Distillates (petroleum), steam-cracked, C5-12 fraction

GHS

General Information

Implementation:

EU

Type of classification:

self-classification

Remarks:

Sub-Group 4a_Flam. Liq. 2 - High Aromatic Cyclic Diolefins, High Indene and non-Benzene Aromatics

This section describes the self-classification of the Resin Oils and Cyclic Dienes category (LOA CAT L) - Sub-group 4 (High Aromatic Cyclic Olefins diolefins and alkanes - Indene content (≤70% w/w)).

The classification is derived from the substances: Indene, Indan, 2 -Methylstyrene, 1,2,4 -Trimethyllbenzene, 1,3,5 -Trimethylbenzene, Naphthalene, Styrene, DCPD, Phenol.

The analytical data for the Resin Oils and Cyclic Dienes category (LOA CAT L) show that there is a clear grouping of structures, substances, and concentrations within the category which are relatively consistent, and which are helpful to identify substances which will have similar biological activity. Reviewing the data there appear to be the following subgroups within the category members and which suggests the subgroups as follow:

-Sub-group 1 - High Bicyclic olefin content with low to medium aromatics content and non-benzene aromatics

-Sub-group 2 - Intermediate Bicyclic olefin content, <15% indene and non-benzene aromatics

-Sub-group 3 - Moderate High Bicyclic olefin content (≤ 25%), high styrene content (>15% w/w) and non-benzene aromatics

-Sub-group 4 - High Aromatic Cyclic Olefins diolefins and alkanes - Indene content (≤70% w/w) and non-benzene aromatics

-Sub-group 5 - High Bicyclic olefin content with low to medium aromatics content and benzene aromatics

-Sub-group 6 - High Aromatic Cyclic Olefins diolefins and alkanes - Indene content (≤70% w/w) and benzene aromatics

Each of the sub-groups were duplicated to accommodate different aquatic classifications.

Related composition

Related composition:

Boundary Composition & SIP

Classification

Physical hazards

Explosives

Reason for no classification:

data conclusive but not sufficient for classification

Flammable gases and chemically unstable gases

Reason for no classification:

data conclusive but not sufficient for classification

Aerosols

Reason for no classification:

data conclusive but not sufficient for classification

Reason for no classification:

hazard class not assessed

Oxidising gases

Reason for no classification:

data conclusive but not sufficient for classification

Gases under pressure

Reason for no classification:

data conclusive but not sufficient for classification

Flammable liquids

Hazard category:

Flam. Liquid 2

Hazard statement:

H225: Highly flammable liquid and vapour.

Flammable solids

Reason for no classification:

data conclusive but not sufficient for classification

Self-reactive substances and mixtures

Reason for no classification:

data conclusive but not sufficient for classification

Pyrophoric liquids

Reason for no classification:

data conclusive but not sufficient for classification

Pyrophoric solids

Reason for no classification:

data conclusive but not sufficient for classification

Self-heating substances and mixtures

Reason for no classification:

data conclusive but not sufficient for classification

Substances and mixtures which in contact with water emit flammable gases

Reason for no classification:

data conclusive but not sufficient for classification

Oxidising liquids

Reason for no classification:

data conclusive but not sufficient for classification

Oxidising solids

Reason for no classification:

data conclusive but not sufficient for classification

Organic peroxides

Reason for no classification:

data conclusive but not sufficient for classification

Corrosive to metals

Reason for no classification:

data conclusive but not sufficient for classification

Desensitized explosives

Reason for no classification:

data conclusive but not sufficient for classification

Health hazards

Acute toxicity - oral

Hazard category:

Acute Tox. 4

Hazard statement:

H302: Harmful if swallowed.

Acute toxicity - dermal

Reason for no classification:

data conclusive but not sufficient for classification

Acute toxicity - inhalation

Hazard category:

Acute Tox. 4

Hazard statement:

H332: Harmful if inhaled.

Skin corrosion / irritation

Hazard category:

Skin Corr. 1B

Hazard statement:

H314: Causes severe skin burns and eye damage.

