test guidelineopen allclose all
- Qualifier:
- equivalent or similar to guideline
- Guideline:
- other: OECD
- Qualifier:
- equivalent or similar to guideline
- Guideline:
- other: EPA-FIFRA
- Qualifier:
- equivalent or similar to guideline
- Guideline:
- other: EPA-TSCA
- Qualifier:
- equivalent or similar to guideline
- Guideline:
- other: Japanese-MAFF
- GLP compliance:
- yes
- Type of study:
- Buehler test
Test material
- Reference substance name:
- 75975-85-8
- EC Number:
- 616-278-7
- Cas Number:
- 75975-85-8
- IUPAC Name:
- 75975-85-8
- Test material form:
- other: liquid
- Details on test material:
- Sponsor ID: 0S# 67708C (Total Base Number = 300)
Springborn ID: S92.007.3263
Receipt Date: March 31, 1992
Physical Description: Brown liquid
Storage Conditions: Room temperature
Expiration Date: None provided
Constituent 1
In vivo test system
Test animals
- Species:
- guinea pig
- Strain:
- Hartley
- Sex:
- male/female
- Details on test animals and environmental conditions:
- Animals and Animal Husbandry
Animal housing and care were based on AAALAC standards and to those published in the Guide for the Care and Use of Laboratory Animals, NIH Publication No. 88-23.
Young adult Hartley Derived Albino guinea pigs were obtained from Harlan Sprague Dawley, Inc., Indianapolis, Indiana, for use in this study. The animals were individually housed in suspended stainless steel cages in an environment-controlled room with a 12/12 hour light/dark cycle. Purina Certified Guinea Pig Chow #5026 and purified water were provided to each animal ad libitum. The guinea pigs were individually identified using cage cards. All animals were acclimated to the laboratory environment for a minimum of five days prior to dosing. Only those animals judged to be healthy were assigned to the study. All range-finding study animals were weighed on the day prior to chamber application; main study animals were weighed on the day prior to the first induction and each subsequent chamber application at challenge and rechallenges.
Study design: in vivo (non-LLNA)
Inductionopen allclose all
- Route:
- epicutaneous, occlusive
- Vehicle:
- other: mineral oil
- Concentration / amount:
- 100% as received, and 75%, 50% and 25% w/v OS# 67708C in USP grade mineral oil
Challengeopen allclose all
- Route:
- epicutaneous, occlusive
- Vehicle:
- other: mineral oil
- Concentration / amount:
- 100% as received, and 75%, 50% and 25% w/v OS# 67708C in USP grade mineral oil
- No. of animals per dose:
- Phase/Group Males / Females
Topical Range-Finding: 2 / 2
Test Group: 5 / 5
Challenge Control Group: 5 / 5
Rechallenge Control Group: 5 / 5
Second Rechallenge Control Group: 5 / 5
DNCB Test Group: 3 / 3
DNCB Control Group: 2 / 1 - Details on study design:
- Fifty-three guinea pigs were assigned to the study.
Range-finding study
Irritation screen: A preliminary irritation screen was performed to determine an appropriate concentration of the test article for the standard sensitization study. The procedure was as follows:
On the day prior to dose administration, the hair was clipped from the dorsal trunk area of two male and two female guinea pigs using a small animal clipper. On the following day, four chambers at four different concentrations (100% as received, and 75%, 50% and 25% w/v OS# 67708C in USP grade mineral oil) were applied to the clipped area of each animal (one chamber for each level of test article). A dose of 0.3 mL of the freshly prepared test substance or test substance mixture was placed on a 25 mm Hilltop chamber. The chambers then were applied to the clipped surface as quickly as possible. The trunk of the animal was wrapped with elastic wrap and secured with tape to prevent removal of the chamber and the animal was returned to its cage.
Approximately six hours after dosing, the elastic wrap, tape and chambers were removed. The test sites were wiped with gauze moistened in USP grade mineral oil to remove test article residue and the animals returned to their cages. Approximately 24 and 48 hours following chamber application the test sites were graded using the following scale:
0 - No reaction
± - Slight patchy erythema
1 - Slight, but confluent or moderate patchy erythema.
