Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

· After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in the recovery position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: If symptoms persist consult doctor.
· Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

Fire-fighting measures

· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· Special hazards arising from the substance or mixture Metal oxide fume
· Protective equipment: No special measures required.
Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Dispose contaminated material as waste according 'Disposal considerations'.
Ensure adequate ventilation.

Accidental release measures

· Personal precautions, protective equipment and emergency procedures Not required.
· Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.

Handling and storage

Handling information: Avoid formation of dust. Always close container tightly after removal of product. Ensure suitable/aeration at the work place and with operational machinery. Wear suitable protecting clothes. In case of insufficient ventilation, wear suitable respiratory equipment.
Storage Requirements: Requirements for storage rooms: Store in a cool, dry well ventilated area. Store away from incompatible substances. Avoid heat effect and sources of ignition. Requirements for containers: Ensure tightness at all times. Observe all current federal, state and local regulation when storing this substance.
Storage: Store away from incompatible substances (Ammonium salts are incompatible with Nitrite Salts: violent explosions if melted, Potassium Chlorate: violent reaction).

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
No classification currently assigned.
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Inland waterway transport (UN RTDG/ADN(R))

UN number:
No classification currently assigned.
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Marine transport (UN RTDG/IMDG)

UN number:
No classification currently assigned.
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Air transport (UN RTDG/ICAO/IATA)

UN number:
No classification currently assigned.
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Special provisions / remarks
Remarks:
GRACE recommends CARGO AIRCRAFT only.
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Exposure controls / personal protection

· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
Filter P3
· Protection of hands:
Protective gloves.
Check the condition of the gloves prior to each use.
The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the
preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation.
Preventive skin protection by use of skin-protecting agents is recommended.
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further
marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of
several substances, the resistance of the glove material can not be calculated in advance and has
therefore to be checked prior to the application.
Butyl rubber, BR
Fluorocarbon rubber (Viton)
Nitrile rubber, NBR
· Penetration time of glove material
EN 420: Minimum requirements for efficiency level 1 for all groups.
The exact break through time has to be obtained from the manufacturer of the protective gloves
and has to be observed.
For the mixture of chemicals mentioned below the penetration time has to be at least 480 minutes
(Permeation according to EN 374 Part 3: Level 6).
· For the permanent contact gloves made of the following materials are suitable:
Butyl rubber, BR
· Not suitable are gloves made of the following materials:
Leather gloves
cloth gloves
· Eye protection:
Safety glasses.
· Body protection: Protective work clothing.

Stability and reactivity

· Reactivity No further relevant information available.
· Chemical stability
No decomposition if used according to specifications.
No decomposition if used and stored according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid
In case of thermal decomposition caused by smouldering and incomplete combustion toxic fumes
may be developed.
· Incompatible materials: Protect from contamination.
· Hazardous decomposition products: Metal oxide smoke

Disposal considerations

Waste treatment methods
· Recommendation:
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.