Registration Dossier
Registration Dossier
Data platform availability banner - registered substances factsheets
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Diss Factsheets
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 204-398-9 | CAS number: 120-46-7
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Developmental toxicity / teratogenicity
Administrative data
- Endpoint:
- developmental toxicity
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 017
- Report date:
- 2017
Materials and methods
Test guideline
- Qualifier:
- according to guideline
- Guideline:
- OECD Guideline 414 (Prenatal Developmental Toxicity Study)
- GLP compliance:
- yes (incl. QA statement)
- Limit test:
- no
Test material
- Reference substance name:
- 1,3-diphenylpropane-1,3-dione
- EC Number:
- 204-398-9
- EC Name:
- 1,3-diphenylpropane-1,3-dione
- Cas Number:
- 120-46-7
- Molecular formula:
- C15H12O2
- IUPAC Name:
- 1,3-diphenylpropane-1,3-dione
Constituent 1
Test animals
- Species:
- rat
- Strain:
- Sprague-Dawley
- Details on test animals or test system and environmental conditions:
- Age/Weight: Timed-pregnant female rats were pregnant for the first time and
shipping schedule arranged to receive animals on GD1, 2, or 3, following confirmed
mating by the supplier. Animals were mated by the supplier at 10-11 weeks of age.
The confirmed day of pregnancy, provided by the supplier, was recorded in the raw
data. The weight variation did not exceed ± 20% of the mean weight.
Animal Room Temperature and Relative Humidity Ranges
The room temperature and humidity ranged from 19-23°C and 38-56%,
respectively.
Administration / exposure
- Route of administration:
- oral: gavage
- Vehicle:
- corn oil
- Details on exposure:
- over a test period of implantation through gestation (GD5-19).
- Analytical verification of doses or concentrations:
- yes
- Details on analytical verification of doses or concentrations:
- The dose preparations (test and control) were sampled at the beginning (as part of
the homogeneity assessment, Section 6.B.6) and again at the end of the study for
verification of dose concentration. Given that dose preparations were made
daily, maintained on a stir plate during dose administration, and used within
approximately 2 hours, the test substance in the preparation was considered to be
stable. - Details on mating procedure:
- not metioned
- Duration of treatment / exposure:
- The test substance or vehicle control (corn oil) was administered daily (7 days/week) via oral
intubation to each rat during gestation days (GD) 5-19 of a 21-day pregnancy - Frequency of treatment:
- The test substance or vehicle control (corn oil) was administered daily (7 days/week) via oral
intubation to each rat during gestation days (GD) 5-19 of a 21-day pregnancy
Doses / concentrationsopen allclose all
- Dose / conc.:
- 0 other: mg/ml
- Dose / conc.:
- 25 other: mg/ml
- Dose / conc.:
- 62.5 other: mg/ml
- Dose / conc.:
- 100 other: mg/ml
- Dose / conc.:
- 0 mg/kg bw/day
- Remarks:
- dibenzoyl methane
- Dose / conc.:
- 100 mg/kg bw/day
- Remarks:
- dibenzoyl methane
- Dose / conc.:
- 250 mg/kg bw/day
- Remarks:
- dibenzoyl methane
- Dose / conc.:
- 400 mg/kg bw/day
- Remarks:
- dibenzoyl methane
- No. of animals per sex per dose:
- 20 timed-pregnant female rats per dose in total, there are 80 female rats
- Control animals:
- yes
- Details on study design:
- This study design was based on the following guidelines:
EPA Health Effects Test Guidelines. OPPTS 870.3700: Prenatal Developmental Toxicity
Study. EPA 712-C-98-207, August 1998.
OECD Guidelines for Testing of Chemicals, Section 4, Test No. 414: Prenatal Developmental
Toxicity Study, adopted 22 January 2001.
ICH Harmonized Tripartite Guideline, Detection of Toxicity to Reproduction for Medicinal
Products. Study for Effects on Embryo-Fetal Developmental (Segment II), S5(R2), Guideline
4.1.3.Step 4 version, 24 June 1993.
Examinations
- Maternal examinations:
- One Group 2 female (Animal 8024) was confirmed to be not pregnant by
ammonium sulfate staining, and one Group 4 female (Animal 8077) was found to
have total litter loss on GD20.
