Registration Dossier
Registration Dossier
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EC number: 212-783-8 | CAS number: 868-85-9
Phototransformation in soil
Administrative data
- Endpoint:
- phototransformation in soil
- Type of information:
- experimental study
- Adequacy of study:
- other information
- Reliability:
- 4 (not assignable)
- Rationale for reliability incl. deficiencies:
- other: Original reference is not yet available. (migrated reliability was 3; rationale for reliability was: Significant methodological deficiencies)
Data source
Reference
- Reference Type:
- publication
- Title:
- No information
- Author:
- Kerzhentsev M, Guillard C, Herrmann J-M, Pichat P (1996) Photocatalytic pollutant removal in water at room temperature: case study of the total degradation of the insecticide fenitrothion (phosphorothioic acid O,O-dimethyl-O-(3-methyl-4-nitro-phenyl) ester). Catalysis Today 27, 215-220
Materials and methods
- Principles of method if other than guideline:
- Method: other (measured): GC-MS
- GLP compliance:
- not specified
Test material
- Reference substance name:
- Reference substance 001
- Details on test material:
- Test type: other: 2.5 mg TiO2 (mainly anatase) suspended in water
IUCLID4 Test substance: other TS: Fenitrothion, 99.3 % purity
Constituent 1
Study design
- Light source:
- other: Philips HPK 125 W UV
- Light spectrum: wavelength in nm:
- > 340
- Details on test conditions:
- Sensitiser (for indirect photolysis): water with additives
Sensitiser concentration: 2.5 mg/l
Results and discussion
- Transformation products:
- yes
Any other information on results incl. tables
RS-Freetext:
Fenitrothion was completely degraded within 50 minutes. For the degradation of DMP, no specific compound was measured. However, the formation of phosphate was observed, and the intermediate occurrance of formate.
The mass spectrum of DMP is not depicted as was done with other spectra in the publication. It is (incompletely) reported to have peaks (m/z) at 79, 80, 47, 29, 95, 66, 109, and 110. Intensities were not reported.
It was stated that DMP occured as an intermediate of complete fenitrothion mineralization.
Degradation in % (for indirect photolysis): > 70 after 150 minute(s)
Applicant's summary and conclusion
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