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The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

First-aid measures

1.Preamble1.1. Indications on Safety Data Sheets (SDS) for the professional user about guidance on safe use of petroleum products, in all its aspects, should take into account that applicable legislation and general accepted practices for the management of industrial routine activities or emergencies, as well as company operating procedures, already compose a background which indicates which general actions are necessary/mandatory, advisable or unadvisable in such cases. An extensive recapitulation of all this background information will not necessarily add information value to a SDS, and may actually decrease the readability of the document, especially in an emergency. Therefore the indications meant for actual inclusion in SDSs can be focused (although not necessarily limited) to:-  Product specific issues (i.e. special hazards or characteristics)-  Key Actions (or group of actions) that are applicable in the specific case1.2. The actual level of detail of information and its phrasing in individual SDSs may reflect local or national conventions or requirements, or company policies, but without infringing on the consistency with the information submitted hereunder. Also, more stringent national or local legal requirements or conventions will take precedence over the guidance provided in this document2. Warning before intervention2.1. Hydrogen sulphide (H2S) can accumulate in the headspace of product storage tanks and reach potentially hazardous concentrations.3. Inhalation 3.1. Symptoms: irritation of the respiratory tract due to excess fume, mists or vapour exposure3.2. If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.3.3. If casualty is unconscious and:* Not breathing – ensure that there is no obstruction to breathing and give artificial respiration by trained personnel.  If necessary, give external cardiac massage and obtain medical assistance.* Breathing – place in the recovery position. Administer oxygen if necessary. 3.4. Obtain medical assistance if breathing remains difficult.3.5. If there is any suspicion of inhalation of H2S: - Rescuers must wear breathing apparatus, belt and safety rope, and follow rescue procedures.- Remove casualty to fresh air as quickly as possible.- Immediately begin artificial respiration if breathing has ceased.-Provision of oxygen may help.- Obtain medical advice for further treatment.4. Skin Contact4.1. Symptoms: dry skin, irritation in case of repeated or prolonged exposure. May cause burn in case of contact with product at high temperature4.2.  Remove contaminated clothing and footwear and dispose of safely.4.3. Wash affected area with soap and water.4.4. Never use gasoline, kerosene or other solvents for washing of contaminated skin.4.5.  Seek medical attention if skin irritation, swelling or redness occurs.4.6. When using high-pressure equipment, injection of product can occur. If high-pressure injuries occur, immediately seek professional medical attention. Do not wait for symptoms to develop4.7.  For minor thermal burns: Cool the burn. Hold the burned area under cold running water for at least five minutes, or until the pain subsides. However, body hypothermia must be avoided.4.8. Do not put ice on the burn; Remove non-sticking garments carefully.  DO NOT attempt to remove portions of clothing glued to burnt skin but cut round them.4.9. Seek medical attention in all cases of serious burns5. Eye Contact5.1. Symptoms: slight irritation (unspecific) . May cause burn in case of contact with product at high temperature5.2. Rinse cautiously with water for several minutes.  Remove contact lenses, if present and easy to do so.  Continue rinsing.5.3.  If irritation, blurred vision or swelling occurs and persists, obtain medical advice from a specialist.5.4. If hot product is splashed into the eye, it should be cooled immediately to dissipate heat, under cold running water.  Immediately obtain specialist medical assessment and treatment for the casualty.6. Ingestion / Aspiration6.1. Symptoms: Few or no symptoms are expected.  If any, nausea and diarrhea might occur. 6.2. Do not induce vomiting. Ask for medical assistance6.3.  Do not give anything by mouth to an unconscious person.