2 - Moderate confluent erythema
3 - Severe erythema with or without edema
Induction phase: On the day prior to dose administration (day -1), the hair was then removed from the left side of ten test animals and six DNCB test animals with a small animal clipper. On the following day (day 1) a dose of 0.3 mL of the freshly prepared test solution was placed on a 25 mm Hilltop chamber. The chamber was then applied to the clipped surface of each animal as quickly as possible. Test animals received 100% OS# 67708C. The DNCB test animals received 0.5% w/v DNCB in acetone/ethanol. The trunk of each test animal was then wrapped with elastic wrap to prevent removal of the chamber and the animal returned to its cage. NOTE: The DNCB positive control group was utilized as a common control group for two other Modified Buehler Studies running concurrently for the Sponsor.
Approximately six hours after dosing, the elastic wrap and chamber were removed. The sites for the test animals were wiped with gauze moistened in USP grade mineral oil and the test sites for the DNCB animals were wiped with gauze moistened in distilled water to remove test article residue. The animals were returned to their cages. Test sites were graded for dermal irritation at approximately 24 and 48 hours following chamber application using the scale presented previously. The above induction and grading procedures were repeated for both the test and DNCB test animals on study day 8 and study day 15 so that a total of three consecutive induction exposures were made to the animals. The animals remained untreated after the last induction until the challenge phase of this study.
Challenge phase: On the day prior to challenge dose administration, the hair was clipped from the left side of the ten test and ten naive challenge control animals and the right side of the DNCB test and control animals with a small animal clipper. On day 29, a dose of 0.3 mL of the freshly prepared test substance mixture was placed on a 25 mm Hilltop chamber. The chamber was then applied to the clipped surface of each test and challenge control animal as quickly as possible. Test and challenge control animals received 50% w/v OS# 67708C in USP grade mineral oil. DNCB test and DNCB control animals received two 25 mm Hilltop chambers containing 0.1 % w /v or 0.2% w /v DNCB in acetone/ethanol. The trunk of each animal was then wrapped with elastic wrap in order to prevent removal of the chamber and the animal was returned to its cage.
Approximately six hours after dosing, the elastic wrap and chamber were removed. The OS# 67708C test sites were wiped with gauze moistened in USP grade mineral oil and the DNCB test sites were wiped with gauze moistened in distilled water to remove test article residue. The animals were then returned to their cages.
Approximately 20 hours after chamber removal the exposure sites were depilated using Neet Cream. The depilatory was placed on the test sites and surrounding areas and left on for no more than fifteen minutes. The depilatory was thoroughly removed with a stream of warm, running water. The animals were dried with a towel and returned to their cages. Approximately 24 and 48 hours after chamber removal, the test sites were graded using the scale presented previously.
Rechallenge phase: The rechallenge was performed on study day 37. On the day prior to rechallenge dose administration, the hair was removed from the right side of the ten test and ten naive rechallenge control animals with a small animal clipper. On the following day, a dose of 0.3 mL of the freshly prepared test substance mixture was placed on a 25 mm Hilltop chamber. The chamber was then applied to the clipped surface of each test and rechallenge control animal as quickly as possible. Test and rechallenge control animals received 25% w/v OS# 67708C in USP grade mineral oil. The trunk of each animal was then wrapped with elastic wrap in order to prevent removal of the chamber and the animal returned to its cage.
Approximately six hours after dosing, the elastic wrap and chamber were removed. The OS# 67708C test sites were wiped with gauze moistened in USP grade mineral oil and the animals were returned to their individual cages. Procedures for depilation and grading were the same as those described for challenge.
Second rechallenge phase: The rechallenge was performed on study day 43. On the day prior to rechallenge dose administration, the hair was removed from the right side of the ten test and ten naive rechallenge control animals with a small animal clipper. On the following day, a dose of 0.3 mL of the freshly prepared test substance mixture was placed on a 25 mm Hilltop chamber. The chamber was then applied to the clipped surface as
quickly as possible. Test and rechallenge control animals received 10% w/v OS# 67708C in USP grade mineral oil. The trunk of each animal was then wrapped with elastic wrap in order to prevent removal of the chamber and the animal returned to its cage. Approximately six hours after dosing, the elastic wrap and chamber were removed. The OS# 67708C test sites were wiped with gauze moistened in USP grade mineral oil and the animals were returned to their individual cages. Procedures for depilation and grading were the same as those described for challenge.
