Reaction mass of 2-{[3-(trimethoxysilyl)propyl]amino}ethanaminium chloride and 2-{benzyl[3-(trimethoxysilyl)propyl]amino}ethanaminium chloride and N-[2-(benzylamino)ethyl]-3-(trimethoxysilyl)propan-1-aminium chloride and N-[2-(dibenzylamino)ethyl]-3-(trimethoxysilyl)propan-1-aminium chloride and N-benzyl-2-{benzyl[3-(trimethoxysilyl)propyl]amino}ethanaminium chloride and N-benzyl-N-[2-(dibenzylamino)ethyl]-3-(trimethoxysilyl)propan-1-aminium chloride.

GHS

General Information

Implementation:

EU

Type of classification:

harmonised classification

Remarks:

Index Number: 612-228-00-3

According to EU GHS Classification, CLP Reg. No. 1272/2008 of 16 Dec 2008, Annex VI, Table 3.1, List of harmonized classification and labelling of hazardous substances, as amended by Re. No 790/2009, 10 August 2009, Reaction mass of: N-(3 -(trimethoxysilyl)propyl)ethylenediamine; N-benzyl-N-(3 -(trimethoxysilyl)propyl)ethylenediamine; N-benzyl-N’-[3 -(trimethoxysilyl)propyl]ethylenediamine; N,N’-bis-benzyl-N’-[3 -(trimethoxysilyl)propyl]ethylenediamine; N,N,N’-tris-benzyl-N’-[3 -(trimethoxysilyl)propyl]ethylenediamine; N,N-bis-benzyl-N’-[3 -(trimethoxysilyl)propyl]ethylenediamine (formal EC No. 414-340-6 changed to EC No. 700 -961 -2) is classified as:

Flam. Liq. 3 (H226)

Acute Tox. 4 (H332)

Acute Tox. 4 (H312)

Acute Tox. 4 (H302)

STOT SE 2 (H371)

Eye Dam. 1 (H318)

Skin Sens. 1 (H317)

Aquatic Chronic 3 (H412)

Related composition

Related composition:

RECONSILE, 700-961-2, reaction mass containing six benzylated amine silanes

Classification

Physical hazards

Explosives

Reason for no classification:

data conclusive but not sufficient for classification

Flammable gases and chemically unstable gases

Reason for no classification:

data conclusive but not sufficient for classification

Aerosols

Reason for no classification:

data conclusive but not sufficient for classification

Reason for no classification:

hazard class not assessed

Oxidising gases

Reason for no classification:

data conclusive but not sufficient for classification

Gases under pressure

Reason for no classification:

data conclusive but not sufficient for classification

Flammable liquids

Hazard category:

Flam. Liquid 3

Hazard statement:

H226: Flammable liquid and vapour.

Flammable solids

Reason for no classification:

data conclusive but not sufficient for classification

Self-reactive substances and mixtures

Reason for no classification:

data conclusive but not sufficient for classification

Pyrophoric liquids

Reason for no classification:

data conclusive but not sufficient for classification

Pyrophoric solids

Reason for no classification:

data conclusive but not sufficient for classification

Self-heating substances and mixtures

Reason for no classification:

data conclusive but not sufficient for classification

Substances and mixtures which in contact with water emit flammable gases

Reason for no classification:

data conclusive but not sufficient for classification

Oxidising liquids

Reason for no classification:

data conclusive but not sufficient for classification

Oxidising solids

Reason for no classification:

data conclusive but not sufficient for classification

Organic peroxides

Reason for no classification:

data conclusive but not sufficient for classification

Corrosive to metals

Reason for no classification:

data conclusive but not sufficient for classification

Desensitized explosives

Reason for no classification:

data conclusive but not sufficient for classification

Health hazards

Acute toxicity - oral

Hazard category:

Acute Tox. 4

Hazard statement:

H302: Harmful if swallowed.

Acute toxicity - dermal

Hazard category:

Acute Tox. 4

Hazard statement:

H312: Harmful in contact with skin.

Acute toxicity - inhalation

Hazard category:

Acute Tox. 4

Hazard statement:

H332: Harmful if inhaled.

Skin corrosion / irritation

Reason for no classification:

data conclusive but not sufficient for classification

Serious eye damage / eye irritation

Hazard category:

Eye Damage 1

Hazard statement:

H318: Causes serious eye damage.

Respiratory sensitisation

Reason for no classification:

data lacking

Skin sensitisation

Hazard category:

Skin Sens. 1B

Hazard statement:

H317: May cause an allergic skin reaction.

Aspiration hazard

Reason for no classification:

data lacking

Reproductive toxicity

Reason for no classification:

data lacking

Effects on or via lactation

Reason for no classification:

data lacking

Germ cell mutagenicity

Reason for no classification:

data conclusive but not sufficient for classification

Carcinogenicity

Reason for no classification:

data lacking

1. Specific target organ toxicity - single (STOT-SE)

Hazard category:

STOT Single Exp. 2

Hazard statement:

H371: May cause damage to organs <or state all organs affected, if known> <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

Affected organs:

other: stomach, duodenum, jejunum, ileum, and thymus

Route of exposure:

oral

1. Specific target organ toxicity - repeated (STOT-RE)

Reason for no classification:

data conclusive but not sufficient for classification

Environmental hazards

Hazardous to the aquatic environment (acute / short-term)

Reason for no classification:

data conclusive but not sufficient for classification

Hazardous to the aquatic environment (long-term)

Hazard category:

Aquatic Chronic 3

Hazard statement:

H412: Harmful to aquatic life with long lasting effects.

Hazardous to the ozone layer

Reason for no classification:

data conclusive but not sufficient for classification

Labelling

Signal word:

Danger

Hazard pictogram

GHS02: flame

GHS08: health hazard

GHS05: corrosion

GHS07: exclamation mark

Hazard statements

H226: Flammable liquid and vapour.

H371: May cause damage to organs <or state all organs affected, if known> <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

H332: Harmful if inhaled.

H318: Causes serious eye damage.

H317: May cause an allergic skin reaction.

H312: Harmful in contact with skin.

H302: Harmful if swallowed.

H412: Harmful to aquatic life with long lasting effects.