Registration Dossier

Administrative data

First-aid measures

General advice:
Take off contaminated clothing and shoes immediately.
Move out of dangerous area.
Keep warm and in a quiet place.
First-aid crew: Ensure self-protection.

If inhaled
:
Provide fresh air.
Keep the victim calm and in a semi-upright position.
If symptoms persist, call a physician.

In case of skin contact
:
Wash off immediately with plenty of water for at least 15 minutes.
If symptoms persist, call a physician.
First treatment with calcium gluconate paste.

In case of eye contact
:
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Call a physician immediately.

If swallowed
:
Rinse mouth with water.
Do not induce vomiting without medical advice.
Call a physician immediately.
Symptoms of poisoning may not appear for several hours. Keep under medical supervision for at least 48 hours.
Immediately drink Calcium solution (in water desolved Calcium tablets).

Most important symptoms and effects, both acute and delayed
Symptoms
:
Symptoms of poisoning may not appear for several hours. Keep under medical supervision for at least 48 hours.

Indication of any immediate medical attention and special treatment needed
Treatment
:
Treat symptomatically.
For specialist advice physicians should contact the Poisons Information Service.
First treatment with calcium gluconate paste.
Immediately drink Calcium solution (in water desolved Calcium tablets).


Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media
: The product itself does not burn.
Use extinguishing measures that are appropriate to local cir-cumstances and the surrounding environment.

Unsuitable extinguishing media
: High volume water jet

5.2 Special hazards arising from the substance or mixture
Specific hazards during fire-fighting
: May form toxic gases on heating or in case of fire.
Hydrogen fluoride

5.3 Advice for firefighters
Special protective equipment for firefighters
: In the event of fire, wear self-contained breathing apparatus.

Further information
: Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions
: Ensure adequate ventilation.
Wear personal protective equipment.
Avoid contact with skin, eyes and clothing.
Do not breathe dust.
Keep people away from and upwind of spill/leak.
Knock down dust with water spray jet.

6.2 Environmental precautions
Environmental precautions
: Do not flush into surface water or sanitary sewer system.
Avoid subsoil penetration.

6.3 Methods and materials for containment and cleaning up
Methods for cleaning up
: Use mechanical handling equipment.
Avoid dust formation.
Pick up and transfer to properly labelled containers.
Adequate disposal

Handling and storage

7.1 Precautions for safe handling
Advice on safe handling
: Provide sufficient air exchange and/or exhaust in work rooms.
Wear personal protective equipment.
Avoid dust formation.

Advice on protection against fire and explosion
: The product is not flammable.
Normal measures for preventive fire protection.
Avoid dust formation.

7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
: Keep containers tightly closed in a dry, cool and well-ventilated place.
Protect from moisture.

Advice on common storage
: Keep in a cool, well-ventilated place away from acids.

Transport information

Shippingopen allclose all
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all

Marine transport (IMDG)

Remarksopen allclose all

Air transport ICAO/IATA

Remarks
Transport: Der innerbetriebliche Transport sollte in dichtschließenden,
vorschriftsmäßig beschrifteten und bruchsicheren Behältern
erfolgen, die gegen Verrutschen und Herabfallen gesichert
sind.

"ENGLISH"

For the in-plant transport use tightly closed, well labelled
and unbreakable containers which are safeguard against
falling.
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Stability and reactivity

10.1 Reactivity
No hazards to be specially mentioned.
10.2 Chemical stability
No decomposition if stored and applied as directed.
10.3 Possibility of hazardous reactions
Hazardous reactions
: Decomposes by reaction with strong acids.

10.4 Conditions to avoid
Conditions to avoid : reacts with acids.

10.5 Incompatible materials
Materials to avoid
: Acids

10.6 Hazardous decomposition products
Risk of decomposition.
: Decomposes by reaction with strong acids.
Hydrofluoric Acid

Thermal decomposition
: > 350 °C
To avoid thermal decomposition, do not overheat.

Disposal considerations

Waste treatment methods
Product
: Dispose of in accordance with local regulations.

Contaminated packaging
: Dispose of in accordance with local regulations.

Waste Code
: Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.