Registration Dossier

Administrative data

First-aid measures

General information:
Seek medical advice immediately
Ensure that the First Aid Personnel are aware of the product involved, and take precautions to protect themselves (e.g. wear personal protection equipment).
Remove affected person from danger area, lay him down.
Remove soiled or soaked clothing immediately
Keep warm, calm and covered up.

After inhalation:
Summon a doctor immediately.
Remove the casualty into fresh air and keep him calm.

After contact with skin:
Take for medical treatment
In case of contact with skin wash off immediately with polyethylene glycol 400, then with plenty of water

After contact with eyes:
Begin with medical treatment.
Rinse the affected eye with plenty of water, at the same time keep the unaffected eye well protected.

After ingestion :
When swallowed seek medical aid immediately and show the physician the packaging or the label of the packaging.

Advice to doctor:

Symptoms:
Headache
Disorientation
Nausea
Cyanosis (change of colour of lips and finger nails to blue gray).
Methaemoglobinaemia

Hazards:
Risk of deterioration due to consumption of alcohol.

Treatment:
Monitor blood circulation.
Keep under medical supervision for at least 48 hours.
If necessary, give oxygen.
In the event of cyanosis give vitamin C, oxygen, keep out of sun.
Against Methaemoglobin anemia: Give 300 ml Toluidine blue intravenously or 1 to 2 mg/kg Methylene blue intravenously.

Fire-fighting measures

Suitable extinguishing media :

alcohol-resistant foam
dry powder
carbon dioxide
water spray jet

Extinguishing media that must not be used for safety reasons :
Full water jet

Special hazards from the substance itself, its combustion products or from its vapours :

In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO)
Carbon dioxide (CO2)
Nitrogen oxides (NOx)
Under certain conditions of combustion traces of other toxic substances cannot be excluded

Special protective equipment for firefighting :

Do not inhale explosion and/or combustion gases
Use self-contained breathing apparatus

Further information :

Fire residues and contaminated firefighting water must be disposed of in accordance with the local regulations.

Accidental release measures

Personal precautions :
Wear personal protective equipment. Unprotected persons must be kept away.
Avoid contact with skin and eyes.
Remove persons to safety.

Environmental precautions :
Do not allow entry to drains,water courses or soil
Contain contaminated water/firefighting water
Prevent spread over a wide area (e.g. by containment or oil barriers).

Methods for cleaning up/taking up :
Pick up with liquid binding materials and if necessary fill in containers capable of being locked.
Clean contaminated floors and objects thoroughly, observing environmental regulations
When picked up, treat material as prescribed under heading "Disposal".
Dispose of absorbed material in accordance with the regulations.
Containers in which spilt substance has been collected must be adequately labelled

Handling and storage

Advice on safe handling :

This substance should be handled under strictly controlled conditions as specified in Reach regulation article 18(4). Site documentation to support
safe handling arrangements in accordance with risk-based management system should be available at each manufacturing site.
Provide good ventilation of working area (local exhaust ventilation if necessary).
Avoid formation of aerosols.
Take precautionary measures against electrostatic loading.
Observe the usual precautions for handling chemicals
Advice on protection against fire and explosion
The product is combustible.
The product vapours are heavier than air.
Vapours may form explosive mixtures with air
Keep away from sources of ignition - refrain from smoking.
Take precautionary measures against electrostatic charges - earthing necessary during loading operations.
Observe the general rules of industrial fire protection

Requirements for storage rooms and vessels :
Keep container tightly closed in a cool, well-ventilated place.
Protect from direct sunlight

Advice on storage compatibility :
Do not store or transport together with foodstuffs
Do not store together with animal feedstocks.

Transport information

Land transport (ADR/RID)

UN number:
1711
Shippingopen allclose all
Class:
6.1
Classification code:
60
Packaging group:
II
Labels:
Xylidine, liquid
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
1711
Shippingopen allclose all
Class:
6.1
Classification code:
60
Packaging group:
II
Labels:
Xylidine, flüssig
Remarksopen allclose all

Marine transport (IMDG)

UN number:
1711
Proper shipping name and description:
Xylidines, liquid
Chemical name:
2,3-dimethylaniline
Class:
6.1
Packaging group:
II
EmS code:
F-A, S-A
Labels:
Xylidine, Liquid
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
1711
Proper shipping name and description:
Xylidines, liquid
Chemical name:
2,3-dimethylaniline
Class:
6.1
Packaging group:
II
Labels:
Xylidine, Liquid
Remarksopen allclose all

Additional transport information

Additional transport information
environmental hazardous substance

Exposure controls / personal protection

This substance should be handled under strictly controlled conditions as specified in Reach regulation article 18(4). Site documentation to support safe handling arrangements in accordance with risk-based management system should be available at each manufacturing site.

General protective measures:

Do not breathe vapours, aerosols or mists.
Avoid contact with eyes and skin

Hygiene measures:

Do not eat, drink or smoke during work time.
Remove soiled or soaked clothing immediately and clean thoroughly before using again.
Garments that cannot be cleaned must be destroyed (burnt).
Keep away from foodstuffs and beverages.
Clean hands and face during work intervals and after work
Avoid contact of the substance.

Respiratory protection :

Full mask

Short term: filter apparatus, Filter A

Hand protection :

Nitrile rubber applied on knitted cotton for mechanical stress.
Because this glove is used only for mechanical protection, the minimum breakthrough time and thickness are not relevant to safety.

For short-term exposure (splash protection):

Nitrile rubber gloves.
Minimum breakthrough time / gloves :30 min
Minimum thickness / gloves0,3 mm


For long-term exposure:

Butyl rubber gloves.
Minimum breakthrough time / gloves :> 8 h
Minimum thickness / gloves0,5 mm

These types of protective gloves are offered by various manufacturers. Please note the manufacturers´ detailed statements, especially about the minimum thickness and the minimum breakthrough time. Consider also the particular working conditions under which the gloves are being used.


Eye protection :

see respiratory protection

Body protection :

Impermeable protective clothing

Stability and reactivity

Thermal decomposition : > 500 °C (Heating rate : 10 K/min)
Method : DTA

Hazardous reactions
Plastic materials can be attacked
Incompatible with acid chlorides and acid anhydrides.
Reactions with oxidising agents.
Reactions with halogens
Reactions with acids.
halogenated hydrocarbons

Hazardous decomposition products
Hazardous decomposition products:
Nitrous gases
Carbon monoxide and carbon dioxide

Disposal considerations

Product
Special waste incineration plant, after consultation with operators
Observe local authority regulations

Uncleaned packaging
Packaging that cannot be cleaned should be disposed of as product waste
For disposal local regulation is binding.