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Guidance on Safe Use

Guidance on Safe Use

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First-aid measures

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. Get medical attention

Eyes: Flush with water while holding eyelids open for at least 15 minutes. Seek medical attention
immediately.

Skin: Remove contaminated clothing. Flush area with large amounts of water. Use soap. Seek
medical attention. Delayed effects may occur.

Ingestion: Get medical attention immediately. Do not induce vomiting unless directed by medical
personnel. Never give anything by mouth to an unconscious person

Fire-fighting measures

Recommended extinguishing agent: Use appropriate media for underlying cause of fire. Use carbon dioxide, dry chemical, or water spray.

Hazardous Combustion Products: Formation of toxic gases is possible during heating or fire. May include oxides of carbon and
nitrogen.

Fire / Explosion Hazards: Strong dust explosion characteristic. Very high sensitivity of a dust cloud to ignition, based on
minimum ignition energy.

Protective equipment: Fire fighters must wear full protective clothing and
breathing apparatus.

Accidental release measures

Personnel involved in clean-up should wear appropriate personal protective equipment. Minimize exposure.

Place waste in an appropriately labeled, sealed container for disposal. Care should be taken to avoid environmental release.

Measures for Cleaning / Collecting: Avoid use of a filtered vacuum to clean spills of dry solids, due to the potential for elec
trostatic discharge and the strong dust explosion potential and very high sensitivity to ignition.

In the environment, this substance is expected to remain in water or migrate through the soil to
groundwater and persist. Toxic to aquatic organisms. May cause long term adverse effects in
the aquatic environment. Releases to the environment should be avoided

Additional Consideration for Large Spills: Non-essential personnel should be evacuated from affected area. Report emergency situations immediately. Clean up operations should only be undertaken by trained personnel

Handling and storage

Storage Conditions: Keep in tightly closed containers away from heat and light. Store in a cool, dry, well-ventilated area.
All conductive elements of the system that contact the dry substance should be properly bonded and grounded and equipped
with proper explosion relief or suppression systems. This material should not be flowed through nonconductive ducts or pipes
because of the potential for electrostatic discharge ignition. Restricting the use of high resistivity materials, such as plastics,
should be considered.

Avoid open handling. Minimize dust generation. Use local exhaust ventilation or perform work under fume
hood/fume cupboard. Avoid inhalation and contact with skin, eye, and clothing.

When handling, use appropriate personal protective equipment. Wash hands and any exposed skin after removal of PPE. Releases to the environment
should be avoided.

Review and implement appropriate technical and procedural waste water and waste disposal measures to prevent occupational exposure
or environmental releases. Potential points of process emissions of this material to the atmosphere should be controlled with
dust collectors, HEPA filtration systems or other equivalent controls.

Transport information

Land transport (ADR/RID)

UN number:
UN 3077
Proper shipping name and description:
Environmentally Hazardous Substance, Solid, n.o.s
Chemical name:
2-Benzylidene Isobutyrylacetanilide)
Language:
English
Class:
9
Classification code:
UN3077
Packaging group:
III
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN 3077
Proper shipping name and description:
Environmentally Hazardous Substance, Solid, n.o.s
Chemical name:
2-Benzylidene Isobutyrylacetanilide)
Language:
English
Class:
9
Classification code:
UN 3077
Packaging group:
III
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN 3077
Proper shipping name and description:
Environmentally Hazardous Substance, Solid, n.o.s
Chemical name:
2-Benzylidene Isobutyrylacetanilide)
Class:
9
Packaging group:
III
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN 3077
Proper shipping name and description:
Environmentally Hazardous Substance, Solid, n.o.s
Chemical name:
2-Benzylidene Isobutyrylacetanilide)
Class:
9
Packaging group:
III
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Exposure Controls

Engineering Controls: Engineering controls should be used as the primary means to control exposures. Use process
containment, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits.

Personal Protective Equipment:

Refer to applicable national standards and regulations in the selection and use of personal protective equipment (PPE).
Hands: Wear impervious gloves to prevent skin contact.
Eyes: Wear safety glasses as minimum protection.
Skin: Wear impervious protective clothing to prevent skin contact - consider use of disposable
clothing where appropriate. Consider use of EN 1073-1: 96.
Respiratory protection: If the applicable Occupational Exposure Limit (OEL) is exceeded, wear an appropriate
respirator with a protection factor sufficient to control exposures to below the OEL.

Stability and reactivity

Reactivity: No data available
Chemical Stability: No data available
Possibility of Hazardous Reactions
Oxidizing Properties: Non-oxidizing
Conditions to Avoid: Avoid direct sunlight, conditions that might generate heat, and sources of ignition. Keep away
from heat and other sources of ignition, including electrostatic discharge.
Incompatible Materials: As a precautionary measure, keep away from strong oxidizers
Hazardous Decomposition

Disposal considerations

Dispose of waste in accordance with all applicable laws and regulations. Member State
specific and Community specific provisions must be considered. Considering the relevant
known environmental and human health hazards of the material, review and implement
appropriate technical and procedural waste water and waste disposal measures to prevent
occupational exposure and environmental release. It is recommended that waste minimization
be practiced. The best available technology should be utilized to prevent environmental
releases. This may include destructive techniques for waste and wastewater.