Study design: in vivo (LLNA)
- Positive control substance(s):
- other: 1-chloro-2,4-dinitrobenzene (DNCB)
Results and discussion
In vivo (non-LLNA)
Resultsopen allclose all
- Reading:
- 1st reading
- Hours after challenge:
- 24
- Group:
- test chemical
- Dose level:
- 50% w/v OS#67708C in mineral oil
- No. with + reactions:
- 9
- Total no. in group:
- 10
- Remarks on result:
- other: Reading: 1st reading. . Hours after challenge: 24.0. Group: test group. Dose level: 50% w/v OS#67708C in mineral oil. No with. + reactions: 9.0. Total no. in groups: 10.0.
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- test chemical
- Dose level:
- 50% w/v OS#67708C in mineral oil
- No. with + reactions:
- 8
- Total no. in group:
- 10
- Remarks on result:
- other: Reading: 2nd reading. . Hours after challenge: 48.0. Group: test group. Dose level: 50% w/v OS#67708C in mineral oil. No with. + reactions: 8.0. Total no. in groups: 10.0.
- Reading:
- 1st reading
- Hours after challenge:
- 24
- Group:
- other: challenge control
- Dose level:
- 50% w/v OS#67708C in mineral oil
- No. with + reactions:
- 1
- Total no. in group:
- 10
- Remarks on result:
- other: Reading: 1st reading. . Hours after challenge: 24.0. Group: other: challenge control. Dose level: 50% w/v OS#67708C in mineral oil. No with. + reactions: 1.0. Total no. in groups: 10.0.
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- other: challenge control
- Dose level:
- 50% w/v OS#67708C in mineral oil
- No. with + reactions:
- 1
- Total no. in group:
- 10
- Remarks on result:
- other: Reading: 2nd reading. . Hours after challenge: 48.0. Group: other: challenge control. Dose level: 50% w/v OS#67708C in mineral oil. No with. + reactions: 1.0. Total no. in groups: 10.0.
- Reading:
- 1st reading
- Hours after challenge:
- 24
- Group:
- other: DNCB
- Dose level:
- 0.1% w/v DNCB in Acetone/Ethanol
- No. with + reactions:
- 6
- Total no. in group:
- 6
- Remarks on result:
- other: Reading: 1st reading. . Hours after challenge: 24.0. Group: other: DNCB. Dose level: 0.1% w/v DNCB in Acetone/Ethanol. No with. + reactions: 6.0. Total no. in groups: 6.0.
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- other: DNCB
- Dose level:
- 0.1% w/v DNCB in Acetone/Ethanol
- No. with + reactions:
- 6
- Total no. in group:
- 6
- Remarks on result:
- other: Reading: 2nd reading. . Hours after challenge: 48.0. Group: other: DNCB. Dose level: 0.1% w/v DNCB in Acetone/Ethanol. No with. + reactions: 6.0. Total no. in groups: 6.0.
- Reading:
- 1st reading
- Hours after challenge:
- 24
- Group:
- other: DNCB Controls
- Dose level:
- 0.1% w/v DNCB in Acetone/Ethanol
- No. with + reactions:
- 1
- Total no. in group:
- 3
- Remarks on result:
- other: Reading: 1st reading. . Hours after challenge: 24.0. Group: other: DNCB Controls. Dose level: 0.1% w/v DNCB in Acetone/Ethanol. No with. + reactions: 1.0. Total no. in groups: 3.0.
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- other: DNCB Controls
- Dose level:
- 0.1% w/v DNCB in Acetone/Ethanol
- No. with + reactions:
- 0
- Total no. in group:
- 3
- Remarks on result:
- other: Reading: 2nd reading. . Hours after challenge: 48.0. Group: other: DNCB Controls. Dose level: 0.1% w/v DNCB in Acetone/Ethanol. No with. + reactions: 0.0. Total no. in groups: 3.0.
