Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

INHALATION :Remove to fresh air, treat symptomatically. Get immediate medical attention. SKIN CONTACT :Immediately flush with plenty of water for at least 15 minutes. Get immediate medical attention. Contaminated clothing, shoes, and leather goods must be discarded or cleaned before re-use. EYE CONTACT :Immediately flush eye with water for at least 15 minutes while holding eyelids open. PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Get immediate medical attention. INGESTION :Do not induce vomiting without medical advice. If conscious, washout mouth and give water to drink. If reflexive vomiting occurs, rinse mouth and repeat administration of water. Get immediate medical attention. NOTE TO PHYSICIAN :Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.

Fire-fighting measures

EXTINGUISHING MEDIA :Foam, Carbon dioxide, Dry powder, Other extinguishing agent suitable for Class B fires, For large fires, use water spray or fog, thoroughly drenching the burning material. Water mist may be used to cool closed containers. FIRE AND EXPLOSION HAZARD :Combustible Liquid; may form combustible mixtures at or above the flash point. Empty product containers may contain product residue. Do not pressurize, cut, heat, weld, or expose containers to flame or other sources of ignition. May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire conditions. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING :In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.

Accidental release measures

PERSONAL PRECAUTIONS :Restrict access to area as appropriate until clean-up operations are complete. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is safe to do so. Ventilate spill area if possible. Remove sources of ignition. Ensure clean-up is conducted by trained personnel only. Do not touch spilled material. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Notify appropriate government, occupational health and safety and environmental authorities. Keep people away from and upwind of spill/leak. METHODS FOR CLEANING UP :SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated surfaces with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations). ENVIRONMENTAL PRECAUTIONS :Do not contaminate surface water. If drains, streams, soil or sewers become contaminated, notify local authority.

Handling and storage

HANDLING :Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Do not breathe vapors/gases/dust. Keep the containers closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Ensure all containers are labeled. Do not use, store, spill or pour near heat, sparks or open flame. Do not mix with acids. STORAGE CONDITIONS :Store in suitable labeled containers. Store the containers tightly closed. Store away from heat and sources of ignition. Have appropriate fire extinguishers available in and near the storage area. Connections must be grounded to avoid electrical charges. SUITABLE CONSTRUCTION MATERIAL :Mild steel, Stainless Steel 316L, HDPE (high density polyethylene), PVC, Polyvinylidene difluoride, Polypropylene, PTFE, CPVC (rigid), EPDM, Kalrez, Plasite 7122, Plasite 4300 UNSUITABLE CONSTRUCTION MATERIAL :Brass, Neoprene, Viton, Buna-N, Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested prior to use. SPECIFIC USE(S) :HYDROGEN SULFIDE SCAVENGER For specific dosages and customized applications please contact your representative.

Transport information

Land transport (ADR/RID)

UN number:
UN2735
Proper shipping name and description:
AMINES, LIQUID, CORROSIVE N.O.S.
Chemical name:
Hexahydro-1,3,5-trimethyl-1,3,5-triazine
Language:
English
Class:
Class 8
Classification code:
C7
Packaging group:
PG III
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN2735
Proper shipping name and description:
AMINES, LIQUID, CORROSIVE N.O.S.
Chemical name:
Hexahydro-1,3,5-trimethyl-1,3,5-triazine
Language:
English
Class:
Class 8
Classification code:
C7
Packaging group:
PG III
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN2735
Proper shipping name and description:
AMINES, LIQUID, CORROSIVE N.O.S.
Chemical name:
Hexahydro-1,3,5-trimethyl-1,3,5-triazine
Class:
Class 8
Packaging group:
PG III
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN2735
Proper shipping name and description:
AMINES, LIQUID, CORROSIVE N.O.S.
Chemical name:
Hexahydro-1,3,5-trimethyl-1,3,5-triazine
Class:
Class 8
Packaging group:
PG III
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

ENGINEERING MEASURES :The use of local exhaust ventilation is recommended to control emissions near the source. Laboratory samples should be handled in a fumehood. Provide mechanical ventilation of confined spaces. PERSONAL PROTECTION GENERAL ADVICE :The use and choice of personal protection equipment is related to the hazard of the product, the workplace and the way the product is handled. In general, we recommend as a minimum precaution that safety glasses with side-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an area where this product is handled should at least wear safety glasses with side-shields. The applicable European standard can be found in EN 166.RESPIRATORY PROTECTION :Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air supplied breathing apparatus is recommended. A suitable filter material depends on the amount and type of chemicals being handled. Consider the use of filter type: A-B-E-K The applicable European standard can be found in EN 140, EN 137, EN 143 and EN 14387. In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection. HAND PROTECTION :When handling this product, the use of chemical gauntlets is recommended. The choice of work glove depends on work conditions and what chemicals are handled, but we have positive experience under light handling conditions using gloves made from PVC Gloves should be replaced immediately if signs of degradation are observed. Breakthrough time not determined as preparation, consult PPE manufacturers. The applicable European standard can be found in EN 374. SKIN PROTECTION :When handling this product, the use of a chemical resistant suit and rubber boots is recommended. The applicable European standard can be found in EN ISO 20345. EYE PROTECTION :Wear a face shield with chemical splash goggles, unless wearing a full-face respirator. The applicable European standard can be found in EN 166. HYGIENE RECOMMENDATIONS :Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep a safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. Always wash thoroughly after handling chemicals. When handling this product never eat, drink or smoke.

Stability and reactivity

STABILITY :Stable under normal conditions. HAZARDOUS POLYMERIZATION :Hazardous polymerization will not occur. CONDITIONS TO AVOID :Heat and sources of ignition including static discharges. MATERIALS TO AVOID :Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors., Contact with strong acids (e.g. sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic) may generate heat, splattering or boiling and toxic vapors.HAZARDOUS DECOMPOSITION PRODUCTS :Under fire conditions:Oxides of carbon, Oxides of nitrogen

Disposal considerations

If this preparation becomes a waste, the final user must define and assign the appropriate European Waste Catalogue code. Use only authorized contractors. Ensure compliance with EC, national and local regulations.Dispose of wastes in an approved incinerator or waste treatment/disposal site, in accordance with all applicable regulations. Do not dispose of wastes in local sewer or with normal garbage. This product is ashless and can be burned directly in appropriate equipment. Any chemical waste is a potential environmental pollutant and is NOT suitable for disposal via ground, municipal sewers, drains, natural streams or rivers. Empty drums should be taken for recycling, recovery, or disposal through a suitably qualified or licensed contractor. EUROPE WASTE CODE :16 03 05*- OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Organic wastes containing dangerous substances. If this product is used in any further processes, the final user must redefine and assign the most appropriate European Waste Catalogue Code.