Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
phototransformation in water
Type of information:
other: BUA report
Adequacy of study:
other information
Reliability:
other: BUA report
Rationale for reliability incl. deficiencies:
other: BUA report

Data source

Referenceopen allclose all

Reference Type:
other: BUA Report
Title:
Unnamed
Year:
1991
Reference Type:
other: BUA Report
Title:
Unnamed
Year:
1994
Reference Type:
other company data
Title:
Unnamed
Year:
1992

Materials and methods

Study type:
other: BUA report
Principles of method if other than guideline:
BUA report
GLP compliance:
not specified

Test material

Constituent 1
Chemical structure
Reference substance name:
2-chloroaniline
EC Number:
202-426-4
EC Name:
2-chloroaniline
Cas Number:
95-51-2
Molecular formula:
C6H6ClN
IUPAC Name:
2-chloroaniline

Study design

Analytical method:
other: BUA report
Light source:
other: BUA report
Sensitiser (for indirect photolysis)
Type of sensitiser:
other: BUA report

Results and discussion

Any other information on results incl. tables

BUA report:

The UV spectra of o- amd m-chloroaniline (> 295 nm) indicated that direct photodegradation of both substances is possible. The half-life for the direct phototransformation of o-chloroaniline was estimated to be 2 -3 h. Thus, the direct phototransformation was assessed to contribute markedly to the elimination of o-chloroaniline in the environment. Additionally, for p-chloroaniline a transformation half-life of 3 hours and a photomineralization half-life of 23 days have been determined in a test system simulating field conditions with water from an estuary in daylight during winter 3 cm below the surface. The half -life for direct photodegradation of m-chloroaniline in water is 1.3 hours in light at 313 nm.

There is no measurment on indirect photodegradation for o-chloroaniline available. But for aniline the half-life of indirect photodegradation in water with carbonate radicals in concentrations wich are found in the environment is 11 hours. The half-life of m-chloroaniline should be the same order of magnitude.

Applicant's summary and conclusion