- Reading:
- 1st reading
- Hours after challenge:
- 24
- Group:
- other: DNCB
- Dose level:
- 0.2% w/v DNCB in Acetone/Ethanol
- No. with + reactions:
- 6
- Total no. in group:
- 6
- Remarks on result:
- other: Reading: 1st reading. . Hours after challenge: 24.0. Group: other: DNCB. Dose level: 0.2% w/v DNCB in Acetone/Ethanol. No with. + reactions: 6.0. Total no. in groups: 6.0.
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- other: DNCB
- Dose level:
- 0.2% w/v DNCB in Acetone/Ethanol
- No. with + reactions:
- 6
- Total no. in group:
- 6
- Remarks on result:
- other: Reading: 2nd reading. . Hours after challenge: 48.0. Group: other: DNCB. Dose level: 0.2% w/v DNCB in Acetone/Ethanol. No with. + reactions: 6.0. Total no. in groups: 6.0.
- Reading:
- 1st reading
- Hours after challenge:
- 24
- Group:
- other: DNCB Controls
- Dose level:
- 0.2% w/v DNCB in Acetone/Ethanol
- No. with + reactions:
- 2
- Total no. in group:
- 3
- Remarks on result:
- other: Reading: 1st reading. . Hours after challenge: 24.0. Group: other: DNCB Controls. Dose level: 0.2% w/v DNCB in Acetone/Ethanol. No with. + reactions: 2.0. Total no. in groups: 3.0.
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- other: DNCB Controls
- Dose level:
- 0.2% w/v DNCB in Acetone/Ethanol
- No. with + reactions:
- 1
- Total no. in group:
- 3
- Remarks on result:
- other: Reading: 2nd reading. . Hours after challenge: 48.0. Group: other: DNCB Controls. Dose level: 0.2% w/v DNCB in Acetone/Ethanol. No with. + reactions: 1.0. Total no. in groups: 3.0.
- Reading:
- rechallenge
- Hours after challenge:
- 24
- Group:
- test chemical
- Dose level:
- 25% w/v OS#67708C in mineral oil
- No. with + reactions:
- 10
- Total no. in group:
- 10
- Remarks on result:
- other: Reading: rechallenge. . Hours after challenge: 24.0. Group: test group. Dose level: 25% w/v OS#67708C in mineral oil. No with. + reactions: 10.0. Total no. in groups: 10.0.
- Reading:
- rechallenge
- Hours after challenge:
- 48
- Group:
- test chemical
- Dose level:
- 25% w/v OS#67708C in mineral oil
- No. with + reactions:
- 10
- Total no. in group:
- 10
- Remarks on result:
- other: Reading: rechallenge. . Hours after challenge: 48.0. Group: test group. Dose level: 25% w/v OS#67708C in mineral oil. No with. + reactions: 10.0. Total no. in groups: 10.0.
- Reading:
- rechallenge
- Hours after challenge:
- 24
- Group:
- negative control
- Dose level:
- 25% w/v OS#67708C in mineral oil
- No. with + reactions:
- 4
- Total no. in group:
- 10
- Remarks on result:
- other: Reading: rechallenge. . Hours after challenge: 24.0. Group: negative control. Dose level: 25% w/v OS#67708C in mineral oil. No with. + reactions: 4.0. Total no. in groups: 10.0.
- Reading:
- rechallenge
- Hours after challenge:
- 48
- Group:
- negative control
- Dose level:
- 25% w/v OS#67708C in mineral oil
- No. with + reactions:
- 5
- Total no. in group:
- 10
- Remarks on result:
- other: Reading: rechallenge. . Hours after challenge: 48.0. Group: negative control. Dose level: 25% w/v OS#67708C in mineral oil. No with. + reactions: 5.0. Total no. in groups: 10.0.