Serious eye damage / eye irritation

Hazard category:

Eye Irrit. 2

Hazard statement:

H319: Causes serious eye irritation.

Respiratory sensitisation

Reason for no classification:

data conclusive but not sufficient for classification

Skin sensitisation

Reason for no classification:

data conclusive but not sufficient for classification

Aspiration hazard

Hazard category:

Asp. Tox. 1

Hazard statement:

H304: May be fatal if swallowed and enters airways.

Reproductive toxicity

Hazard category:

Repr. 2

Hazard statement:

H361: Suspected of damaging fertility or the unborn child <state specific effect if known> <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

Effects on or via lactation

Reason for no classification:

data conclusive but not sufficient for classification

Germ cell mutagenicity

Hazard category:

Muta. 2

Hazard statement:

H341: Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

Carcinogenicity

Hazard category:

Carc. 2

Hazard statement:

H351: Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routs of exposure cause the hazard>.

Route of exposure:

inhalation

oral

1. Specific target organ toxicity - single (STOT-SE)

Hazard category:

STOT Single Exp. 3

Hazard statement:

H335: May cause respiratory irritation.

Affected organs:

other: Respiratory system, lungs

Route of exposure:

inhalation

1. Specific target organ toxicity - repeated (STOT-RE)

Hazard category:

STOT Rep. Exp. 1

Hazard statement:

H372: Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

Affected organs:

other: hearing organs

Route of exposure:

inhalation

Environmental hazards

Hazardous to the aquatic environment (acute / short-term)

Reason for no classification:

data conclusive but not sufficient for classification

Hazardous to the aquatic environment (long-term)

Hazard category:

Aquatic Chronic 2

Hazard statement:

H411: Toxic to aquatic life with long lasting effects.

Hazardous to the ozone layer

Reason for no classification:

data lacking

Labelling

Signal word:

Danger

Hazard pictogram

GHS02: flame

GHS05: corrosion

GHS07: exclamation mark

GHS08: health hazard

GHS09: environment

Hazard statements

H225: Highly flammable liquid and vapour.

H302: Harmful if swallowed.

H332: Harmful if inhaled.

H314: Causes severe skin burns and eye damage.

H319: Causes serious eye irritation.

H341: Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

H351: Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routs of exposure cause the hazard>.

H361d: Suspected of damaging the unborn child.

H335: May cause respiratory irritation.

H372: Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

H304: May be fatal if swallowed and enters airways.

H411: Toxic to aquatic life with long lasting effects.

Precautionary statements

P201: Obtain special instructions before use.

P202: Do not handle until all safety precautions have been read and understood.

P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P240: Ground and bond container and receiving equipment.

P241: Use explosion-proof [electrical/ventilating/lighting/...] equipment.

P242: Use non-sparking tools.

P243: Take actions to pevent static discharges.

P260: Do not breathe dust/fume/gas/mist/vapours/spray.

Manufacturer/supplier or the competent authority to specify applicable conditions.

P261: Avoid breathing dust/fume/gas/mist/vapours/spray.

P264: Wash ... thoroughly after handling.

P270: Do not eat, drink or smoke when using this product.

P271: Use only outdoors or in a well-ventilated area.

P273: Avoid release to the environment.

- if this is not the intended use

P280: Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

P301+P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor/…

P301+P312: IF SWALLOWED: Call a POISON CENTER/doctor/... if you feel unwell.

P301+P330+P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].

P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P308+P313: IF exposed or concerned: Get medical advice/attention.

P310: Immediately call a POISON CENTER/doctor/…

P312: Call a POISON CENTER/doctor/.../if you feel unwell.

P314: Get medical advice/attention if you feel unwell.

P321: Specific treatment (see ... on this label).

P330: Rinse mouth.

P331: Do NOT induce vomiting.

P337+P313: If eye irritation persists: Get medical advice/attention.

P363: Wash contaminated clothing before reuse.

P370+P378: In case of fire: Use... to extinguish.

P391: Collect spillage.

P403+P233: Store in a well-ventilated place. Keep container tightly closed.

P403+P235: Store in a well-ventilated place. Keep cool.

P405: Store locked up.

P501: Dispose of contents/container to ...