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EC number: 211-063-0 | CAS number: 628-96-6
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Eye irritation
Administrative data
- Endpoint:
- eye irritation: in vivo
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- other: The HPVIS rating for this study is “Excellent” and it is selected as a “Key Study”.
Data source
Reference
- Reference Type:
- other company data
- Title:
- Unnamed
- Year:
- 1 985
Materials and methods
Test guideline
- Qualifier:
- equivalent or similar to guideline
- Guideline:
- OECD Guideline 405 (Acute Eye Irritation / Corrosion)
- Deviations:
- not specified
- Principles of method if other than guideline:
- Instillation into conjunctival sac of one eye from glass syringe. The eyes (cornea, iris and conjunctiva) were examined immediately pre-treatment. For treatment, the lower lid was gently pulled away from the eye. 0.1 mL of undiluted NG was then placed in the sac thus formed. The eyelids were then gently held together briefly ensure adequate distribution. The contra lateral eye served as the untreated control. One minute post-treatment, the eyelids of the treated eyes of three rabbits were everted and rinsed with 300 mL of water over a period of three minutes. The treated eye areas of all six rabbits were examined at 1 h, 24 h, 48 h, 72 h and 7 days post-treatment.
- GLP compliance:
- yes
- Remarks:
- Complied with FDA GLP regulations of 6/20/79, proposed TSCA GLP regulations of 5/9/79, and proposed FIFRA GLP regulations of 4/18/80.
Test material
- Reference substance name:
- Glycerol trinitrate
- EC Number:
- 200-240-8
- EC Name:
- Glycerol trinitrate
- Cas Number:
- 55-63-0
- Molecular formula:
- C3H5N3O9
- IUPAC Name:
- propane-1,2,3-triyl trinitrate
Constituent 1
- Specific details on test material used for the study:
- The test material was neat NG, isolated from an ethanol solution immediately prior to testing (it is unsafe to transport the undiluted material). Isolation was by a chemical engineer from sponsor's nearby NG plant who was familiar with chemistry, physical properties and handling of NG. The ethanol solution was from commercial production (usually 99+ per cent pure). An analysis was not supplied.
Test animals / tissue source
- Species:
- rabbit
- Strain:
- New Zealand White
- Details on test animals or tissues and environmental conditions:
- TEST TYPE: Single dose (acute) Eye Irritation
SEX: 6 male rabbits
Test system
- Vehicle:
- unchanged (no vehicle)
- Controls:
- no
- Duration of treatment / exposure:
- single dose administration
- Observation period (in vivo):
- Rabbits were observed 1, 24, 48, 72 hours and 7 days post-treatment
- Number of animals or in vitro replicates:
- 6 (3 administered treatment without washing, 3 administered treatment with washing)
- Details on study design:
- Instillation into conjunctival sac of one eye from glass syringe. The eyes (cornea, iris and conjunctiva) were examined immediately pre-treatment. For treatment, the lower lid was gently pulled away from the eye. 0.1 mL of undiluted NG was then placed in the sac thus formed. The eyelids were then gently held together briefly ensure adequate distribution. The contra lateral eye served as the untreated control. One minute post-treatment, the eyelids of the treated eyes of three rabbits were everted and rinsed with 300 mL of water over a period of three minutes. The treated eye areas of all six rabbits were examined at 1 h, 24 h, 48 h, 72 h and 7 days post-treatment.
Results and discussion
In vivo
Resultsopen allclose all
- Irritation parameter:
- conjunctivae score
- Basis:
- animal: unwashed eye (1 of 3)
- Time point:
- other: 1 hour
- Score:
- 1
- Max. score:
- 1
- Reversibility:
- fully reversible within: 24 hours
- Irritation parameter:
- conjunctivae score
- Basis:
- animal: unwashed eye (2 of 3)
- Time point:
- other: 1 hour
- Score:
- 1
- Max. score:
- 1
- Reversibility:
- fully reversible within: 24 hours
- Irritation parameter:
- conjunctivae score
- Basis:
- other: washed eye (1 of 3)
- Time point:
- other: 1 hour
- Score:
- 1
- Max. score:
- 1
- Reversibility:
- fully reversible within: 24 hours
- Irritation parameter:
- conjunctivae score
- Basis:
- animal: washed eye (2 of 3)
- Time point:
- other: 1 hour
- Score:
- 1
- Max. score:
- 1
- Reversibility:
- fully reversible within: 24 hours
- Irritation parameter:
- conjunctivae score
- Basis:
- animal: washed eye (3 of 3)
- Time point:
- other: 1 hour
- Score:
- 1
- Max. score:
- 1
- Reversibility:
- fully reversible within: 24 hours
- Irritation parameter:
- chemosis score
- Basis:
- animal: washed eye (1 of 3)
- Time point:
- other: 1 hour
- Score:
- 1
- Max. score:
- 1
- Reversibility:
- fully reversible within: 24 hours
- Irritation parameter:
- conjunctivae score
- Remarks:
- conjuctival redness
- Basis:
- animal: washed eye (1 of 3)
- Time point:
- other: 1 hour
- Score:
- 1
- Max. score:
- 1
- Reversibility:
- fully reversible within: 24 hours
- Irritation parameter:
- cornea opacity score
- Basis:
- animal #1
- Remarks:
- washed and unwashed eye
- Time point:
- 24/48/72 h
- Score:
- 0
- Max. score:
- 0
- Reversibility:
- other: All rabbit eyes were normal when examined 24/48/72 hours and 7 days post treatment.