- Reading:
- other: second rechallenge
- Hours after challenge:
- 24
- Group:
- test chemical
- Dose level:
- 10% w/v OS#67708C in mineral oil
- No. with + reactions:
- 7
- Total no. in group:
- 10
- Remarks on result:
- other: Reading: other: second rechallenge. . Hours after challenge: 24.0. Group: test group. Dose level: 10% w/v OS#67708C in mineral oil. No with. + reactions: 7.0. Total no. in groups: 10.0.
- Reading:
- other: second rechallenge
- Hours after challenge:
- 48
- Group:
- test chemical
- Dose level:
- 10% w/v OS#67708C in mineral oil
- No. with + reactions:
- 7
- Total no. in group:
- 10
- Remarks on result:
- other: Reading: other: second rechallenge. . Hours after challenge: 48.0. Group: test group. Dose level: 10% w/v OS#67708C in mineral oil. No with. + reactions: 7.0. Total no. in groups: 10.0.
- Reading:
- other: second rechallenge
- Hours after challenge:
- 24
- Group:
- negative control
- Dose level:
- 10% w/v OS#67708C in mineral oil
- No. with + reactions:
- 0
- Total no. in group:
- 10
- Remarks on result:
- other: Reading: other: second rechallenge. . Hours after challenge: 24.0. Group: negative control. Dose level: 10% w/v OS#67708C in mineral oil. No with. + reactions: 0.0. Total no. in groups: 10.0.
- Reading:
- other: second rechallenge
- Hours after challenge:
- 48
- Group:
- negative control
- Dose level:
- 10% w/v OS#67708C in mineral oil
- No. with + reactions:
- 0
- Total no. in group:
- 10
- Remarks on result:
- other: Reading: other: second rechallenge. . Hours after challenge: 48.0. Group: negative control. Dose level: 10% w/v OS#67708C in mineral oil. No with. + reactions: 0.0. Total no. in groups: 10.0.
Any other information on results incl. tables
Body weight Data | |||||
Group | Animal | Body Weight(g) | |||
Number/Sex | One Day Prior to Dosing | ||||
Range-Finding | 8186/M | 492 | |||
8187/M | 470 | ||||
8215/F | 435 | ||||
8216/F | 403 | ||||
Group | Animal | Body Weight {g) | |||
Number/Sex | Day -1 | Day28 | Day 36 | Day 42 | |
Test | 8400/M | 428 | 594 | 604 | 531 |
8401/M | 444 | 614 | 627 | 640 | |
8402/M | 424 | 594 | 622 | 633 | |
8403/M | 419 | 534 | 548 | 550 | |
8404/M | 423 | 595 | 602 | 618 | |
8510/F | 419 | 534 | 550 | 544 | |
8511/F | 406 | 516 | 515 | 518 | |
8512/F | 449 | 489 | 497 | 453 | |
8513/F | 458 | 547 | 567 | 569 | |
8514/F | 433 | 637 | 652 | 640 | |
Challenge Contrel | 8405/M | 433 | 666 | - | - |
8406/M | 450 | 625 | - | - | |
8407/M | 441 | 660 | - | - | |
8408/M | 452 | 708 | - | - | |
8409/M | 433 | 675 | - | - | |
8515/F | 396 | 534 | - | - | |
8516/F | 428 | 550 | - | - | |
8517/F | 400 | 515 | - | - | |
8518/F | 436 | 597 | - | - | |
8519/F | 431 | 552 | - | - | |
Rechallenge Controls | 8410/M | 419 | - | 621 | - |
8411/M | 389 | - | 612 | - | |
8412/M | 403 | - | 652 | - | |
8413/M | 402 | - | 658 | - | |
8414/M | 373 | - | 758 | - | |
8520/F | 401 | - | 607 | - | |
8521/F | 406 | - | 550 | - | |
8522/F | 373 | - | 517 | - | |
8523/F | 413 | - | 571 | - | |