Fire-fighting measures

1. Product specific hazards and other issues1.1. This substance will float and can be reignited on surface water.2. Extinguishing Media - Foam (Specifically trained personnel only)- Water fog (Specifically trained personnel only)- Dry chemical powder- Carbon dioxide- Other inert gases (subject to regulations)- Sand or earth3. Unsuitable Extinguishing Media3.1. Do not use direct water jets on the burning product; they could cause splattering and spread the fire.3.2. Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam.4. Combustion Products4.1. Incomplete combustion is likely to give rise to a complex mixture of airborne solid and liquid particulates and gases, including carbon monoxide, H2S, SOx (sulfur oxides) or sulfuric acid and unidentified organic and inorganic compounds.5. Protective Equipment for Firefighters5.1. In case of a large fire or in confined or poorly ventilated spaces wear full fire resistant protective clothing and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Accidental release measures

1. General information1.1. Stop or contain leak at the source if safe to do so.  Avoid direct contact with released material.  Stay upwind. In case of large spillages, alert occupants in downwind areas.1.2. Keep non-involved personnel away from the area of spillage. Alert emergency personnel.Except in case of small spillages, the feasibility of any actions should always be assessed and advised, if possible, by a trained, competent person in charge of managing the emergency.1.3. It is recommended to eliminate all ignition sources if safe to do so (e.g. electricity, sparks, fires, flares). 1.4. When the presence of dangerous amounts of H2S around the spilled product is suspected or proved, additional or special actions may be warranted, including access restrictions, use of special protection equipment, procedures and personnel training.1.5. If required, notify relevant authorities according to all applicable regulations. 2. Personal protection equipment for emergency responders2.1. Small spillages: normal antistatic working clothes are usually adequate. Large spillages: full body suit of chemically resistant and antistatic material, if necessary heat resistant and insulated.2.2. Work gloves providing adequate chemical resistance, specifically to aromatic hydrocarbons. Note: gloves made of PVA are not water-resistant, and are not suitable for emergency use.If contact with hot product is possible or anticipated, gloves should be heat-resistant and thermally insulated.2.3. Work helmet. Antistatic non-skid safety shoes or boots, if necessary heat-resistant.2.4. Goggles or face shield, if splashes or contact with eyes is possible or anticipated.2.5. Respiratory protection: A half or full-face respirator with filter(s) for organic vapours/H2S or a Self Contained Breathing Apparatus (SCBA) can be used according to the extent of spill and predictable amount of exposure. If the situation cannot be completely assessed, or if an oxygen deficiency is possible, only SCBA’s should be used.3. Spillages onto land 3.1. Prevent product from entering sewers, rivers, waterways or other bodies of water.3.2. If necessary dike the product with dry earth, sand or similar non-combustible materials. 3.3.  Let hot product cool down naturally3.4. Large spillages may be cautiously covered with foam, if available, to limit fire risk. Do not use direct jets3.5. When inside buildings or confined spaces ensure adequate ventilation.3.6. Absorb spilled product with suitable non-combustible materials.3.7. Collect free product with suitable means. Collect recovered product and other contaminated materials in suitable containers for recycle, recovery or safe disposal.3.8. In case of soil contamination, remove contaminated soil for remediation or disposal, in accordance with local regulations.4. Spillages in water or at sea4.1.  Product less dense than water: In case of small spillages in closed waters (i.e. ports), contain product with floating barriers or other equipment.  Collect spilled product by absorbing with specific floating absorbents4.2. If possible, large spillages in open waters should be contained with floating barriers or other mechanical means.  If this is not possible, control the spreading of the spillage, and collect the product by skimming or other suitable mechanical means.4.3. The use of dispersants should be advised by an expert, and, if required, approved by local authorities.4.4. Collect recovered product and other contaminated materials in suitable tanks or containers for recycle, recovery or safe disposal.4.5.   Product which is denser than water will sink to the bottom, and usually no intervention will be feasible. If possible, collect the product and contaminated materials with mechanical means, and store/dispose of according to relevant regulations. In special situations (to be assessed on case-by case basis, according to expert judgement and local conditions), excavations of trenches on the bottom to collect the product, or burying the product with sand may be a feasible option.5. Additional information5.1. Note: recommended measures are based on the most likely spillage scenarios for this material; however, local conditions (wind, air temperature, wave/current direction and speed) may significantly influence the choice of appropriate actions.  For this reason, local experts should be consulted when necessary.  Local regulations may also prescribe or limit actions to be taken.5.2. Concentration of H2S in tank headspaces may reach hazardous values, especially in case of prolonged storage. This situation is especially relevant for those operations which involve direct exposure to the vapours in the tank.5.3. Spillages of limited amounts of products, especially in the open air when vapours will be usually quickly dispersed, are dynamic situations, which are unlikely to entail exposure to dangerous concentrations.  As H2S has a density greater than ambient air, a possible exception may regard the build-up of dangerous concentrations in specific spots, like trenches, depressions or confined spaces.  In all these circumstances, however, the correct actions should be assessed on a case-by-case basis.