All other Group 1-4 females were confirmed pregnant, with viable pregnancies,
at scheduled sacrifice on GD20. - Ovaries and uterine content:
- Gravid uterine weights were comparable between control and treated groups for all confirmed pregnant females carrying viable fetuses to GD20, and there were no test substance-related macroscopic findings or effects on the placentae.
- Fetal examinations:
- the (external) fetal male sex ratios, total mean litter weight, and number of
live fetuses per litter were comparable across treatment groups. Under the study conditions, the administration of Dibenzoyl methane resulted in no treatment-related
external, visceral or skeletal teratogenic effects. - Statistics:
- Statistical Methods of the Parental (P) Generation: Mean and standard deviations were calculated for all quantitative data collected from dams.
When warranted by sufficient group sizes, data within groups were evaluated for homogeneity of
variances and normality by Bartlett’s test (Bartlett, 1937). Where Bartlett’s test indicated
homogeneous variances, treated and control groups were compared using a one-way analysis of
variance (ANOVA). When one-way analysis of variance was significant, a comparison of the
treated groups to control for multiple comparisons was performed by Dunnett’s test (Dunnett,
1964, 1980). Where variances were considered significantly different by Bartlett’s test, groups
were compared using a non-parametric method (Kruskal-Wallis non-parametric analysis of
variance; Kruskal and Wallis, 1952). When non-parametric analysis of variance was significant,
comparison of treated groups to control was performed using Dunn’s test (Dunn, 1964).
Statistical Methods of the Filial (F1) Generation
The litter was the experimental unit for evaluation where appropriate. Mean and standard
deviations were calculated independently for control and treatment groups. Similarly, mortality,
sex, along with skeletal and visceral changes were analyzed as number per litter. These analyses
were performed independently on control and the test groups. Inferential comparisons between
control and the test groups were made with regards to homogeneity of variance, normality, and
ANOVA, where appropriate.
Results and discussion
Results: maternal animals
General toxicity (maternal animals)
- Clinical signs:
- effects observed, non-treatment-related
- Description (incidence and severity):
- Maternal Examinations During Pregnancy:
Test substance-related clinical signs were noted in Group 4 animals and consisted
of: an increased incidence and/or severity in alopecia (8/20 animals) and anogenital
staining (6/20 animals); unilateral ocular discharge in 2/20 animals; slight
to moderate hypersalivation in 4/20 animals; and soft feces in 1/20 animals.
Corresponding detailed clinical observations included: hair loss in 5/20 animals;
lacrimation in 1/20 animals; salivation (above normal) in 1/20 animals; and
salivation (excessive) in 1/20 animals.
Incidental clinical signs noted during the study included: slight to moderate
alopecia on the left/right flank, forepaw/limb, and/or back of 2/20 Group 1, 2/20
Group 2, and 1/20 Group 3 animals; superficial eschar on the back of 1/20 Group 1 and 1/20 Group 4 animals; ano-genital staining in 1/20 Group 2 animals;
slight dehydration in 1/20 Group 3 animals, and a broken upper incisor in 1/20
Group 4 animals.
Corresponding detailed clinical observations included: hair loss in 2/20 Group 1,
2/20 Group 2, and 1/20 Group 3 animals; and urine stained/wet coat in 1/20
Group 2 animals. - Dermal irritation (if dermal study):
- not specified
- Mortality:
- no mortality observed
- Description (incidence):
- All animals survived until scheduled sacrifice on GD20.
- Body weight and weight changes:
- effects observed, non-treatment-related
- Description (incidence and severity):
- Maternal Examinations During Pregnancy:Lower mean body weights were observed in Group 4 animals that were
statistically significant on Days 8-17 (p<0.05-0.001). Lower mean daily body
weight gain was also observed in the Group 4 animals on Days 5-8 (p<0.001) and
the overall Day 3-20 (p<0.05).
Mean body weights for animals in Groups 2 and 3 were generally comparable to
the control Group 1 throughout the study. Incidental statistically significant
decreases in mean body weights occurred in Group 3 on Day 8 (p<0.05).