8524/F | 396 | - | 521 | - | |
Second Rechallenge Controte | 8415/M | 425 | - | - | 701 |
8416/M | 410 | - | - | 672 | |
8417/M | 470 | - | - | 879 | |
8418/M | 452 | - | - | 714 | |
8419/m | 440 | - | - | 712 | |
8525/f | 425 | - | - | 594 | |
8526/F | 402 | - | - | 552 | |
8527/F | 435 | - | - | 586 | |
8528/F | 417 | - | - | 559 | |
8529/F | 414 | - | - | 571 | |
DNCB Test | 8355/M | 421 | 561 | - | - |
8356/M | 461 | 697 | - | - | |
8357/M | 444 | 635 | - | - | |
8465/F | 409 | 468 | - | - | |
8466/F | 388 | 535 | - | - | |
8467/F | 392 | 496 | - | - | |
DNCß Control | 8358/F | 439 | 681 | - | - |
8359/M | 412 | 599 | - | - | |
8468/F | 419 | 537 | - | - |
Table 2 | |||
Individual Range-Finding Scores | |||
(OS# 67708C) | |||
Treatment | Animal Number/ Sex | Dermal Scores | |
24 hr | 48 hr | ||
100% w/v OS# 67708C | 8186/M | ± | ± |
8187/M | ± | 0 | |
8215/F | 0 | 0 | |
8216/F | ± | ± | |
75% w/v OS# 67708C in Mineral Oil | 8186/M | 0 | 0 |
8187/M | ± | 0 | |
8215/F | ± | 0 | |
8216/F | ± | 0 | |
50% w/v OS# 67708C in Mineral Oil | 8186/M | 0 | 0 |
8187/M | ± | 0 | |
8215/F | ± | 0 | |
8216/F | 0 | 0 | |
25% w/v OS# 67708C in Mineral Oil | 8186/M | 0 | 0 |
8187/M | 0 | 0 | |
8215/F | 0 | 0 | |
8216/F | 0 | 0 |
Table 3 | |||||||
Individual Induction Scores | |||||||
(OS* 67708C) | |||||||
Group | Animal No./ Sex | Dermal Scores | |||||
Induction 1* | Induction 2* | Induction 3* | |||||
24 Hr | 48 Hr | 24 Hr | 48 Hr | 24 Hr | 48 Hr | ||
Test | 8400/M | ± | 0 | 0 | 0 | ± | 0 |
8401/M | 0 | 0 | 0 | 0 | ± | ± | |
8402/M | 0 | 0 | ± | 0 | ± | ± | |
8403/M | 0 | 0 | 0 | 0 | ± | ± | |
8404/M | 0 | 0 | 0 | 0 | ± | ± | |
8510/F | 0 | 0 | ± | 0 | ± | ± | |
8511/F | 0 | 0 | ± | 0 | 1 | ± | |
8512/F | 0 | ± | ± | 0 | 1 | ± | |
8513/F | 0 | ± | 0 | 0 | 1 | ± | |
8514/F | 0 | 0 | 0 | 0 | ± | 0 | |
*100% (as received) OS* 67708C. |
Table 4 | |||||||
Individual Induction Scores | |||||||
(DNCB) | |||||||
Group | Animal No./ Sex | Dermal Scores | |||||
Induction 1* | Induction 2* | Induction 3* | |||||
24 Hr | 48 Hr | 24 Hr | 48 Hr | 24 Hr | 48 Hr | ||
DNCB Test | 8355/M | ± | ± | 3b,c | 3b,c | 3c, d | 3b, c, d |
8356/M | ± | ± | 3b,c | 3b,c | 3b, d, e | 3b,c | |
8357/M | 1 | 1c | 3b,c | 3b,c | 2c | 3d, e | |
8465/F | ± | 2c | 3b,c | 3b,c | 3b, c, d | 3b, c, d | |
8466/F | 1 | 1c | 3b,c | 3b,c | 3b, c, d | 3b, c, d | |
8467/F | ± | ± | 3b,c | 3b,c | 3b, c, d | 3b, c, d | |
a0.5% w/v DNCB | |||||||
bEschar | |||||||
cSlinght edema | |||||||
dblanching | |||||||
eModerate edema |
Table 5 | ||||
Individual Challenge Scores | ||||
(OS# 67708C) | ||||
Group | Challenge Treatment | Animal No./Sex | Dermal Scores | |
24 Hr | 48 Hr | |||
Test | 50%w/vOS# 67708C in USP Grade Mineral Oil | 8400/M | 1 | 1 |
8401/M | 1 | 1a | ||
8402/M | ± | ± | ||
8403/M | 1 | 1 | ||
8404/M | 1 | 1 | ||
8510/F | 1 | 1a | ||
8511/F | 1 | ± | ||
8512/F | 1 | 1a | ||
8513/F | 1 | 1 | ||
8514/F | 2a | 2a | ||
Mean | 1.1 | 1.0 | ||
Challenge Controls | 50%w/vOS# 67708C in USP Grade Mineral Oil | 8405/M | ± | ± |
