Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Inhalation :
Not specifically applicable.

Skin contact :
Remove all contaminated clothing and footwear. Wash immediately and thoroughly for a prolonged period (at least 15
minutes). In case of inflammation (redness, irritation, ...) obtain medical attention.

Eye contact :
Immediately rinse with plenty of running water for a prolonged period, (at least 15 minutes) whilst keeping the eyes wide open. Always obtain medical advice immediately, even if there are no symptoms.

Ingestion :
NEVER attempt to induce vomiting. Rinse mouth out with water.

Further information:
Place contaminated clothing in a sealed bag for disposal. Use appropriate protective equipment when treating a contaminated person.

Fire-fighting measures

Extinguishing media
- Suitable : Water sprayPowdersCarbon dioxide (CO2)Foam
- Not suitable : Strong water jet.
If there is a a fire close by, use suitable extinguishing agents.

Specific hazards : Combustible. Toxic gases are released.

Specific fire fighting methods : Use appropriate means for fighting adjacent fires. Stay upwind.
Evacuate the personnel away from the fumes.
Cool down the containers/equipment exposed to heat with a water spray.

Protection of fire-fighters : Impermeable boots and protective equipment.
Self-contained breathing apparatus.

Accidental release measures

Personal precautions : Avoid contact with skin and eyes.
NO flames, NO sparks. Eliminate all sources of ignition.
Do not breathe vapours.
Prevent the product from spreading into the environment.
Protective equipment:
- appropriate gloves.
- water-proof boots.
- safety glasses.
Mark out the contaminated area with signs and prevent access to unauthorized personnel.
Warn of danger.
Mechanically ventilate the spillage area, whilst avoiding the formation of explosive concentrations.

Environmental precautions
Prevent the product from spreading into the environment.
Contain the spilled material by bunding (product is hazardous for the environment).

Methods for cleaning up
- Recovery : Recover as much of the product as possible.
Recover the product by vacuuming/shovelling or sweeping.
Collect up the product and place it in a spare container:
- suitably labelled.
- with a closing device.
- Cleaning/Decontamination : Wash non-recoverable remainder with large amounts of water.

Handling and storage

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.

Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Processor/User of the Registrant’s intermediate.

HANDLING
Technical measures : Use in a closed system. Earth the equipment used to transfer the product.
Measures: Avoid any direct contact with the product. Avoid the formation or spread of mists in the atmosphere.
Safe handling advice : Comply with instructions for use (refer to technical sheet).
STORAGE
Technical measures : The floor of the depot should be impermeable and designed to form a water-tight basin.
Storage tanks must be: earthed and equipped with an adequate safety valve.
Storage conditions
- Recommended : Store:
- away from any source of ignition.
- in a cool, well-ventilated area
Incompatible products : Strong oxidizing agents.
Packaging : Product must only be kept in the original packaging.
- Steel drums with an inner lining.
Packaging materials
- Recommended : Coated steels. Glass.
- Not suitable : Aluminium and its alloys. Ordinary steel.

Transport information

Land transport (ADR/RID)

UN number:
Not regulated
Shippingopen allclose all
Class:
Not regulated
Classification code:
Not regulated
Packaging group:
Not regulated
Labels:
Not regulated
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
Not regulated
Shippingopen allclose all
Class:
Not regulated
Classification code:
Not regulated
Packaging group:
Not regulated
Labels:
Not regulated
Remarksopen allclose all

Marine transport (IMDG)

UN number:
Not regulated
Proper shipping name and description:
Not regulated
Chemical name:
Not regulated
Class:
Not regulated
Packaging group:
Not regulated
EmS code:
Not regulated
Labels:
Not regulated
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
Not regulated
Proper shipping name and description:
Not regulated
Chemical name:
Not regulated
Class:
Not regulated
Packaging group:
Not regulated
Labels:
Not regulated
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.

Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Processor/User of the Registrant’s intermediate.

Engineering measures :
Only process in a closed system.
Extraction to remove vapours at their source.
Ensure good ventilation of the work station.

Personal protective equipment
- Respiratory protection: Rescue type personal respiratory protection must be permanently available and easily accessible with no delay.
- Hand protection : Impermeable protective gloves.
- Eye protection : Goggles.
- Skin and body protection: Protective clothing. Safety foot-wear.
Collective emergency equipment:
Safety shower. Eye fountain.
Emergency equipment and first-aid box with instructions readily available.
Hygiene measures: Do NOT drink, eat or smoke in the workplace. Separate normal clothes from work-clothes.

Stability and reactivity

Stability : Stable at ambient temperature and under normal conditions of use.
Hazardous reactions
- Materials to avoid :
- bases.
- strong oxidizing agents.
- Hazardous decomposition products : On combustion or on thermal decomposition (pyrolysis) releases: toxic vapours.(Phenol).(Carbon oxides (CO + CO2)).

Disposal considerations

RESIDUES FROM PRODUCT
Destruction/Disposal : Incinerate at a licensed installation.
Prohibition : Discharging waste into rivers and drains is forbidden.
CONTAMINATED PACKAGING
Prohibition : Do not dispose of the product at a rubbish tip.
Decontamination/cleaning : Allow it to drain thoroughly.
Destruction/Disposal : Entrust the thoroughly decontaminated packaging to a licensed waste-contractor.
NOTE : The user's attention is drawn to the possible existence of local regulations regarding disposal.