Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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First-aid measures

General advice: Take off all contaminated clothing immediately. If feeling unwell seek medical advice.
Inhalation: Remove to fresh air. Seek medical advice immediately.
Skin contact: Wash off with plenty of water and soap immediately, seek medical advice if necessary.
Eye contact: With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes. Consult a physician immediately.
Ingestion: Do not induce vomiting and seek medical advice immediately.

Fire-fighting measures

Suitable extinguishing media: CO2, dry powder, foam, water spray
Specific hazards during fire fighting: In case of fire cool endangered containers with water. Hazardous fumes in fires, specific to the product: nitrogen oxides (NOx), isocyanate-containing vapours. Under certain fire conditions, traces of other toxic products may occur.
Protective equipment for fire-fighting: In case of fire: wear a self contained respiratory apparatus.

Accidental release measures

Personal precautions: Use personal protective equipment. Ensure adequate ventilation.
Environmental Precautions: Should not be released into the environment.
Methods for cleaning or taking up: Pick up mechanically with a suitable material and collect in a suitable container. Protect against water.
Suitable binder: sand (for damming up), acid binder, universal absorbent, sawdust.

Handling and storage

Advice on safe handling: Open the containers with caution.
Avoid contact with skin and eyes.
Protect from moisture.
If possible, use material transfer/filling, metering and blending plants that are closed, or
provide for local suction devices.
Fire and explosion protection: Normal measures for preventive fire protection.

Transport information

Land transport (ADR/RID)

UN number:
2290
Shippingopen allclose all
Class:
6.1
Classification code:
T1
Packaging group:
III
Labels:
6
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
2290
Proper shipping name and description:
Isophorone diisocyanate
Chemical name:
CYCLOHEXANE,5-ISOCYANATO-1-(ISOCYANATOMETHYL)-1,3,3-TRIMETHYL-
Language:
English
Class:
6.1
Classification code:
T1
Packaging group:
III
Labels:
6
Remarksopen allclose all

Marine transport (IMDG)

UN number:
2290
Proper shipping name and description:
Isophorone diisocyanate
Chemical name:
CYCLOHEXANE,5-ISOCYANATO-1-(ISOCYANATOMETHYL)-1,3,3-TRIMETHYL-
Class:
6.1
Packaging group:
III
EmS code:
F-A, S-A
Labels:
6
Remarks
Clear of living quarters.

Air transport ICAO/IATA

UN number:
2290
Proper shipping name and description:
Isophorone diisocyanate
Chemical name:
CYCLOHEXANE,5-ISOCYANATO-1-(ISOCYANATOMETHYL)-1,3,3-TRIMETHYL-
Class:
6.1
Packaging group:
III
Labels:
6
Remarks
ERG-Code 6L
SpecialProvisionsopen allclose all

Exposure controls / personal protection

European and/or national OEL: Germany. TRGS 900, Limit Values in the Ambient Air at the Workplace TRGS 900 01 2006 AGW: 0,005 ppm//0,046 mg/m3
Advice on system design: If possible, use material transfer/filling, metering and blending plants that are closed, or provide for local suction devices.
Respiratory Protection: Use respiratory equipment with suitable filter (combined filter A2-P2) or wear a self contained respiratory apparatus
Persons suffering from hypersensitivity of the respiratory tract and skin (asthma, chronic bronch are advised to avoid contact with and handling of this product.
Hand protection:
A)
Type of material Fluorinated rubber (FPM)
Material thickness 0,4 mm
Breakthrough time > 480 min

B)
Type of material Fluorinated rubber (Vitoject)
Material thickness 0,7 mm
Breakthrough time > 120 min
Test method DIN EN 374

C)
Type of material butyl-rubber
Material thickness 0,5 mm
Breakthrough time > 480 min
Test method DIN EN 374

D)
Type of material Polyvinyl chloride (PVC)
Material thickness 0,5 mm
Breakthrough time > 480 min
Test method DIN EN 374

Eye protection: Close-fitting protective goggles (e.g. closed goggles)
Body protection: Suitable protective clothing - Use disposable clothing if appropriate.
Industrial hygiene: Do not inhale vapours / aerosols. Avoid contact with skin and eyes. Remove immediately all contaminated clothing.
Use disposable clothing if appropriate.
When using do not eat, drink or smoke.

Stability and reactivity

Decomposition products: isocyanate-containing vapours
Thermal decomposition: Decomposition starts at approx. 260 °C
Hazardous reactions: Reacts violently with amines (exothermic). Exothermic reaction with acids, alkalis, powerful oxidants, alcohols. Reacts with water, whereby carbon dioxide is produced; pressure may build up in closed containers (danger of bursting).

Disposal considerations

With respect to local regulations, e.g. dispose of to suitable waste incineration plant.
No waste key number as per the European Waste Types List can be
assigned to this product, since such classification is based on the (as
yet undetermined) use to which the product is put by the consumer.
The waste key number must be determined as per the European Waste Types
List (decision on EU Waste Types List 2000/532/EC) in cooperation with
the disposal firm / producing firm / official authority.