Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

4.1. Description of first aid measures
General advice Medical treatment is necessary if symptoms are evidently caused by effects of the
product on the skin, eyes or respiratory system. Remove contaminated, soaked
clothing.
Inhalation Move subject to fresh air and keep him calm. In case of complaints get medical
advice.
Skin contact Wash off immediately with soap and water. If skin irritation persists, call a
physician.
Eye contact Flush eyes thoroughly with water.
Ingestion Do not induce vomiting. Get medical advice immediately.
4.2. Most important symptoms and effects, both acute and delayed
Product has dermal defatting effect, May cause eye/skin irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

Fire-fighting measures

5.1. Extinguishing media
Suitable extinguishing media dry chemical, carbon dioxide, foam
Extinguishing media which must not
be used for safety reasons
water
5.2. Special hazards arising from the substance or mixture
May be released in case of fire: carbon monoxide, carbon dioxide, organic products of decomposition.
5.3. Advice for firefighters
Wear self-contained breathing apparatus.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Take care for adequate ventilation. Use personal protective clothing. Keep away sources of ignition. Use breathing
apparatus if exposed to vapours/dust/mist/aerosol.
6.2. Environmental precautions
Prevent product from getting into subsoil/soil. Prevent product from getting into drains/surface water/groundwater.
6.3. Methods and material for containment and cleaning up
Larger quantities: Remove mechanically (by pumping). Use explosion-proof equipment! Smaller quantities and/or residues:
Contain with absorbent material (e.g. sand, diatomaceous earth, acid absorbent, universal absorbent or sawdust). Dispose
of in accordance with regulations.
6.4. Reference to other sections
For personal protection see section 8.

Handling and storage

7.1. Precautions for safe handling
Safe handling advice Keep container tightly closed. Ensure the area is well ventilated.
Advice on protection against fire and explosion
When heated above the flash point and/or during spraying (atomizing), ignitible
mixtures may form in air. In the event of fire, cool the endangered containers with
water.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
Keep only in the original container at a temperature not exceeding 30 °C. Protect
from light. Fill the container by approximately 90 % only as oxygen (air) is required
for stabilisation. With large storage containers make sure the oxygen (air) supply is
sufficient to ensure stability. Can polymerize with intense heat release.
7.3. Specific end use(s)
no

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
Not a dangerous good within the meaning of transportation regulations.
Shippingopen allclose all
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

Shippingopen allclose all
Special provisions / remarks
Remarks:
Not a dangerous good within the meaning of transportation regulations.

Marine transport (UN RTDG/IMDG)

UN number:
Not a dangerous good within the meaning of transportation regulations.
Shippingopen allclose all
Special provisions / remarks
Remarks:
Not a dangerous good within the meaning of transportation regulations.

Air transport (UN RTDG/ICAO/IATA)

Shippingopen allclose all
Special provisions / remarks
Remarks:
Not a dangerous good within the meaning of transportation regulations.
SpecialProvisionsopen allclose all

Exposure controls / personal protection

8.1. Control parameters
see section 8.2.
8.2. Exposure controls
For monitoring procedures refer for instance to "Empfohlene Analysenverfahren für Arbeitsplatzmessungen",
Schriftenreihe der Bundesanstalt für Arbeitsschutz and "NIOSH Manual of Analytical Methods", National Institute for
Occupational Safety and Health

Protective measures
Do not inhale vapours. Avoid contact with eyes and skin.
Hygiene measures
Remove soiled or soaked clothing immediately. Follow the usual good standards of
occupational hygiene. Store work clothing separately. Use skin protective
preparation as preventive skin protection.
Respiratory protection
not required on normal handling
Hand protection
nitrile rubber gloves (minimal thickness 0.33 mm), Break through time > 10 min (EN 374)
butyl rubber gloves (minimal thickness 0.7 mm), Break through time > 30 min (EN 374)
In practice, due to variable exposure conditions, this information can only be an aid
to orientation for the selection of a suitable chemical protection glove. In particular,
this information does not substitute suitability tests by the end user.
Splash protection
neoprene gloves
nitrile rubber gloves
General information
Gloves should be replaced regularly, especially after extended contact with the
product. For each work-place a suitable glove type has to be selected.
Eye protection
tightly fitting goggles
Skin and body protection
On handling of larger quantities: face mask, chemical-resistant boots and apron

Stability and reactivity

10.1. Reactivity
see section 10.2.
10.2. Chemical Stability
No decomposition if stored and applied as directed.
Depolymerization begins at 200 °C
10.3. Possibility of hazardous reactions
Polymerization with heat evolution may occur in the presence of radical forming substances (e.g. peroxides), reducing
substances, and/or heavy metal ions.
10.4. Conditions to avoid
High temperature.
10.5. Incompatible materials
Free radical initiators.
Reducing agents.
Tertiary amines.
Heavy metals.
peroxides
oxidizing agents
Mineral acids.
10.6. Hazardous decomposition products
None when used as directed.
Under conditions of thermal decomposition: Methacrylates

Disposal considerations

13.1. Waste treatment methods
Product
Waste is non-hazardous. It should be disposed of in accordance with the
regulations after consultation of the competent local authorities and the disposal
company in a suitable and licensed facility.

Uncleaned packaging
Contaminated packaging should be emptied optimally and after appropriate
professional cleansing may be taken for reuse. Packaging that cannot be cleaned
should be disposed of professionally. Uncontaminated packaging may be taken for
recycling.

Code of waste EWC
13 02 05
waste engine, gear and lubricating oils - mineral-based non-chlorinated engine,
gear and lubricating oils
Always check the given waste codes according to the actual conditions of
manufacturing, formulation or use in your facilities.