Handling and storage

1. General Information1.1. Obtain special instructions before use 1.2. Ensure that all relevant regulations regarding handling and storage facilities of flammable products are followed.1.3. A specific assessment of inhalation risks from the presence of H2S in tank headspaces, confined spaces, product residue, tank waste and waste water, and unintentional releases must be made to help determine controls appropriate to local circumstances.1.4. It is recommended to keep away from sparks/open flames/hot surfaces. – No smoking.1.5. Use and store only outdoors or in a well-ventilated area.1.6. Avoid contact with the product.1.7. Avoid release to the environment.2. Handling2.1. Take precautionary measures against static electricity.2.2. Ground/bond containers, tanks and transfer/receiving equipment.2.3. The vapour is heavier than air. Beware of accumulation in pits and confined spaces.2.4. Do not breathe fume/ mist/ vapours2.5. Avoid contact with skin. Precautions should be taken to avoid skin burns when handling hot product.2.6. Use adequate personal protective equipment as required.2.7. For more information regarding protective equipment and operational conditions see Exposure scenarios. 3. Storage3.1. Storage area layout, tank design, equipment and operating procedures must comply with the relevant European, national or local legislation.3.2. Storage installations should be designed with adequate bunds so as to prevent ground and water pollution in case of leaks or spills. 3.3. Cleaning, inspection and maintenance of internal structure of storage tanks must be done only by properly equipped and qualified personnel as defined by national, local or company regulations. 3.4. Before entering storage tanks and commencing any operation in a confined area, check the atmosphere for oxygen content, hydrogen sulphide (H2S) and flammability. 3.5. Store separately from oxidising agents.4. Recommended and Unsuitable Materials for Storage4.1. Recommended materials: For containers, or container linings use mild steel, stainless steel.4.2. Unsuitable materials: some synthetic materials may be unsuitable for containers or container linings depending on the material specification and intended use. Compatibility should be checked with the manufacturer 5. Container AdviceIf the product is supplied in containers:5.1. Keep only in the original container or in a suitable container for this kind of product.5.2. Store in a well-ventilated place. 5.3. Keep containers tightly closed and properly labelled.5.4. Empty containers may contain combustible product residues. Do not weld, solder, drill, cut or incinerate empty containers, unless they have been properly cleaned.6. Hygiene measures6.1. Ensure that proper housekeeping measures are in place.6.2. Contaminated materials should not be allowed to accumulate in the workplaces and should never be kept inside the pockets.6.3. Keep away from food and beverages.6.4. Do not eat, drink or smoke while using this product.6.5. Wash the hands thoroughly after handling.6.6. Change contaminated clothes at the end of working shift.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
UN 3256. See Additional transport information 01.UN 3257. See Additional transport information 05.UN 3082. See Additional transport information 07.
Shipping information
Proper shipping name and description:
ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S. See Additional transport information 01.ELEVATED TEMPERATURE LQUID, N.O.S. See Additional transport information 05.ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. See Additional transport information 07.
Chemical name:
Heavy fuel oil. See Additional transport information 02.Heavy fuel oil. See Additional transport information 02.Heavy fuel oil. See Additional transport information 02.
Language:
English
Labels:
3 Flammable liquids. Environmentally hazardous substance mark. See Additional transport information 03.9 Miscellaneous dangerous substances and articles. Environmentally hazardous substance mark. See Additional transport information 03. Mark for elevated temperature substances. See Additional transport information 06. 9 Miscellaneous dangerous substances and articles. Environmentally hazardous substance mark. See Additional transport information 03.
Special provisions / remarks
Remarks:
Hazard identification number (HIN) 30. UK Emergency action code (EAC) 2Y. Tunnel restriction code: D/E (Note: ADR requirement only). Hazard identification number (HIN) 99. UK Emergency action code (EAC) 2Y. Tunnel restriction code: D (Note: ADR requirement only). Hazard identification number (HIN) 90. UK Emergency action code (EAC) 3Z. Tunnel restriction code: E (Note: ADR requirement only).

