Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

Currently viewing:

Administrative data

First-aid measures

Eye contact: Holding the eyelids apart, flush eyes promptly with copious flowing water for at least 20 minutes. Get medical attention immediately.
Skin contact: Remove contaminated clothing. Wash skin thoroughly with mild soap and plenty of water for at least 15 minutes. Wash clothing before re-use. Get medical attention if irritation occurs.
Inhalation: In case of inhalation, remove person to fresh air. Keep him quiet and warm. Apply artificial respiration if necessary and get medical
attention immediately.
Ingestion: If swallowed, wash mouth thoroughly with plenty of water. Get medical attention immediately.

************************************************************************
NOTE: Never give an unconscious person anything to drink.
************************************************************************

Notes to the physician: Treat symptomatically and supportively. No specific antidote.

Fire-fighting measures

Suitable extinguishing media: Material is not combustible. Use extinguishing media appropriate to surrounding fire conditions.
Fire fighting procedure: Fire fighters should wear full protective clothing and self-contained breathing apparatus (SCBA). Contain runoff to prevent entry into water or drainage systems.
Unusual fire and explosion hazards: When heated to decomposition, may release poisonous and corrosive fumes of Carbon Dioxide, Carbon Monoxide and Phosphorus Oxides.

Accidental release measures

Personal precautions: Wear appropriate safety clothing and eye/face protection.
Methods for cleaning up: Soak up with sand or other suitable absorbant and dispose of as solid waste. Collect in suitable and properly labeled containers. Ventilate area and wash spill site after material pickup is complete.
Environmental precautions: Prevent product from entering drains, ditches and rivers.

Handling and storage

Handling: Avoid bodily contact. Keep containers tightly closed.
Storage: Store in a dry, cool, well-ventilated area away from incompatible materials. Crystallizes at temperatures below 4.4°C (40°F). Maximum recommended storage temperature of 65°C (149°F).

Transport information

Land transport (ADR/RID)

UN number:
3082
Proper shipping name and description:
Proper shipping name: Environmentally hazardous substance, liquid, n.o.s (triphenyl phosphate, tert-butylated triphenyl phosphate mixtures containing 10% to 48% triphenyl phosphates)
Chemical name:
triphenyl phosphate, tert-butylated triphenyl phosphate mixtures containing 10% to 48% triphenyl phosphates
Language:
English
Class:
9 - Miscellaneous Dangerous Substances and articles
Classification code:
M6
Packaging group:
III
Labels:
9
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3082
Proper shipping name and description:
Proper shipping name: Environmentally hazardous substance, liquid, n.o.s (triphenyl phosphate, tert-butylated triphenyl phosphate mixtures containing 10% to 48% triphenyl phosphates)
Chemical name:
triphenyl phosphate, tert-butylated triphenyl phosphate mixtures containing 10% to 48% triphenyl phosphates
Language:
English
Class:
9 - Miscellaneous Dangerous Substances and articles
Classification code:
M6
Packaging group:
III
Labels:
9
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3082
Proper shipping name and description:
Proper shipping name: Environmentally hazardous substance, liquid, n.o.s (triphenyl phosphate, tert-butylated triphenyl phosphate mixtures containing 10% to 48% triphenyl phosphates)
Chemical name:
triphenyl phosphate, tert-butylated triphenyl phosphate mixtures containing 10% to 48% triphenyl phosphates
Class:
9 - Miscellaneous Dangerous Substances and articles
Packaging group:
M6
EmS code:
F-A S-F
Labels:
9
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3082
Proper shipping name and description:
Proper shipping name: Environmentally hazardous substance, liquid , n.o.s (triphenyl phosphate, tert-butylated triphenyl phosphate mixtures containing 10% to 48% triphenyl phosphates)
Chemical name:
triphenyl phosphate, tert-butylated triphenyl phosphate mixtures containing 10% to 48% triphenyl phosphates
Class:
9
Packaging group:
III
Labels:
9
Remarksopen allclose all

Additional transport information

Additional transport information
DOT

Proper shipping name: Environmentally hazardous substance, liquid , n.o.s
(triphenyl phosphate, tert-butylated triphenyl phosphate mixtures containing 10% to
48% triphenyl phosphates)
Class: 9 - Miscellaneous Hazardous Material
Label: 9
Packing Group: III
Not regulated for surface and air transport in non-bulk (<119 gallons) packagings.
(contains triphenyl phosphate which is a Marine Pollutant per 49CFR 172.101
Appendix B)

Exposure controls / personal protection

Exposure Limits :
Components ACGIH-TLV Data OSHA (PEL) Data
t-Butylphenyl diphenyl phosphate (56803-37-3) Not determined Not determined
Bis(t-butylphenyl)phenyl phosphate (65652-41-7) Not determined Not determined
Tri(t-butylphenyl) phosphate (78-33-1) Not determined Not determined
Triphenyl phosphate (115-86-6) 3 mg/m³ 3 mg/m³

Ventilation requirements: Ventilation must be sufficient to maintain atmospheric concentration below recommended exposure limit.

Personal protective equipment:
- Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment.
- Hand protection Protective gloves
- Eye protection Chemical safety goggles
- Skin and body protection Body covering clothes and boots

Hygiene measures: Safety shower and eye bath should be provided. Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking.

Stability and reactivity

Stability: Stable under normal conditions.
Materials to avoid: Strong oxidizers, strong acids and strong alkalis. It hydrolyzes slowly at normal temperatures in acidic or alkaline aqueous solutions.
Conditions to avoid: Heating above decomposition temperature.
Hazardous decomposition products: Carbon dioxide and carbon monoxide, Phosphorus oxides.
Hazardous polymerization: Not expected to occur.

Disposal considerations

Waste disposa:l Dispose of in a safe manner in accordance with local/national regulations.
Disposal of Packaging: Dispose of in a safe manner in accordance with local/national regulations.