reaction product of diphenylmethanediisocyanate, toluenediisocyanate ( reaction mass of isomers: 65 % 2,4- and 35 % 2,6-diisocyanate), octylamine, oleylamine and 4-ethoxyaniline (molar ratio 3.88:1:6.38:0.47:2.91)

Guidance on Safe Use

First-aid measures

General instructions:

Remove victim from contaminated area. Lay down quiet in recovery position. In any case show the MSDS to the physician.

Inhalation:

Remove to fresh air. Lay down quiet in recovery position. If breathing is difficult, give artificial respiration with breathing bag. Get medical attention.

Skin contact:

Remove contaminated clothing and shoes. Wash skin with plenty of water and soap. If irritation persists, get medical attention.

Eye contact:

Rinse immediately with plenty of water for at least 15 min. Separate eyelids with fingers. Get medical attention immediately.

Ingestion:

Do not induce vomiting. Seek medical advice immediately.

Fire-fighting measures

Protective equipment for fire fighters:

Protective suit with self-contained breathing apparatus.

Suitable extinguishing media:

Water spray; foam; carbon dioxide; dry extinguishing media;

Extinguishing media not suitable for safety reasons:

Water jet;

Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases:

In case of fire, formation of carbon monoxide, carbon dioxide, nitrogen oxides, hydrocyanic acid, toxic pyrolysis products.

Other information:

Collect extinguishing water separately; it must not reach the sewage or ground waters. Extinguishing water and combustion residues have to be collected separately and treated as special waste in accordance with local regulations. Cool endangered containers with water spray and remove out of danger area, if possible.

Accidental release measures

Personal precautions:

Keep off any unprotected persons. Wear personal protective equipment (chemical protective gloves, goggles, working protection). Avoid contact with skin and eyes and breathing of dust.

Environmental precautions:

Avoid penetration into water ways, sewage and soil. In case of release into the environment, inform the local competent authorities.

Clean-up of spills:

Take up by mechanical means. Store in closed containers and dispose in accordance with federal, state, and local regulations. Clean up spill area with water and treat as special waste.

Handling and storage

Handling:

Handling only with appropriate protective equipment in well ventilated areas. Avoid contact with skin and eyes. Take off contaminated clothing and shoes. Wash thoroughly after handling. Do not eat, drink, or smoke during work.

Storage:

Keep containers tightly closed and dry in a cool, well-ventilated place. Prevent for liquid-proof floors in storage rooms. Do not store together with food, feedstuff and beverages. Protect from heat and direct sunlight.

Transport information

Shipping

SpecialProvisions

Shipping

Remarks

Marine transport (UN RTDG/IMDG)

Shipping

Remarks

Shipping

Remarks

Additional transport information

Additional information

Special provisions / remarks / other:

Not classified for transportation.

Exposure controls / personal protection

Exposure controls:

The product contains no ingredients which have to be monitored and controlled for working place exposure limits.

General protective and hygiene measures:

Handling only in appropriate working areas with sufficient ventilation/exhaustion at the workplace. Handling only with appropriate protective equipment. Avoid contact with skin and eyes and breathing of dust. Use skin protection cream.

Remove contaminated clothing and shoes immediately and wash before reuse. Do not eat, drink, or smoke during work. Wash hands thoroughly before breaks and after work.

Protective equipment: Not necessary in general. Precautionary recommendations:

Respiratory protection:

Not necessary in general. In case of dust formation, use dust mask or particle filter P2.

Hand protection:

Butyl rubber/nitrile rubber gloves with a minimum thickness of 0.2 mm and a penetration time > 480 min. Information on suitability for the applied medium should be requested at the glove manufacturer.

Eye protection:

Safety glasses with side protection. Goggles. Face shield.

Body protection:

Protective clothing and shoes.

Stability and reactivity

Materials to avoid/dangerous reactions:

No special materials to be avoid. No dangerous reactions known if stored and handled according to intended working/storage instructions.

Thermal decomposition/hazardous decomposition products:

No thermal decomposition if stored and handled properly. No hazardous decomposition products on intended use. In case of fire, formation of carbon oxides, nitrogen oxides, toxic pyrolysis products as hydrocyanic acid possible.

Disposal considerations

Product:

Recommendations: Should be disposed in a special waste landfill or special waste incineraton plant in accordance with state, local and federal regulations. The European Waste Catalogue Number must be allocated in accordance with the local competent authorities and local waste management enterprises.

Packaging:

Recommendations: Packagings should be completely emptied and recycled. Packagings which could not be cleansed should be disposed off as product waste.