Inland waterway transport (UN RTDG/ADN(R))

UN number:
UN 3256. See Additional transport information 01, 09.UN 3257. See Additional transport information 05, 09.UN 3082. See Additional transport information 08, 09.ID 9001. See Additional transport information 08, 09.ID 9003. See Additional transport information 08, 09.
Shipping information
Proper shipping name and description:
ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S. See Additional transport information 01.ELEVATED TEMPERATURE LQUID, N.O.S. See Additional transport information 05.ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. See Additional transport information 08.SUBSTANCES WITH A FLASH-POINT ABOVE 60°C handed over for carriage at a TEMPERATURE WITHIN A RANGE OF 15K BELOW THEIR FLASH-POINT OR WITH A FLASH-POINT >60°C, HEATED TO LESS THAN 15K FROM THE FLASH-POINT. or SUBSTANCES WITH A FLASH-PONT ABOVE 60°C BUT NOT MORE THAN 100°C. See Additional transport information 08.SUBSTANCES WITH A FLASH-PONT ABOVE 60°C BUT NOT MORE THAN 100°C or SUBSTANCES WHERE 60°C
Chemical name:
Heavy fuel oil. See Additional transport information 02.Heavy fuel oil. See Additional transport information 02.Heavy fuel oil. See Additional transport information 02.None. See Additional transport information 02.None. See Additional transport information 02
Language:
English
Labels:
3 Flammable liquids. Environmentally hazardous substance mark. See Additional transport information 03.9 Miscellaneous dangerous substances and articles. Environmentally hazardous substance mark. See Additional transport information 03. Mark for elevated temperature substances. See Additional transport information 06. 9 Miscellaneous dangerous substances and articles . Environmentally hazardous substance mark. See Additional transport information 08.3 Flammable liquids. Environmentally hazardous substance mark. See Additional transport information 08.9 Miscellaneous dangerous substances and articles . Environmentally hazardous substance mark. See Additional transport information 08.
Special provisions / remarks
Remarks:
None.None.Substance transported by inland waterway in a tank vessel may have a different classification to substance being transported in packaging by inland waterway. . See Additional transport information 08Substance transported by inland waterway in a tank vessel may have a different classification to substance being transported in packaging by inland waterway. See Additional transport information 08Substance transported by inland waterway in a tank vessel may have a different classification to substance being transported in packaging by inland waterway. See Additional transport information 08

Marine transport (UN RTDG/IMDG)

UN number:
UN 3256. See Additional transport information 01.UN 3257. See Additional transport information 05UN 3082. See Additional transport information 07.
Shipping information
Proper shipping name and description:
ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S. See Additional transport information 01.ELEVATED TEMPERATURE LQUID, N.O.S. See Additional transport information 05.ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. See Additional transport information 07.
Chemical name:
Heavy fuel oil. See Additional transport information 02.Heavy fuel oil. See Additional transport information 02.Heavy fuel oil. See Additional transport information 02.
Labels:
3 Flammable liquids. Marine pollutant mark. See Additional transport information 03.9 Miscellaneous dangerous substances and articles. Marine pollutant mark. See Additional transport information 03. Mark for elevated temperature substances. See Additional transport information 06. 9 Miscellaneous dangerous substances and articles. Environmentally hazardous substance mark. See Additional transport information 03.
Marine pollutant
Special provisions / remarks
Remarks:
None.None.None.

