Registration Dossier

Administrative data

First-aid measures

General advice:
Pay attention to self-protection.
Remove victims from hazardous area. Immediately remove soiled or soaked clothing and remove it to a
safe distance. Keep victim warm, in a stabilizedposition and covered.
Do not leave victims unattended.
If the casualty is unconscious: Place the victim in the recovery position.

Inhalation:
Inhalation is possible if aerosols, mists, dusts, or smoke form.
Move victims into fresh air.
With labored breathing: Provide with oxygen. Consult a doctor.
If the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician
immediately.

Skin contact:
Wash off affected area immediately with plenty of water for at least 15 minutes.
With liposoluble substances, products, or preparations, continue decontamination with polyethylene glycol
400 after initial rinsing with water and then wash with water and soap.
If symptoms persist, consult a physician for treatment.

Eye contact:
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
Consult an ophthalmologist immediately if the symptoms persist.
When dealing with caustic substances, notify emergency physician immediately (key words: burns in eye).

Ingestion:
Rinse out mouth.
Immediately give large quantities of water to drink.
Consult a physician immediately.
When dealing with caustic substances, notify emergency physician immediately.

Notes to physician:
In case of substances with high water solubility, inhalation of vapors, aerosols, mists, and smoke from
caustic substances, products, and preparations, as well as caustic gases, results in irritations up to
formation of necrosis in the upper respiratory tract.
The initial focus is on the local action: signs of irritation of the respiratory tract such as coughing, burning
behind the sternum, tears, burning in the eyes or nose.
There is a fundamental risk of acute toxic pulmonary edema!
In case of substances with low water solubility, only slight local irritations may appear at first, but after
several hours of latency without symptoms, may develop into increasingly labored breathing and cyanosis
as a result of a delayed pulmonary edema.
There is a danger of underestimating the severity of the intoxication!

Fire-fighting measures

Suitable extinguishing media:
Water spray, foam, CO2, dry powder.

Extinguishing media which must not be used for safety reasons:
high volume water jet

Specific hazards during fire fighting:
In case of fire cool endangered containers with water.
Hazardous fumes in fires, specific to the product:
hydrochloric acid
Under certain fire conditions, traces of other toxic products may occur.

Special protective equipment for fire-fighters:
In case of fire: Have ready/wear respiratory protection equipment.
Wear suitable protective clothing.

Further information:
Water used to extinguish fire should not enter drainage systems, soil, or stretches of water Ensure there
are sufficient retaining facilities for water used to extinguish fire. Contaminated fire-extinguishing water
must be disposed of in accordance with the regulations issued by the appropriate local authorities.
Fire residues should be disposed of in accordance with the regulations.

Accidental release measures

Personal precautions
Keep away from sources of ignition - No smoking.
Ensure adequate ventilation.
Do not allow to enter drains (danger of explosion).
Wear personal protective equipment; see section 8.

Environmental precautions
Prevent product from entering drains.

Methods for cleaning up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).

Handling and storage

Handling
Safe handling advice:
If possible, use material transfer/filling, metering and blending plants that are closed, or provide for local suction devices.
Wear personal protective equipment; see section 8.
Ensure adequate ventilation.

Advice on protection against fire and explosion
Take precautionary measures against static charges, keep away from sources of ignition.
Explosion protection equipment required.

Storage
Requirements for storage areas and containers:
Keep container tightly closed.
Keep in a well-ventilated place.
Keep in a cool place.
Protect from moisture.
For transport, storage and tank installations only use suitable materials.
Suitable materials: drums with polyethylene lining, polyethylene, enamel
Unsuitable materials: iron, light metals

German storage class
3A - Flammable Liquids

Transport information

Land transport (ADR/RID)

UN number:
2924
Proper shipping name and description:
FLAMMABLE LIQUID, CORROSIVE, N.O.S. (Crotylchloride)

Chemical name:
Crotylchloride
Language:
English
Class:
3
Classification code:
FC
Packaging group:
II
Labels:
3 (8)
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
2924
Proper shipping name and description:
FLAMMABLE LIQUID, CORROSIVE, N.O.S. (Crotylchloride)

Chemical name:
Crotylchloride
Language:
English
Class:
3
Classification code:
FC
Packaging group:
II
Labels:
3, 8
Remarksopen allclose all

Marine transport (IMDG)

UN number:
2924
Proper shipping name and description:
FLAMMABLE LIQUID, CORROSIVE, N.O.S. (Crotylchloride)
Chemical name:
Crotylchloride
Class:
3 (8)
Packaging group:
II
EmS code:
F-E, S-C
Labels:
3, 8
Remarks
Loading instructions/Remarks:
IMDG: Clear of living quarters.
IMDG: IMDG Code segregation group 10 - Liquid halogenated hydrocarbons

Air transport ICAO/IATA

UN number:
2924
Proper shipping name and description:
Flammable liquid, corrosive, n.o.s. (Crotylchloride)

Chemical name:
Crotylchloride
Class:
3 (8)
Packaging group:
II
Labels:
3, 8
Remarks
Loading instructions/Remarks:
IATA_C: ERG-Code 3CH
IATA_P: ERG-Code 3CH

Additional transport information

Additional transport information
Combination traffic :
Labelling of containers / shipping units following main product run as per sea or air transport
regulations.

Exposure controls / personal protection

Components with workplace control parameters:

Engineering measures:
Provide good ventilation or extraction.

Personal protective equipment
Respiratory protection:
In case of dusts/vapours/aerosols being formed or if the limit values like TLV are exceeded:
use respiratory equipment with suitable filter or wear a self contained respiratory apparatus
Note time limit for wearing respiratory protective equipment.

Hand protection
Recommendation:
suitable protective gloves

Glove material nitrile rubber
Material thickness 0,85 mm
Break through time > 480 min
Method DIN EN 374

Eye protection:
protective goggles or face protection

Skin and body protection:
suitable protective clothing
Use disposable clothing if appropriate.
during fire-fighting
full protective suit

Hygiene measures:
Do not inhale vapours / aerosols.
Avoid contact with skin and eyes.
Use disposable clothing if appropriate.
No eating, drinking, smoking, or snuffing tobacco at work. Wash face and/or hands before break and end of
work.
Wash off immediately in the event of contact with the skin (rinsing agent: glycol polyethylene 400), rinse off
afterwards with copious amounts of water.
Take off clothing and shoes contaminated with product. Clean before reuse.

Protective measures:
The personal protective equipment used must meet the requirements of directive 89/686/EEC and
amendments (CE certification).

Stability and reactivity

Hazardous decomposition products hydrogen chloride

Thermal decomposition Decomposition at elevated temperatures.
Comparatively stable at ambient temperature.

Disposal considerations

Product:
With respect to local regulations, e.g. dispose of to suitable waste incineration plant.
No waste key number as per the European Waste Types List can be assigned to this product, since such
classification is based on the (as yet undetermined) use to which the product is put by the consumer.
The waste key number must be determined as per the European Waste Types List (decision on EU Waste
Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.