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Physical & Chemical properties

Auto flammability

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Administrative data

Endpoint:
auto-flammability
Type of information:
experimental study
Adequacy of study:
key study
Study period:
5/3/2010-21/4/2010
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: According to EU method A.15, DIN method 51794 and IEC standard 79-4

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2010
Report date:
2010

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: DIN 51794
Qualifier:
according to guideline
Guideline:
other: IEC 79-4
GLP compliance:
yes (incl. QA statement)

Test material

Constituent 1
Chemical structure
Reference substance name:
Hexadecyldimethylamine
EC Number:
203-997-2
EC Name:
Hexadecyldimethylamine
Cas Number:
112-69-6
Molecular formula:
C18H39N
IUPAC Name:
hexadecyldimethylamine

Results and discussion

Auto-ignition temperature (liquids / gases)
Auto-ignition temperature:
255 °C
Atm. press.:
>= 992.4 - <= 994.3 hPa
Remarks on result:
other:

Any other information on results incl. tables

Main study - auto-ignition temperature of the test susbtance

The estimated auto-ignition temperature in the preliminary test was 270°C.

Test   Volume (µl)  Auto-ignition temp (ºC)  Ignition delay (s)  Colour of the flame  Minimum auto-ignition temp(ºC)
70  262 25 orange/blue  257
  140 257 40 orange/blue   
  200 258 27 orange/blue   
 2 50 262 25 orange/blue   261
100 261 16 orange/blue 
  150 262 19 orange/blue   
 3 125 260 15 orange/blue   255
250 255 25 orange/blue 
  300 258 18  orange/blue   

Ignition of the test substance within 5 minutes after introduction was observed with each sample volume and with each test a minimum auto-ignition temperature was obtained. The maximum deviation between the three values was < 10°C. According to the guidelines, no further testing was required.

The lowest temperature at which ignition of the test substance occurred was 255°C, which is also the auto-ignition temperature if rounded down to the nearest 5°C.

Applicant's summary and conclusion

Conclusions:
The test substance is auto-ignitable with an auto-ignition temperature at 992.4 and 994.3 hPa of 255ºC.
Executive summary:

The test was performanced according to EU method A.15, DIN method 51794 and IEC standard 79-4. A commercially available auto-ignition temperature apparatus was used for the determination of the degree of auto-ignitability of the substance. The test substance is auto-ignitable with an auto-ignition temperature 255ºC.