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Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

4.1. Description of first aid measures

Remove contaminated clothing.

If inhaled:

If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention.

On skin contact:

Wash thoroughly with soap and water.

On contact with eyes:

Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

On ingestion:

Rinse mouth immediately and then drink plenty of water, seek medical attention.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further symptoms are possible

4.3. Indication of any immediate medical attention and special treatment needed

Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

Fire-fighting measures

5.1. Extinguishing media

Suitable extinguishing media:

water spray, dry powder, foam, carbon dioxide

5.2. Special hazards arising from the substance or mixture

nitrogen oxides, carbon oxides

The substances/groups of substances mentioned can be released in case of fire.

5.3. Advice for fire-fighters

Special protective equipment:

Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:

Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Avoid inhalation. Avoid contact with the skin, eyes and clothing.

6.2. Environmental precautions

Do not discharge into drains/surface waters/groundwater.

6.3. Methods and material for containment and cleaning up

For large amounts: Pump off product.

For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr). Dispose of absorbed material in accordance with regulations.

6.4. Reference to other sections

Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.

Handling and storage

7.1. Precautions for safe handling

Ensure thorough ventilation of stores and work areas.

Protection against fire and explosion:

Take precautionary measures against static discharges. Sources of ignition should be kept well clear.

7.2. Conditions for safe storage, including any incompatibilities

Further information on storage conditions: Containers should be stored tightly sealed in a dry place.

Storage stability:

Storage temperature: 20 °C

Storage duration: 6 Months

From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.

7.3. Specific end use(s)

For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.

Transport information

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Marine transport (UN RTDG/IMDG)

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Exposure controls / personal protection

8.1. Control parameters

Components with occupational exposure limits

No occupational exposure limits known.

PNEC

freshwater: 0,0747 mg/l

marine water: 0,00747 mg/l

intermittent release: 0,747 mg/l

STP: 100 mg/l

sediment (freshwater): 0,278 mg/kg

sediment (marine water): 0,0278 mg/kg

soil: 0,0118 mg/kg

8.2. Exposure controls

Personal protective equipment

Respiratory protection:

Respiratory protection in case of vapour/aerosol release.

Hand protection:

Chemical resistant protective gloves (EN 374)

Suitable materials also with prolonged, direct contact (Recommended:  Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):

butyl rubber (butyl) - 0.7 mm coating thickness

Suitable materials short-term contact and/or splashes (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN 374)

chloroprene rubber (CR) - 0.5 mm coating thickness

nitrile rubber (NBR) - 0.4 mm coating thickness

fluoroelastomer (FKM) - 0.7 mm coating thickness

polyvinylchloride (PVC) - 0.7 mm coating thickness

Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.

Eye protection:

Tightly fitting safety goggles (splash goggles) (e.g. EN 166)

Body protection:

Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

General safety and hygiene measures

Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes. Wearing of closed work clothing is required additionally to the stated personal protection equipment.

Stability and reactivity

10.1. Reactivity

No hazardous reactions if stored and handled as prescribed/indicated.

Formation of flammable gases:       Remarks:       Forms no flammable gases in the presence of water.

10.2. Chemical stability

The product is stable if stored and handled as prescribed/indicated.

10.3. Possibility of hazardous reactions

Reacts with bases. Reacts with acids. Exothermic reaction.

10.4. Conditions to avoid

Avoid all sources of ignition: heat, sparks, open flame. See MSDS section 7 - Handling and storage.

10.5. Incompatible materials

Substances to avoid:

bases, strong acids

10.6. Hazardous decomposition products

Hazardous decomposition products:

carbon oxides, nitrogen oxides

Disposal considerations

13.1. Waste treatment methods

Incinerate in suitable incineration plant, observing local authority regulations.

A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.

The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.

Contaminated packaging:

Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.