Mean daily body weight gain for animals in Groups 2 and 3 were generally
comparable to control Group 1 throughout the study. Statistically significant
decrease in mean daily body weight gain occurred in Group 3 on Days 5-8
(p<0.001). Statistically significant increases in mean daily body weight gain
occurred in Group 3 on Days 8-11 (p<0.01) and in Group 4 on Days 11-14
(p<0.01). These incidental changes did not impact the overall body weight
parameters.
Animals in Group 1 had a mean final terminal body weight of 381.4g with a
mean final adjusted body weight of 300.924g following correction for gravid
uterine weight. The net adjusted weight change from GD3 to terminal sacrifice
was 66.874g. For Groups 2, 3 and 4, mean final body weights of 379.9, 380.2
and 360.5g were observed with mean final adjusted body weights of 304.042,
299.451 and 288.955g, respectively. The net adjusted weight change from GD3
to terminal sacrifice was 70.515g for Group 2, 65.751g for Group 3, and 55.105g
for Group 4. All gravid uterus and mean adjusted body weights for animals in
Groups 2-3 were comparable to control Group 1. Group 4 animals had a
statistically significant decrease in mean final adjusted body weights (p<0.05)
that correlated to a lower terminal body weight and was associated with a slightly
lower gravid uterine weight and lower adjusted weight change from GD3. - Food consumption and compound intake (if feeding study):
- effects observed, non-treatment-related
- Description (incidence and severity):
- Lower mean daily food consumption and food efficiency were observed in Group
4 animals and were statistically significant for mean daily food consumption on
Days 5-11 (p<0.01-0.001) and mean food efficiency on Days 5-8 (p<0.001). A
statistically significant increase in mean food efficiency was observed on Days 8-
14 (p<0.01-0.001).
Mean daily food consumption for animals in Groups 2 and 3 were generally
comparable to control Group 1 throughout the study. Incidental statistically
significant decrease in mean food consumption occurred in Group 3 on Days 5-8
(p<0.01). - Food efficiency:
- effects observed, non-treatment-related
- Description (incidence and severity):
- Mean food efficiency for animals in Groups 2 and 3 were generally comparable
to control Group 1 throughout the study. Statistically significant changes in
mean food efficiency occurred in Group 3 and consisted of decrease on Days 5-8
(p<0.01) and increase on Days 8-11 (p<0.001). These incidental changes did not
impact the overall body weight parameters. - Water consumption and compound intake (if drinking water study):
- not specified
- Ophthalmological findings:
- not specified
- Haematological findings:
- not specified
- Clinical biochemistry findings:
- not specified
- Urinalysis findings:
- no effects observed
- Behaviour (functional findings):
- effects observed, non-treatment-related
- Description (incidence and severity):
- There were no gross abnormalities in any of the female rats at terminal sacrifice
on GD20. - Immunological findings:
- not specified
- Organ weight findings including organ / body weight ratios:
- not specified
- Gross pathological findings:
- not specified
- Neuropathological findings:
- not specified
- Histopathological findings: non-neoplastic:
- not specified
- Histopathological findings: neoplastic:
- not specified
- Other effects:
- not specified
- Details on results:
- In summary, all animals survived until scheduled sacrifice on GD20, with one Group 2
female confirmed to be not pregnant and one Group 4 female found to have total litter
loss. Clinical signs attributed to the administration of Dibenzoyl methane were limited to
Group 4 females and consisted of increased incidence in alopecia and ano-genital
staining, ocular discharge, hypersalivation, and soft feces. These signs had
corresponding detailed clinical observations of hair loss, lacrimation, and increased or
excessive salivation. Generally, lower mean body weights, daily body weight gain, daily
food consumption, and food efficiency were observed in the Group 4 animals. Group 4
animals had a decrease in mean final adjusted body weights that correlated to a lower
terminal body weight and was associated with a slightly lower gravid uterine weight and
lower adjusted weight change from GD3. Due the nature and incidence of clinical
observations and the magnitude of body weight parameters decreases, these test
substance-related changes were not considered to be adverse.
