Registration Dossier

Administrative data

First-aid measures

Description of first aid measures
First aid personnel should pay attention to their own safety. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). Immediately remove contaminated clothing.

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention. Immediately administer a corticosteroid from a controlled/metered dose inhaler.

On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.

On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

On ingestion:
Do not induce vomiting. Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.


Most important symptoms and effects, both acute and delayed
Symptoms: Additional information on symptoms and effects may be included in the GHS labeling phrases available in Section 2 of the SDS and in the Toxicological assessments available in Section 11 of the SDS. Further symptoms are possible.

Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. Pulmonary odema prophylaxis. Medical monitoring for at least 24 hours.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam, carbon dioxide

Special hazards arising from the substance or mixture
nitrogen oxides, carbon oxides
If product is heated above decomposition temperature, toxic vapours will be released.

Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Avoid all sources of ignition: heat, sparks, open flame. Avoid inhalation. Avoid contact with the skin, eyes and clothing.

Environmental precautions
Do not discharge into drains/surface waters/groundwater.

Methods and material for containment and cleaning up
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr). Dispose of absorbed material in accordance with regulations.
Wear suitable protective equipment. Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Collect waste in suitable containers, which can be labeled and sealed. Incinerate or take to a special waste disposal site in accordance with local authority regulations.

Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be found in section "Exposure control/personal protection" and "Disposal considerations".

Handling and storage

Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Handle under dry inert gas. Handle in accordance with good industrial hygiene and safety practice. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.

Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.

Conditions for safe storage, including any incompatibilities
Segregate from acids and acid forming substances.
Further information on storage conditions: Keep under inert gas.

Storage stability:
Storage duration: 24 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.

Specific end use(s)
For the relevant identified use(s) listed in Section 1 of the SDS the advice mentioned in this section is to be observed.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

Control parameters

Components with occupational exposure limits
No occupational exposure limits known.

PNEC
freshwater: 0.03 mg/l
intermittent release: 0.302 mg/l
marine water: 0.003 mg/l
STP: 11.17 mg/l
sediment (freshwater): 0.144 mg/kg
sediment (marine water): 0.0144 mg/kg
soil: 0.011 mg/kg
oral (secondary poisoning):
No PNEC oral derived, as accumulation in organisms is not to be expected.
DNEL
No DNEL value available.

Exposure controls
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Combination filter for gases/vapours of organic compounds and solid and liquid particles (f.e. EN 14387 Type A-P2)

Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
fluoroelastomer (FKM) - 0.7 mm coating thickness
Suitable materials for short-term contact (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN 374)
nitrile rubber (NBR) - 0.4 mm coating thickness
butyl rubber (butyl) - 0.7 mm coating thickness
chloroprene rubber (CR) - 0.5 mm coating thickness
polyvinylchloride (PVC) - 0.7 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.

Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.

Body protection:
chemical-protection suit (f.e. according to EN 14605)

General safety and hygiene measures
Contact with eyes and skin must be avoided. Wearing of closed work clothing is required additionally to the stated personal protection equipment. Do not breathe vapour/spray. The substance was registered as a transported isolated intermediate. The manufacturer/importer has received the confirmation by the user that the substance is used under strictly controlled conditions in accordance with art. 18 of the REACH regulation (EC) No 1907/2006. Handle in accordance with good industrial hygiene and safety practice. Take off immediately all contaminated clothing. Store work clothing separately. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks).

Stability and reactivity

Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals:
Corrosive effects to metal are not anticipated. In the presence of water or moisture metal corrosion cannot be excluded.
Formation of flammable gases: Remarks: Forms no flammable gases in the presence of water.

Chemical stability
The product is stable if stored and handled as prescribed/indicated.

Possibility of hazardous reactions
Reacts with acids and strong oxidizing agents. Strong exothermic reaction. Reacts with nitrites.

Conditions to avoid
Avoid all sources of ignition: heat, sparks, open flame. See MSDS section 7 - Handling and storage.

Incompatible materials
Substances to avoid:
strong acids, strong oxidizing agents, nitrosating agents

Hazardous decomposition products
Hazardous decomposition products:
carbon oxides, nitrogen oxides, nitrous gases

Disposal considerations

Waste treatment methods

Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.

Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.