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Diss Factsheets

Physical & Chemical properties

Explosiveness

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Reference
Endpoint:
explosive properties of explosives
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
guideline study with acceptable restrictions
Qualifier:
according to guideline
Guideline:
UN Manual of Tests and Criteria: Part I: Classification procedures, test methods and criteria relating to explosives of Class 1
GLP compliance:
no
Test series:
UN Test series 1
Method:
UN Test 1 (b): Koenen test
Parameter:
limiting diameter (mm)
Result:
negative, no violent effect on heating under confinement
Remarks on result:
other: not explosive
Test series:
UN Test series 1
Method:
UN Test 1 (c) (i): Time/pressure test
Parameter:
limiting diameter (mm)
Result:
negative, no ability to deflagrate
Remarks on result:
other: not explosive

Result screening DTA:

 No.  Mass  Temperature Range  Type of Effect  Energy
 1  25.3 mg  147 °C to approx. 345 °C  exothermic  620 J/g
 2  25.3 mg  147 °C to approx. 345 °C  exothermic  620 J/g

 

Result Koenen Test:

 Nozzle Diameter  Sample Mass  Reaction Initiation after  Results
 1 mm  25.0 g  29 s  No fragments, cartridge unchanged
1 mm  25.0 g  26 s  No fragments, cartridge unchanged
 1 mm  25.0 g  24 s  No fragments, cartridge unchanged

Results Time pressure test:

 Test Run  Sample Mass  Max. Pressure  Time from 690 kPa to 2070 kPa
 1  5.0 g  813 kPa  N/A
 2  5.0 g  656 kPa  N/A
 3  5.0 g  531 kPa  N/A
Interpretation of results:
GHS criteria not met
Conclusions:
Based on results of screening DTA, Koenen test and time pressure test Reactive Red 141 is not explosive when tested according to UN-MTC.
Executive summary:

Based on results of screening DTA, Koenen test and time pressure test Reactive Red 141 is not explosive when tested according to UN-MTC.

Description of key information

Based on results of screening DTA, Koenen test and time pressure test Reactive Red 141 is not explosive when tested according to UN-MTC.

Key value for chemical safety assessment

Explosiveness:
non explosive

Additional information

Justification for classification or non-classification

Based on tests according to UN-MTC (screening DTA, Koenen Test, Time pressure test) Reactive Red 141 has no explosiveness properties and therefore, the substance is not classified for physical hazards according to Regulation (EC) No 1272/2008 (CLP).