Maternal developmental toxicity
- Number of abortions:
- no effects observed
- Description (incidence and severity):
- There were no abortions or premature deliveries throughout gestation of the
pregnant females. One Group 4 female (Animal 8077) was determined to have
suffered total litter loss - Pre- and post-implantation loss:
- no effects observed
- Description (incidence and severity):
- Pre-implantation loss for all confirmed pregnant females in Groups 2-3 was
comparable to control Group 1 with mean values of 5.09, 2.96, and 5.91 for
Groups 1-3, respectively. A slight increase in pre-implantation loss at 9.56% was
observed for Group 4 females when compared to control Group 1. This increase
was observed to be within published data range and is therefore interpreted to be
of no toxicological significance (Hood, 2012). - Total litter losses by resorption:
- no effects observed
- Description (incidence and severity):
- Total number of resorptions for all confirmed pregnant females in Group 2 and 3
were comparable to control Group 1 with mean values of 0.6, 0.5, and 0.6% for Groups 1-3, respectively. Group 4 confirmed pregnant females had a slightly
higher total number of resorptions of 1.3%, mainly due to the total litter loss.
These values resulted in post-implantation loss of 4.46, 4.17, 4.10, and 9.75% for
Groups 1-4, respectively. Although the increase in post-implantation loss was
observed to be within published data range (Hood, 2012), its correlation with the
presence of a total litter loss are interpreted to be of toxicological relevance but
no adversity. - Early or late resorptions:
- effects observed, non-treatment-related
- Description (incidence and severity):
- Mean early resorptions were 0.4 for Groups 1-3 and 0.6 for Group 4. These values resulted in post-implantation loss of 3.07, 2.86, 2.71, and 4.33% for Group 1-4, respectively. No late resorptions were observed.
- Dead fetuses:
- no effects observed
- Description (incidence and severity):
- The number of live fetuses was comparable for all confirmed pregnant females.
The mean values of live fetuses per litter in Group 1 were 12.6 with a total of 20
litters. Group 2 with 19 viable litters, Groups 3 with 20 viable litters, and Group
4 with 19 (of 20) viable litters had an average number of live fetuses of 12.8,
12.6, and 11.5, respectively. - Changes in pregnancy duration:
- not specified
- Changes in number of pregnant:
- not specified
- Other effects:
- not specified
- Details on maternal toxic effects:
- In summary, 20 females in Group 1 (100%), 19 females in Group 2 (95%), 20 females in
Group 3 (100%), and 20 females in Group 4 (100%) were confirmed pregnant. Under the
study conditions, administration of Dibenzoyl methane resulted in no adverse changes in
uterine parameters throughout the treatment period, for all confirmed pregnant females in
Group 2 and 3. Group 4 had one pregnant female with total litter loss and a slight
increase in post-implantation loss and number of resorptions that were not considered to
be adverse.
Effect levels (maternal animals)
- Remarks on result:
- other: not specified
- Remarks:
- not specified
Maternal abnormalities
- Abnormalities:
- not specified
Results (fetuses)
- Fetal body weight changes:
- effects observed, non-treatment-related
- Description (incidence and severity):
- Total mean litter weight was comparable between control and test substancetreated
animals. Values were 51.15, 52.38, 51.85, and 48.87 g in Groups 1-4,
respectively - Reduction in number of live offspring:
- effects observed, non-treatment-related
- Description (incidence and severity):
- A total of 20 litters in Group 1 (251 fetuses), 19 litters in Group 2 (244 fetuses),
20 litters in Group 3 (252 fetuses), and 19 litters in Group 4 (229 fetuses) were
examined at caesarean section for external fetal malformations on GD20. - Changes in sex ratio:
- effects observed, non-treatment-related
- Description (incidence and severity):
- The (external) fetal male sex ratio was 47.01, 52.46, 49.21 and 50.66% for
Groups 1-4, respectively, and was comparable across treatment groups. - Changes in litter size and weights:
- effects observed, non-treatment-related
- Description (incidence and severity):
- Total mean litter weight was comparable between control and test substancetreated