8406/M | ± | ± | ||
8407/M | ± | ± | ||
8408/M | ± | 1 | ||
8409/M | ± | ± | ||
8515/F | ± | ± | ||
8516/F | 1 | ± | ||
8517/F | ± | ± | ||
8518/F | 0 | 0 | ||
8519/F | ± | ± | ||
Mean | 0.5 | 0.5 | ||
aslight edema | ||||
bmoderate edema | ||||
csevere edema | ||||
NOTE: For the purpose af calculation, ± = 0.5. |
Table 6 | ||||
individual challenge Scores | ||||
{DNCB) | ||||
Group | Challenge Treatment | Animal No./ Sex | Dermal Scores | |
24 Hr | 48 Hr | |||
DNCB Test | 0.1% w/v in Acetone/Ethanol | 8355/M | 3a, b | 3a, b |
8356/M | 3a, c, d | 3a, c, d | ||
8357/M | 3a, c, d | 3a, c, d | ||
8465/F | 3a, b | 3a, b | ||
8466/F | 3a, c | 3a, c | ||
8467/F | 3a, b,d | 3a, b,d | ||
Mean | 3.0 | 3.0 | ||
DNCB Controls | 0.1% w/vin Acetone/Ethanol | 8358/M | 1 | ± |
8359/M | ± | ± | ||
8968/F | ± | 0 | ||
Mean | 0.7 | 0.3 | ||
DNCB Test | 0.2% w/vin Acetone/Ethanol | 8355/M | 3a, b | 3a, c, d |
8356/M | 3a, c, d | 3a, c, d | ||
8357/M | 3a, c, d | 3a, c, d | ||
8465/F | 3a, c | 3a, c, d | ||
8466/F | 3a, c | 3a, c | ||
8467/F | 3a, c, d | 3a, c, d | ||
Mean | 3.0 | 3.0 | ||
DNCB Controls | 0.2% w/v in Acetone/Ethanol | 8358/M | 1 | 1 |
8359/M | ± | ± | ||
8968/F | 1 | ± | ||
Mean | 0.8 | 0.7 | ||
ablanching | ||||
bslight edema | ||||
cmoderate edema | ||||
deschar | ||||
NOTE: For the purpose of calculation, ± = 0.5 |
Table 7 | ||||
IndividualRechallenge Scores | ||||
(0S#67708C) | ||||
Group | Challenge Treatment | Animal No./Sex | DermalScores | |
24 Hr | 48 Hr | |||
Test | 25%w/v OS# 67708C In USP grademineral Oil | 8400/M | 1 | 2a |
8401/M | 2a | 2a | ||
8402/M | 1 | 1 | ||
8403/M | 1 | 1 | ||
8404/M | 2a | 2b | ||
8510/F | 2a | 2b | ||
8511/F | 1 | 1 | ||
8512/F | 2a | 2a | ||
8513/F | 2a | 2a | ||
8514/F | 2 | 2a | ||
Mean | 1.6 | 1.7 | ||
Rectialtenga Controls | 25% w/v OS# 67708Cin USP Grade MineralOil | 8410/M | ± | 1 |
8411/M | ± | 1 | ||
8412/M | 1 | 1 | ||
8413/M | ± | ± | ||
8414/M | 1 | 1 | ||
8520/F | ± | ± | ||
8521/F | 1 | ± | ||
8522/F | ± | ± | ||
8523/F | 1 | 1 | ||
8524/F | ± | ± | ||
Mean | 0.7 | 0.8 | ||
aSlight edema | ||||
bModerate edema | ||||
NOTE: For the purpose af calculation, ± = 0.5. |
Table 8 | ||||
Individual Second Rechallenge Scores | ||||
(OS# 67708C) | ||||
Group | Challenge Treatment | Animal No./ Sex | Dermal Scores | |
24 Hr | 48 Hr | |||
Test | 10% w/v OS# 6770GC irt usp Grede Mineral Oil | 8400/M | 1a | 1a |
8401/M | 2a | 2a | ||
8402/M | ± | ± | ||
8403/M | 1 | ± | ||
8404/M | 2b | 2b | ||
8510/F | 1 | 1a | ||
8511/F | ± | ± | ||
8512/F | 1 | 1 | ||
8513/F | 1 | 1 | ||
8514/F | 2a | 2a | ||
Mean | 1.2 | 1.2 | ||
Fectiallenge Controls | 1d% w/v 677DSC In dsp Grade Mineral Oil | 8415/M | ± | ± |
8416/M | 0 | ± | ||
8417/M | ± | ± | ||
8418/M | 0 | ± | ||
8419/M | ± | ± | ||
8525/F | ± | ± | ||
8526/F | ± | ± | ||
8527/F | ± | ± | ||
8528/F | 0 | ± | ||
8529/F | 0 | 0 | ||
Mean | 0.3 | 0.5 | ||
aSlight edema | ||||
bModerate edema | ||||
NOTE: For the purpose af calculation, ± = 0.5. |
Applicant's summary and conclusion
