Registration Dossier
Registration Dossier
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EC number: 244-334-7 | CAS number: 21324-40-3
Auto flammability
Administrative data
- Endpoint:
- relative self-ignition temperature (solids)
- Type of information:
- other: Statement
- Adequacy of study:
- supporting study
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 008
- Report date:
- 2008
Materials and methods
Test guideline
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.16 (Relative Self-Ignition Temperature for Solids)
- Deviations:
- no
- GLP compliance:
- yes (incl. QA statement)
Test material
- Reference substance name:
- Lithium hexafluorophosphate(1-)
- EC Number:
- 244-334-7
- EC Name:
- Lithium hexafluorophosphate(1-)
- Cas Number:
- 21324-40-3
- Molecular formula:
- F6P.Li
- IUPAC Name:
- lithium(1+) hexafluoro-λ⁵-phosphanuide
- Details on test material:
- - Name of test material (as cited in study report): LiPF6
- Substance type: inorganic
- Physical state: white powder
- Analytical purity: > 99.9%
- Lot/batch No.: P07102202
- Expiration date of the lot/batch: 31 December 2008
- Stability under storage conditions: stable
- Storage condition of test material: At room temperature protected from light under nitrogen
Constituent 1
Results and discussion
Relative self-ignition temperature (solids)
- Remarks on result:
- not determinable
- Remarks:
- see "any other information on results" section
Any other information on results incl. tables
LiPF6 hydrolyses readily in contact with water or moisture. With this reaction, the formation of a white fume (most likely hydrogen fluoride (HF)) occurred. Due to release of HF, the thermocouple of the system is not expected to give reliable temperature readings. Furthermore according to the safety phrases, the oven should be placed in a fumehood, which was technically not possible.
In conclusion, it was not possible to perform the study on the self-ignition temperature of the test substance.
Applicant's summary and conclusion
- Conclusions:
- It was not possible to perform the study on the self-ignition temperature of the test substance.
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