Registration Dossier

Administrative data

First-aid measures

- After inhalation: Move to fresh air. Keep patient warm and at rest. Call a physician or poison control center immediately.
- After skin contact: Wash off thoroughly with plenty of soap and water, if available with polyethyleneglycol 400, subsequently rinse with water. If symptoms persist, call a physician.
- After eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Get medical attention if irritation develops and persists.
- After swallowing: Rinse mouth. Do NOT induce vomiting. Call a physician or poison control center immediately.

Fire-fighting measures

- Suitable extinguishing agents: Water spray, Carbon dioxide (CO2), Foam, Sand
- Special hazards caused by the material, its products of combustion or resulting gases: Hydrogen chloride (HCl), Carbon monoxide (CO)
- Protective equipment: In the event of fire, wear self-contained breathing apparatus.
- Additional information: In the event of fire and/or explosion do not breathe fumes. Contain the spread of the fire-fighting media.
Do not allow run-off from fire fighting to enter drains or water courses.

Accidental release measures

- Person-related safety precautions: Avoid contact with spilled product or contaminated surfaces. Use personal protective equipment.
- Measures for environmental protection: Do not allow to get into surface water, drains and ground water.
- Measures for cleaning/collecting: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder).
Clean contaminated floors and objects thoroughly, observing environmental regulations. Keep in suitable, closed containers for disposal.

Handling and storage

Manufacture and use takes place under strictly controlled conditions. The substance is rigorously contained (production, use), appropriate risk management measures are applied and a management system is in place. An authorisation scheme covers the process and a procedure ensures that only trained and authorised persons handle the substance. Process procedures for containment during cleaning and maintenance have been accounted for in plant and engineering design as appropriate for the site. Procedures to ensure containment have been applied for all stages of production and processing. Occupational procedures have been assessed and are documented.

Personal precautions while handling the product:

- respiratory protection: If product is handled while not enclosed, and if contact may occur: Wear respirator with an organic vapours and gas filter mask (protection factor 10) conforming to EN140 type A or equivalent.
- eye protection: Wear goggles conforming to EN166 (Field of Use 5 or equivalent).
- hand/skin/body protection: Wear CE Marked (or equivalent) nitrile rubber gloves (minimum thickness 0,40 mm). Wash when contaminated. Dispose of when contaminated inside, when perforated or when contamination outside cannot be removed. Wear standard coverall and type 6 suit.
Wear two layers of clothing wherever possible. Polyester/cotton or cotton overalls should be worn under chemical protection suit and
should be professionally laundered frequently. If chemical protection suit is splashed, sprayed or significantly contaminated, decontaminate as far as possible, then carefully remove and dispose of as advised by manufacturer.

- Hygene measures: Wash hands always before eating, drinking, smoking or using the toilet. Avoid contact with skin, eyes and clothing.
Keep working clothes separately. Wash hands before breaks and immediately after handling the product. Remove soiled clothing immediately and clean thoroughly before using again. Garments that cannot be cleaned must be destroyed (burnt).

Transport information

Land transport (ADR/RID)

UN number:
3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2-CHLOROMETHYL-8-(1,1-DIMETHYLETHYL)-1,4-DIOXASPIRO[4.5]DECANE)
Chemical name:
2-CHLOROMETHYL-8-(1,1-DIMETHYLETHYL)-1,4-DIOXASPIRO[4.5]DECANE
Language:
English
Class:
9
Classification code:
M6
Packaging group:
III
Labels:
Packaging 9, E1
Bulk 9, E1
HazID 90
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2-CHLOROMETHYL-8-(1,1-DIMETHYLETHYL)-1,4-DIOXASPIRO[4.5]DECANE)
Chemical name:
2-CHLOROMETHYL-8-(1,1-DIMETHYLETHYL)-1,4-DIOXASPIRO[4.5]DECANE
Language:
English
Class:
9
Classification code:
M6
Packaging group:
III
Labels:
Packaging 9, E1
Bulk 9, E1
HazID 90
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(2-CHLOROMETHYL-8-(1,1-DIMETHYLETHYL)-1,4-DIOXASPIRO[4.5]DECANE)
Chemical name:
(2-CHLOROMETHYL-8-(1,1-DIMETHYLETHYL)-1,4-DIOXASPIRO[4.5]DECANE)
Class:
9
Packaging group:
III
EmS code:
F-A, S-F
Labels:
Packaging 9, P
Bulk 9, P
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(2-CHLOROMETHYL-8-(1,1-DIMETHYLETHYL)-1,4-DIOXASPIRO[4.5]DECANE )
Chemical name:
(2-CHLOROMETHYL-8-(1,1-DIMETHYLETHYL)-1,4-DIOXASPIRO[4.5]DECANE )
Class:
9
Packaging group:
III
Labels:
Packaging 9, E1
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

- Advice on safe handling: Use only in area provided with appropriate exhaust ventilation.
- Advice on protection against fire and explosion: Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place.
Store in a place accessible by authorized persons only.

Stability and reactivity

No hazardous reactions when stored and handled according to prescribed instructions.
Materials to avoid: Acids and Bases

Disposal considerations

During the whole life cycle of the substance all necessary measures in accordance to art. 18(4) of (EC) 1907/2006 are undertaken. The substance is handled under strictly controlled conditions.

In accordance with current regulations and, if necessary, after consultation with the site operator and/or with the responsible authority, the product may be taken to a waste disposal site or incineration plant.