- Interpretation of results:
- sensitising
- Remarks:
- Migrated information Under the conditions of this test, OS# 67708C is considered a contact sensitizer in guinea pigs.
- Conclusions:
- Under the conditions of this test, OS# 67708C (Total Base Number = 300) is considered a contact sensitizer in guinea pigs.
- Executive summary:
The potential of the calcium sulfonate read across substance (CAS 75975-85-8, Total Base Number = 300) to elicit a delayed contact hypersensitivity response was evaluated in guinea pigs. Five male and five female guinea pigs were treated topically with 100% of the test substance, once per week, for three consecutive weeks. Following a two week rest period, the ten test animals and ten previously untreated (naive) challenge control guinea pigs were topically challenged with 50% w/v of the test substance in USP grade mineral oil. Challenge responses in the test animals were compared to those of the challenge controls. Approximately one week after challenge, the ten test animals and ten previously untreated (naive) rechallenge control guinea pigs were topically rechallenged with 25% w/v ofthe test substance in USP grade mineral oil. Rechallenge responses in the test animals were compared to those of the rechallenge controls. Approximately one week after rechallenge, a second rechallenge was performed with 10% w/v ofthe test substance in USP grade mineral oil using the ten test animals and ten new naive second rechallenge control animals in order to confirm previous challenge results. Second rechallenge responses in the test animals were compared to those of the second rechallenge controls.
A dinitrochlorobenzene (DNCB) positive control group consisting of six DNCB test and three DNCB control guinea pigs was included in this study. The DNCB test animals received 0.5% w/v DNCB in an acetone/ethanol vehicle for induction and 0.1% w/v and 0.2% w/v DNCS in acetone/ethanol for challenge.
Evidence of delayed contact dermal sensitization was observed following the challenge and two rechallenges with the test substance. Slight to moderate dermal reactions (grades ± to 2) were observed for the test animals at both the 24 and 48 hour scoring intervals. No to slight reactions (grades 0 to 1) were observed for the challenge control animals at both the 24 and 48 hour scoring intervals. The 24 and 48 hour group mean scores were higher in test animals than in the challenge control animals. For both rechallenges. the test animals exhibited greater dermal responses to the test article than either of the naive rechallenge control groups.
Challenge with DNCB produced substantially stronger dermal responses in animals previously induced with the positive control demonstrating that the test system could detect potential contact sensitizers.
Based on the results of this study, the calcium sulfonate read across substance (CAS 75975-85-8) is considered a contact sensitizer in guinea pigs.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.