animals. Values were 51.15, 52.38, 51.85, and 48.87 g in Groups 1-4,
respectively. - Changes in postnatal survival:
- not specified
- External malformations:
- effects observed, non-treatment-related
- Description (incidence and severity):
- Malposition of the 4th sternebrae was observed in one Group 3 fetus (11F of
Dam 8054). Additional malformations occurred in one Group 1 fetus (5F of
Dam 8008) that consisted of absences of the 1st-6th lumbar vertebral arch, 2nd-13th
thoracic vertebral arch, and 2nd-13th thoracic ribs. These findings are considered
to be incidental and of no significance from a developmental toxicology
perspective. - Skeletal malformations:
- effects observed, non-treatment-related
- Description (incidence and severity):
- One hundred and thirty-one (131) fetuses from 20 litters in Group 1, 126 from 19
litters in Group 2, 132 from 20 litters in Group 3, and 119 fetuses from 19 litters
in Group 4 were evaluated for skeletal malformations and developmental
variations - Visceral malformations:
- no effects observed
- Description (incidence and severity):
- Of the 120 fetuses from 20 litters in Group 1, 118 from 19 litters in Group 2, 120
from 20 litters in Group 3, and 110 fetuses from 19 litters in Group 4 evaluated
for visceral malformations and developmental variations, no malformations were
noted in any fetus during visceral examination. One incidental developmental
variation of the ureters, a slight dilation on the right side, occurred in one Group
2 fetus (F7 of Dam 8036). - Other effects:
- not specified
- Details on embryotoxic / teratogenic effects:
- Variations occurred with equal incidence in all groups on test consisting in most
cases of bone unossification or incomplete ossification. Overall, there was no
pattern of ossification changes associated with test substance administration and
therefore all ossification developmental variations are considered incidental or to
be within the developmental biological spectrum.
Fetuses evaluated in Groups 1-4, respectively, exhibited the following skeletal
variations in the caudal vertebrae: 22.1, 4.0, 4.5, and 6.7% incomplete
ossification of the 1st caudal vertebrae; 24.4, 24.6, 25.0, 31.9% unossified 2nd
caudal vertebrae; 51.9, 40.5, 34.1, and 36.1% incomplete ossification of the 2nd
caudal vertebrae; 99.2, 88.9, 94.7, and 95.0% unossified 3rd caudal vertebrae; 0.8,
10.3, 5.3, and 2.5% incomplete ossification of the 3rd caudal vertebrae; and 100.0,
99.2, 100.0 and 100.0% unossified 4th caudal vertebrae. Additional incidental
variation of unossified 1st caudal vertebrae was observed in two Group 1 fetuses.
Incomplete ossification of the 1st thoracic vertebral arch was observed in one
Group 1 fetus.
Incidental skeletal variations in the pelvic girdle included: bilateral unossified
ischium in one Group 1 fetus; bilateral incomplete ossification of the ischium in
one Group 1 fetus; bilateral incomplete ossification of the pubis in three Group 1
fetuses; and unilateral (right) incomplete ossification of the pubis in one Group 1
fetus.
Fetuses evaluated in Groups 1-4, respectively, exhibited the following variations
in the metatarsal bones: 99.2, 100.0, 100.0, and 98.3% unossified 1st phalanges
(bilateral); 99.2, 100.0, 100.0, and 99.2% unossified 2nd-5th phalanges (bilateral);
and 98.5, 100.0, 100.0, and 99.2% unossified 1st metatarsal (bilateral).
Additional incidental variations of incomplete ossification of the 1st metatarsal
(bilateral) in one Group 1 fetus and incomplete ossification of the 5th metatarsal
(bilateral) in one Group 3 fetus were observed.
Fetuses evaluated in Groups 1-4, respectively, exhibited the following variations
in the skull bones: 0.8, 0.8, 0.8 and 0.8% incomplete ossification of the occipital
bone; 2.3, 0.8, 1.5, and 0.8% unossified hyoid; and 12.2, 2.4, 2.3, and 1.7%
incomplete ossification of the hyoid. In addition, one Group 3 (0.8%) and two
Group 4 (1.7%) fetuses had incomplete ossification of the frontals (bilateral); one
Group 1 (0.8%), one Group 3 (0.8%), and three Group 4 (2.5%) fetuses had incomplete ossification of the parietals (bilateral); one Group 1 (0.8%), three
Group 3 (2.3%) and four Group 4 (3.4%) fetuses had incomplete ossification of
the interperietal; and one Group 2 (0.8%) fetus had incomplete ossification of the
left maxilla.