Air transport (UN RTDG/ICAO/IATA)

UN number:
UN 3256. See Additional transport information 01.UN 3257. See Additional transport information 05.UN 3082. See Additional transport information 07.
Shipping information
Proper shipping name and description:
ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S. See Additional transport information 01. The substance is forbidden on cargo aircraft. The substance is forbidden on passenger and cargo aircraft. See Additional transport information 04.ELEVATED TEMPERATURE LQUID, N.O.S. See Additional transport information 05. . The substance is forbidden on cargo aircraft. The substance is forbidden on passenger and cargo aircraft. See Additional transport information 04.ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. See Additional transport information 07.
Chemical name:
Heavy fuel oil. See Additional transport information 02. The substance is forbidden on cargo aircraft. The substance is forbidden on passenger and cargo aircraft. See Additional transport information 05.Heavy fuel oil. See Additional transport information 02. The substance is forbidden on cargo aircraft. The substance is forbidden on passenger and cargo aircraft. See Additional transport information 05.Heavy fuel oil. See Additional transport information 02.
Labels:
3 Flammable liquids. Environmentally hazardous substance mark. See Additional transport information 03. The substance is forbidden on cargo aircraft. The substance is forbidden on passenger and cargo aircraft. See Additional transport information 04.9 Miscellaneous dangerous substances and articles. Environmentally hazardous substance mark. See Additional transport information 03. Mark for elevated temperature substances. See Additional transport information 06. The substance is forbidden on cargo aircraft. The substance is forbidden on passenger and cargo aircraft. See Additional transport information 04.9 Miscellaneous dangerous substances and articles. Environmentally hazardous substance mark. See Additional transport information 03.
Special provisions / remarks
Remarks:
None.None.None.