- Remarks on result:
- no indication of irritation
- Irritation parameter:
- cornea opacity score
- Basis:
- animal #2
- Remarks:
- washed and unwashed eye
- Time point:
- 24/48/72 h
- Score:
- 0
- Max. score:
- 0
- Reversibility:
- other: All rabbit eyes were normal when examined 24/48/72 hours and 7 days post treatment.
- Remarks on result:
- no indication of irritation
- Irritation parameter:
- cornea opacity score
- Basis:
- animal #3
- Remarks:
- washed and unwashed eye
- Time point:
- 24/48/72 h
- Score:
- 0
- Max. score:
- 0
- Reversibility:
- other: All rabbit eyes were normal when examined 24/48/72 hours and 7 days post treatment.
- Remarks on result:
- no indication of irritation
- Irritation parameter:
- iris score
- Basis:
- animal #1
- Remarks:
- washed and unwashed eye
- Time point:
- 24/48/72 h
- Score:
- 0
- Max. score:
- 0
- Reversibility:
- other: All rabbit eyes were normal when examined 24/48/72 hours and 7 days post treatment.
- Remarks on result:
- no indication of irritation
- Irritation parameter:
- iris score
- Basis:
- animal #2
- Remarks:
- washed and unwashed eye
- Time point:
- 24/48/72 h
- Score:
- 0
- Max. score:
- 0
- Reversibility:
- other: All rabbit eyes were normal when examined 24/48/72 hours and 7 days post treatment.
- Remarks on result:
- no indication of irritation
- Irritation parameter:
- iris score
- Basis:
- animal #3
- Remarks:
- washed and unwashed eye
- Time point:
- 24/48/72 h
- Score:
- 0
- Max. score:
- 0
- Reversibility:
- other: All rabbit eyes were normal when examined 24/48/72 hours and 7 days post treatment.
- Remarks on result:
- no indication of irritation
- Irritation parameter:
- conjunctivae score
- Remarks:
- conjunctival redness
- Basis:
- animal #1
- Remarks:
- washed and unwashed eye
- Time point:
- 24/48/72 h
- Score:
- 0
- Max. score:
- 0
- Reversibility:
- other: All rabbit eyes were normal when examined 24/48/72 hours and 7 days post treatment.
- Remarks on result:
- no indication of irritation
- Irritation parameter:
- conjunctivae score
- Remarks:
- conjunctival redness
- Basis:
- animal #2
- Remarks:
- washed and unwashed eye
- Time point:
- 24/48/72 h
- Score:
- 0
- Max. score:
- 0
- Reversibility:
- other: All rabbit eyes were normal when examined 24/48/72 hours and 7 days post treatment.
- Remarks on result:
- no indication of irritation
- Irritation parameter:
- conjunctivae score
- Remarks:
- conjunctival redness
- Basis:
- animal #3
- Remarks:
- washed and unwashed eye
- Time point:
- 24/48/72 h
- Score:
- 0
- Max. score:
- 0
- Reversibility:
- other: All rabbit eyes were normal when examined 24/48/72 hours and 7 days post treatment.
- Remarks on result:
- no indication of irritation
- Irritation parameter:
- chemosis score
- Basis:
- animal #1
- Remarks:
- washed and unwashed eye
- Time point:
- 24/48/72 h
- Score:
- 0
- Max. score:
- 0
- Reversibility:
- other: All rabbit eyes were normal when examined 24/48/72 hours and 7 days post treatment.
- Remarks on result:
- no indication of irritation
- Irritation parameter:
- chemosis score
- Basis:
- animal #2
- Remarks:
- washed and unwashed eye
- Time point:
- 24/48/72 h
- Score:
- 0
- Max. score:
- 0
- Reversibility:
- other: All rabbit eyes were normal when examined 24/48/72 hours and 7 days post treatment.
- Remarks on result:
- no indication of irritation
- Irritation parameter:
- chemosis score
- Basis:
- animal #3
- Remarks:
- washed and unwashed eye
- Time point:
- 24/48/72 h
- Score:
- 0
- Max. score:
- 0
- Reversibility:
- other: All rabbit eyes were normal when examined 24/48/72 hours and 7 days post treatment.
- Remarks on result:
- no indication of irritation
Any other information on results incl. tables
There was no miosis, mydriasis, other ocular effects or evidence of systemic effects in any of the rabbits treated. All rabbit eyes were normal when examined at all other post-treatment times.
Applicant's summary and conclusion
- Interpretation of results:
- other: not irritating
- Executive summary:
The only effects observed were at one hour post-dosing. They were: Draize rating "1" conjunctival discharge in the treated eyes of 2/3 rabbits whose eyes were not washed and in 3/3 rabbits whose eyes were washed. Rating "1" conjunctival chemosis was seen in 1/3 rabbits whose eyes were washed, and conjunctival redness was seen in another of the rabbits whose eye was washed after treatment. There was no miosis, mydriasis, other ocular effects or evidence of systemic effects in any of the rabbits treated. All rabbit eyes were normal when examined at all other post-treatment times.
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