Incidental skeletal variations in the ribs included: short 13th thoracic rib on the
left side of two Group 2 fetuses and one Group 4 fetus; short 13th thoracic rib on
the right side of one Group 2 and one Group 4 fetus; and supernumerary 14th
thoracic rib (bilateral) in two Group 1 fetuses, two Group 2 fetuses, and one
Group 3 fetus, supernumerary 14th thoracic rib on the left side of four Group 1
fetuses and one Group 4 fetus; and supernumerary 14th thoracic rib on the right
side of one Group 1 fetus.
Fetuses evaluated in Groups 1-4, respectively, exhibited the following variations
in the sternebra: 3.1, 6.3, 6.1, and 21.0% incomplete ossification of the 2nd
sternebra; 3.1, 3.2, 5.3, and 16.8% incomplete ossification of the 4th sternebra;
6.9, 10.3, 16.7, and 25.2% unossified 5th sternebra; 80.9, 82.5, 71.2, and 68.1%
incomplete ossification of the 5th sternebra; 2.3, 1.6, 1.5, and 1.7% unossified 6th
sternebra; and 60.3, 44.4, 40.9, and 53.8% incomplete ossification of the 6th
sternebra. In addition, one Group 1 fetus had unossified 1st-3rd sternebra; one
Group 4 fetus had bipartite ossification of the 1st-3rd and 6th sternebra; one Group
1 fetus and three Group 3 fetuses had incomplete ossification of the 1st sternebra;
two Group 1, three Group 3; and two Group 4 fetuses had incomplete ossification
of the 3rd sternebra; one Group 1 and one Group 3 fetus had unossified 4th
sternebra; one Group 3 and one Group 4 fetus had bipartite ossification of the 4th
sternebra; and one Group 1, one Group 3, and three Group 4 fetuses had bipartite
ossification of the 5th sternebra.
Incidental skeletal variations in the cervical vertebrae included incomplete
ossification of 3rd-5th cervical vertebral arch in one Group 4 fetus and of the 6th
cervical vertebral arch in one Group 2 and one Group 4 fetus.
In the pectoral girdle, 25.2, 11.1, 7.6, and 12.6% of fetuses in Groups 1-4,
respectively, exhibited an unossified 4th metacarpal (bilateral) and 13.0, 9.5, 15.9,
10.9% had incomplete ossification of the 4th metacarpal (bilateral). Bilateral
unossification of the 1st (98.5, 100.0, 99.2, and 97.5%), 2nd (79.4, 64.3, 50.8, and
55.5%), 3rd (85.5, 75.4, 62.1, and 63.9%), 4th (99.2, 100.0, 99.2, and 99.2%), and
5th (99.2, 100.0, 99.2, and 98.3%) phalanges occurred in Groups 1-4,
respectively. Additional incidental variations in the pectoral griddle included:
incomplete ossification of the 4th metatarsal (left) in three Group 1, three Group 2
and one Group 3 fetuses; unossified 1st-5th phalange (left) in one Group 1 fetus;
and incomplete ossification of the 2nd phalange (bilateral) in one Group 1, two
Group 3, and two Group 4 fetuses.
Incidental skeletal variations in the sacral vertebra included: unossification of
the 1st-4th sacral vertebral arch in one Group 1 fetus; incomplete ossification of
the 3rd sacral vertebral arch in two Group 1 fetuses; and incomplete ossification
of the 4th sacral vertebral arch in twelve Group 1 fetuses, two Group 3 fetuses,
and one Group 4 fetus.
In summary, the (external) fetal male sex ratios, total mean litter weight, and number of
live fetuses per litter were comparable across treatment groups. Under the study conditions, the administration of Dibenzoyl methane resulted in no treatment-related
external, visceral or skeletal teratogenic effects.
Effect levels (fetuses)
- Dose descriptor:
- NOAEL
- Effect level:
- <= 400 mg/kg bw/day (nominal)
- Based on:
- test mat.
- Sex:
- male/female
- Basis for effect level:
- external malformations
- visceral malformations
- Remarks on result:
- other:
Fetal abnormalities
- Abnormalities:
- effects observed, non-treatment-related
- Localisation:
- other: abdomen/tail
- Description (incidence and severity):
- Aside from a incidental variation of the abdomen/tail area in Group 1, noted as a
“thread-like tail” for fetus number 5 (F5) of Dam 8008, no other external
abnormalities were observed in any pups in Groups 1-4.
