Registration Dossier
Registration Dossier
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EC number: 202-358-5 | CAS number: 94-71-3
Guidance on Safe Use
Administrative data
First-aid measures
- General advice:
Show the safety data sheet to the doctor in attendance.
First aider needs to protect himself.
Place affected clothing in a sealed bag for subsequent decontamination.
- Following inhalation:
Move to fresh air.
If breathing is difficult, give oxygen.
If symptoms persist, call a physician.
- Following skin contact:
Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
Wash immediately and thoroughly for a prolonged period (at least 15 minutes).
Consult a physician if necessary.
- Following eye contact:
Rinse with running water whilst keeping the eyes wide open (at least 15 minutes)
If eye irritation persists, consult a specialist.
- Following ingestion:
Do NOT induce vomiting.
Rinse mouth with water.
If symptoms persist, call a physician.
- Most important symptoms and effects:
No data available
Fire-fighting measures
- Suitable extinguishing media:
Water spray
Carbon dioxide (CO2)
Foam
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
- Unsuitable extinguishing media:
High volume water jet
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
- Special hazards arising from the substance or mixture:
On combustion, toxic gases are released.
Combustible solid.
Risk of dust explosion.
- Advice for fire fighter:
Special protective equipment for firefighters
Special protective equipment for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
Self-contained breathing apparatus (EN 133)
Specific fire fighting methods
Use appropriate means for fighting adjacent fires.
Evacuate personnel to safe areas.
Cool containers/tanks with water spray.
Accidental release measures
- Personal precautions, Protective equipment and emergency procedures:
Remove all sources of ignition.
Avoid contact with eyes
Do not breathe vapour.
Personal protective equipment
Safety glasses
Boots
Mark the contaminated area with signs and prevent access to unauthorized personnel.
Signal word
Ventilate the area.
- Environmental precautions:
Do not allow uncontrolled discharge of product into the environment.
Dam up.
- Methods and material for containment and cleaning up:
Recovery
Keep in properly labelled containers.
with a closing device.
Decontamination/cleaning
Wash off with plenty of water.
Disposal
Treat recovered material as described in the section "Disposal considerations".
Handling and storage
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.
Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Processor/User of the Registrant’s intermediate.
- Precautions for safe handling:
Earth the equipment.
Avoid dust formation.
Avoid exposure - obtain special instructions before use.
Persons with a history of skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used.
- Hygiene measures
- The substance/product is registered with strictly controlled conditions as defined in Article 18(4) of Regulation (EC) No. 1907/2006 (REACH Regulation) and must therefore be handled as such.
Use clean, well-maintained personal protection equipment.
Wash hands before breaks and immediately after handling the product.
When using do not eat, drink or smoke.
- Conditions for safe storage, including any incompatibilities:
Technical measures/Storage conditions
The floor of the depot should be impermeable and designed to form a water-tight basin.
Keep away from open flames, hot surfaces and sources of ignition.
Keep in a cool, well-ventilated place.
Keep away from: Strong oxidizing agents
Packaging material
Suitable material
glass
Remarks
Aluminium and its alloys.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- Not regulated
Shippingopen allclose all
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- Not regulated
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- Not regulated
Shipping information
- Proper shipping name and description:
- Not regulated
- Chemical name:
- Not regulated
- Labels:
- Not regulated
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- Not regulated
Shipping information
- Proper shipping name and description:
- Not regulated
- Chemical name:
- Not regulated
- Labels:
- Not regulated
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.
Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Processor/User of the Registrant’s intermediate.
Engineering measures :
Only process in a closed system.
Extraction to remove vapours at their source.
Ensure good ventilation of the work station.
Personal protective equipment
- Respiratory protection: Rescue type personal respiratory protection must be permanently available and easily accessible with no delay.
- Hand protection : Impermeable protective gloves.
- Eye protection : Goggles.
- Skin and body protection: Protective clothing. Safety foot-wear.
Collective emergency equipment:
Safety shower. Eye fountain.
Emergency equipment and first-aid box with instructions readily available.
Hygiene measures: Do NOT drink, eat or smoke in the workplace. Separate normal clothes from work-clothes.
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.
Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Processor/User of the Registrant’s intermediate.
1. Engineering measures
Facilities and equipment easily cleanable.
Apply technical measures to comply with the occupational exposure limits.
2. Protection measures
Selection of appropriate personal protective equipment should be based on an evaluation of the performance characteristics of the protective equipment relative to the task(s) to be performed, conditions present, duration of use, and the potential hazards and/or risks that may occur during use.
The protective equipment must be selected in accordance with current local standards and in cooperation with the supplier of the protective equipment.
The protective equipment must be selected in accordance with current CEN standards and in cooperation with the supplier of the protective equipment.
3. Hand protection
Where there is a risk of contact with hands, use appropriate gloves
Gloves must be inspected prior to use.
Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough
The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.
5. Body protection
Choose body protection according to the amount and concentration of the dangerous substance at the work place.
Remove and wash contaminated clothing.
Wear suitable protective clothing, gloves and eye/face protection.
6. Eye protection
Safety goggles
7. Respiratory protection
Use a respirator with an approved filter if a risk assessment indicates this is necessary.
8. Hygiene measures
The substance/product is registered with strictly controlled conditions as defined in Article 18(4) of Regulation (EC) No. 1907/2006 (REACH Regulation) and must therefore be handled as such.
Ensure that eyewash stations and safety showers are close to the workstation location.
Use clean, well-maintained personal protection equipment.
Wash hands before breaks and immediately after handling the product.
When using do not eat, drink or smoke.
Stability and reactivity
1. Reactivity
No hazards to be specially mentioned.
2. Chemical stability
Stable at room temperature.
3. Possibility of hazardous reactions
Hazardous polymerisation does not occur.
4. Conditions to avoid
Heat, flames and sparks.
Static electricity
Avoid dust formation.
5. Incompatible materials
Bases
Strong oxidizing agents
6. Hazardous decomposition products
On combustion or on thermal decomposition (pyrolysis) releases:
Toxic Gas
Disposal considerations
Product Disposal Prohibition :
Avoid release to the environment.
Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities.
Advice on cleaning and disposal of packaging
Allow it to drain thoroughly.
Dispose of in accordance with local regulations.
Measure for waste avoidance or recovery
Do not dispose of with domestic refuse.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
