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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
auto-flammability
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2005
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: GLP missing, but test similar to national standard (VDI 2263)

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2001
Report date:
2001

Materials and methods

Test guideline
Qualifier:
equivalent or similar to guideline
Guideline:
other: national standard (VDI 2263)
Principles of method if other than guideline:
Testing in Grewer oven (small wire cage with a volume of 8 cm3)

Test material

Constituent 1
Chemical structure
Reference substance name:
3-hydroxy-N-(o-tolyl)-4-[(2,4,5-trichlorophenyl)azo]naphthalene-2-carboxamide
EC Number:
229-440-3
EC Name:
3-hydroxy-N-(o-tolyl)-4-[(2,4,5-trichlorophenyl)azo]naphthalene-2-carboxamide
Cas Number:
6535-46-2
Molecular formula:
C24H16Cl3N3O2
IUPAC Name:
3-hydroxy-N-(2-methylphenyl)-4-[(2,4,5-trichlorophenyl)diazenyl]-2-naphthamide
Test material form:
solid: nanoform, no surface treatment

Results and discussion

Auto-ignition temperature (liquids / gases)open allclose all
Auto-ignition temperature:
> 420 °C
Atm. press.:
ca. 1 013 hPa
Remarks on result:
other:
Auto-ignition temperature:
>= 270 °C
Atm. press.:
ca. 1 013 hPa
Remarks on result:
other:
Relative self-ignition temperature (solids)open allclose all
Relative self-ignition temperature:
> 420 °C
Remarks on result:
other:
Remarks:
at atm. press. of ca.1013.0 hPa
Relative self-ignition temperature:
>= 270 °C
Remarks on result:
other:
Remarks:
at atm. press. of ca.1013.0 hPa

Any other information on results incl. tables

With the substance

1. as delivered, a self-heating was not detected until 420°C. Above the melting point the test item melted and flew out of the wire basket without showing an oxidising reaction.

2. in mixture with kieselguhr (1:1) a first reaction was detected at 270°C which was intensified from 300°C to a maximum temperature of 600°C. The beginning of the reaction at 270°C corresponds to the exothermal reaction in the thermal stability test (closed glass crucibles).

Applicant's summary and conclusion