Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Description of key information

Because the substance is a strong acid (pKa -4.9) it is considered to be corrosive to the skin and eyes.

Key value for chemical safety assessment

Skin irritation / corrosion

Endpoint conclusion
Endpoint conclusion:
no study available

Eye irritation

Endpoint conclusion
Endpoint conclusion:
no study available

Respiratory irritation

Endpoint conclusion
Endpoint conclusion:
no study available

Additional information

Justification for classification or non-classification

According to Annex I of the EU Classification, Labeling and Packaging of Substances and Mixtures (CLP) Regulation (EC) No. 1272/2008 and according to Chapter 3.2.2 of the Guidance on the Application of the CLP Criteria (November 2012), Skin Corr. 1A should be applied when classification is based upon consideration of pH alone. Since the substance is a strong acid (pKa -4.9) and no additional experimental results are available, HBF4 needs to be classified as Corrosive Cat. 1A, H314 (Causes severe skin burns and eye damage).

Armonised classification of HBF4 is Corrosive Cat. 1B, H314. However, due to classification based on pH, this substance should be classified as Corrosive Cat. 1A, H314