Overall developmental toxicity
- Key result
- Developmental effects observed:
- yes
- Lowest effective dose / conc.:
- 400 mg/kg bw/day (nominal)
- Treatment related:
- yes
- Relation to maternal toxicity:
- not specified
- Dose response relationship:
- yes
- Relevant for humans:
- not specified
Applicant's summary and conclusion
- Conclusions:
- Under the conditions of the study and based on the maternal and fetal developmental toxicity
endpoints evaluated, the no-adverse-effect level (NOAEL) for general toxicological and
developmental parameters for the administration of Dibenzoyl methane by oral gavage was
determined to be 400 mg/kg/day. - Executive summary:
A prenatal developmental toxicity study was conducted in timed-pregnant CRL Sprague-Dawley
CD® IGS rats to determine the potential of Dibenzoyl methane to produce pre-natal
developmental toxicity, when administered orally throughout pregnancy, from implantation to
one day prior to term delivery. Eighty (80) timed-pregnant female rats were selected for the test
and equally distributed into four groups (twenty females per group). Dose levels of 100, 250, and
400 mg/kg/day of Dibenzoyl methane, respectively, as well as vehicle control (corn oil), were
selected for the test.
The test substance or vehicle control (corn oil) was administered daily (7 days/week) via oral
intubation to each rat during gestation days (GD) 5-19 of a 21-day pregnancy. The test substance
was administered as a 25 mg/mL, 62.5 mg/mL, 100 mg/mL w/v mixture in corn oil. Animals
were observed daily during pregnancy for clinical signs and mortality. Individual body weights
and food consumption for all pregnant females are reported on GD3, 5, 8, 11, 14, 17, and 20.
Gross necropsies and caesarean sections were performed on all pregnant rats, where the
pregnancy status and uterine contents were evaluated. The conceptuses were assessed for
viability, external observations, and then for visceral and skeletal variations.
The neat test substance, as determined by measured Dibenzoyl methane, was found to be stable
under the conditions of storage at PSL over the course of this study. The test substance was
considered to be homogenously distributed in all dose solutions. All concentration verification
values were slightly above the targeted concentrations, indicating the animals received at least the
dose levels of 100, 250, and 400 mg/kg/day for Groups 2-4, respectively.
All animals survived until scheduled sacrifice on GD20, with one Group 2 female confirmed to
be not pregnant and one Group 4 female found to have total litter loss. Clinical signs attributed to
the administration of Dibenzoyl methane were limited to Group 4 females and consisted of
increased incidence in alopecia, ano-genital staining, ocular discharge, hypersalivation and soft
feces. These signs had corresponding detailed clinical observations of hair loss, lacrimation, and
increased or excessive salivation. Generally, lower mean body weights, daily body weight gain,
food consumption, and food efficiency were observed in the Group 4 animals. Group 4 animals
had a decrease in mean final adjusted body weights that correlated to a lower terminal body
weight and was associated with a slightly lower gravid uterine weight and lower adjusted weight
change from GD3. Due the nature and incidence of clinical observations and the magnitude of
body weight parameters decreases, these test substance-related changes were not considered to be
adverse.
Administration of Dibenzoyl methane resulted in no adverse changes in uterine parameters
throughout the treatment period, for all confirmed pregnant females carrying viable fetuses to
GD20 in Group 2 and 3. Group 4 had one pregnant female with total litter loss and a slight
increase in post implantation loss and number of resorptions that were within published data
range and therefore not considered to be adverse.
A total of 20 litters in Group 1 (251 fetuses), 19 litters in Group 2 (244 fetuses), 20 litters in
Group 3 (252 fetuses), and 19 litters in Group 4 (229 fetuses) were examined at caesarean section
for external fetal malformations on GD20, prior to evaluation for visceral or skeletal
malformations and developmental variations. The (external) fetal male sex ratio, total mean litter
weight, and the number of live fetuses were comparable across treatment groups. There were no
external, visceral or skeletal teratogenic effects related to the administration of Dibenzoyl
methane.
Under the conditions of the study, and based on the maternal and fetal developmental toxicity
endpoints evaluated, the no-adverse-effect level (NOAEL) for general toxicological and
developmental parameters for the administration of Dibenzoyl methane by oral gavage was
determined to be 400 mg/kg/day.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.