Additional transport information

Additional information
Special provisions / remarks / other:
Preamble0.1The transportation of dangerous goods (by land, water or air) is a specialized professional field. Dangerous goods transport is regulated by an extensive body of recommendations, regulations, rules and agreements to ensure an adequate and harmonised level of safety for man and environment. Whereas some of these requirements have been adopted as European Union legislation (see reference), others are legally binding international treaties or sector agreements. They cover all the relevant technical aspects involved in the transport of dangerous goods (e.g. choice of equipment, labelling, documentation, packaging design, testing procedures, operating procedures etc.).0.2In addition to legal obligations discussed in the previous paragraph, Member states will also have in place detailed binding regulations governing the general conduct of transport activities, including licensing and inspection of vehicles, the authorization of drivers and other personnel, and issues relating to the rules of the road. There may also be specific national exceptions and requirements. 0.3The legal framework and its accompanying detailed provisions will specify which actions are necessary/mandatory, advisable or forbidden. Extensive repetition of this background information is not practicable in a safety data sheet, and could make the document too long and difficult to read and understand, especially in an emergency when clear, brief information is needed.0.4 The consideration of this background information enables the content of the safety data sheet to be concentrated on the identification of a product's proper shipping name and its hazard classification. Where it is relevant, other information may be added. This information will act as key for the professional for retrieving the necessary specific information in the relevant body of transport codes, rules and regulations.0.5Substances in this category may be classified differently. Factors affecting classification include composition, closed flash point, initial boiling point and aquatic toxicity. The differences are explained in additional transport information paragraphs that have been numbered. Additional transport information 01The proper shipping name UN 3256 ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S. is applied to heavy fuel oil with a flash-point above 60°C that is transported at a temperature at or above its flash point.Additional transport information 02When it is listed, special provision 274 in the dangerous goods list requires the technical name in brackets to be added to the proper shipping name. According to the UN Model Regulations the technical name shall be a recognized chemical or other name used in scientific and technical handbooks, journals and texts. Petroleum substances are identified by the full substance name or short name. It is recommended that the appropriate short name is used. The appropriate short name is Heavy fuel oil. Special provision 274 applies to UN 3082, UN 3256 and UN 3257. Special provision 274 does not apply to ID 9001 or ID 9003. Additional transport information 03The substance will require a marine pollutant mark / environmentally hazardous substance mark because it is classified as Environmentally hazardous substance - Category: Chronic 2.Additional transport information 04UN 3256 ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S. is forbidden on cargo aircraft. It is also forbidden on aircraft carrying passengers and cargo.UN 3257 ELEVATED TEMPERATURE LIQUID, N.O.S. is forbidden on cargo aircraft. It is also forbidden on aircraft carrying passengers and cargo.Additional transport information 05The proper shipping name UN 3257 ELEVATED TEMPERATURE LIQUID, N.O.S. is required for heavy fuel oil with a flash-point above 60°C that being transported at a temperature of 100°C or more, but below its flash-point.Additional transport information 06When it is listed, special provision 580 in the dangerous goods list requires the use of an elevated temperature mark for liquids transported at a temperature of 100°C or more. Special provision 580 aplies to UN 3257.Additional transport information 07The proper shipping name UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. is applied to substances with a closed flash point of greater than 60°C for transport by land (ADR/RID), marine (IMDG) and air (ICAO/IATA). UN 3082 can be used provided the substance cannot be assigned to other entries in classes 1 – 8, and provided the substance cannot be assigned to other entries in class 9.Additional transport information 08When transport is by inland waterway (ADNR) the use of UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. will apply to substances that are being transported in packages. UN 3082 can be used provided the substance cannot be assigned to other entries in classes 1 – 8, and provided the substance cannot be assigned to other entries in class 9. For transport by inland waterway in tank vessels other UN numbers may take precedence over UN 3082. UN 3082 belongs to Class 9 Miscellaneous dangerous substances and articles and Classification code M6 applies. If the substance is classified as UN 3082, an environmentally hazardous substance mark will be required because it is classified as Environmentally hazardous substance - Category: Chronic 2.For transport by inland waterway (ADNR) in bulk in a tank vessel UN 3082 can be used provided the substance does not meet the classification criteria of any other class or substance within Class 9.For transport in tank vessels, other UN numbers and proper shipping names will be required if the criteria for classification as ID 9001 or ID 9003 are met.ID 9001 SUBSTANCES WITH A FLASH-POINT ABOVE 60°C handed over for carriage at a TEMPERATURE WITHIN A RANGE of 15K BELOW THEIR FLASH-POINT OR WITH A FLASH-POINT >60°C, HEATED TO LESS THAN 15K FROM THE FLASH-POINT.ID 9001 belongs to Class 3 Flammable liquids and Classification code F3 applies. Packaging group does not apply to tank vessels. If the substance is classified as ID 9001, an environmentally hazardous substance mark will be required because the substance is classified as Environmentally hazardous substance - Category: Chronic 2.ID 9003 SUBSTANCES WITH A FLASH-PONT ABOVE 60°C BUT NOT MORE THAN 100°C or SUBSTANCES WHERE 60°C

Exposure controls / personal protection

Note: In this case the information in heading 8 is not required, according to Art. 14 (1) and (2), and Annex VI, Sect. 5.6 of the Regulation.(If applicable, substance registered as an isolated or transported intermediate). Please refer to the assessment report on Risk Management Measures in Section 13 which provides the required information on Strictly Controlled Conditions for the registration of this isolated/transported intermediate.

Stability and reactivity

Disposal considerations