Registration Dossier

Administrative data

First-aid measures

Description of first aid measures

Inhalation:
Get medical attention immediately. Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Ingestion:
Get medical attention immediately. Wash out mouth with water. Move exposed person to fresh air. Keep person warm and at rest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Skin contact:
Get medical attention immediately. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Eye contact:
Get medical attention immediately. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician.




Fire-fighting measures

Extinguishing media
Suitable extinguishing media : In case of fire, use water spray (fog), foam, dry chemical or CO2.

Unsuitable extinguishing media: None known.

Special hazards arising from the substance or mixture

Hazards from the substance or mixture : In a fire or if heated, a pressure increase will occur and the container may burst.
Hazardous combustion products: Decomposition products may include the following materials: carbon oxides

Advice for firefighters

Special precautions for fire-fighters: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Special protective equipment for fire fihghters: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Accidental release measures

Personal precautions,protective equipment and emergency procedures:
No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Avoid breathing vapour or mist. Provide adequate ventilation. Put on appropriate personal protective equipment .
Environmental precautions:Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up
Small spill:
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Large Spill:
Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations . Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product.

Handling and storage

Precautions for safe handling:
Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous.

Conditions for safe storage, including any incompatibilities:
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.

Seveso II Directive - Reporting thresholds (in tonnes) Danger criteria:

Category Notification and MAPP threshold Safety report threshold
H2: Acute toxicity 2 any route of entry or 50 200
Acute toxicity 3 Inhalation/Dermal route of 50 200
entry C2: Toxic

Transport information

Land transport (ADR/RID)

UN number:
UN2810
Shippingopen allclose all
Class:
6,Toxic
Classification code:
Toxic
Packaging group:
III
Labels:
Hazard identification number: 60

SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN2810
Shippingopen allclose all
Class:
6,Toxic
Classification code:
Toxic
Packaging group:
III
Labels:
Hazard identification number: 60
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN2810
Proper shipping name and description:
TOXIC LIQUID, ORGANIC, N.O.S.
Chemical name:
(3-ALLYL (DIHYDRO) FURANE-2, 5-DIONE)
Class:
6,Toxic
Packaging group:
III
EmS code:
Emergency
schedules (EmS)
F-A, S-A
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN2810
Proper shipping name and description:
TOXIC LIQUID, ORGANIC, N.O.S.
Chemical name:
(3-ALLYL (DIHYDRO) FURANE-2, 5-DIONE)
Class:
6,Toxic
Packaging group:
III
Remarks
Passenger
aircraft
655: 60 L
Cargo aircraft
663: 220 L

Additional transport information

Additional transport information
Transport in bulk according to Annex : Not available. II of MARPOL 73/78 and the IBC Code
Hazard notes:
Slightly toxic.
Irritating to skin.
Risk of serious damage to eyes.
Keep away from cargo susceptible to odour.
Keep away from foodstuffs, acids and alkalis.

Exposure controls / personal protection

Control parameters
Exposure limit values: Not available

Recommended monitoring procedures:
If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Exposure controls:
Risk management measures
Occupational exposure controls
Technical measures:
If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits.
Personal protection measures:
Respiratory protection:
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Recommended: Full mask with type ABEK filter.
Hand protection:
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. After contamination with product change the gloves immediately and dispose of them according to relevant national and local regulations
Recommended: (< 1 hour) Rubber gloves.
Eye protection:
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts.
Recommended: safety glasses with side-shields
Skin protection:
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Recommended: Wear protective clothing.
Hygiene measures:
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Environmental exposure controls
Technical measures:
Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.





Stability and reactivity

Reactivity: No specific test data related to reactivity available for this product or its ingredients.

Chemical stability: The product is stable.

Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur.

Conditions to avoid: Highly reactive with alkalis and alcohols

Incompatible materials : No specific data.

Hazardous decomposition products: Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Disposal considerations

Waste treatment methods:
Product:
Methods of disposal:
Examine possibilities for re-utilisation. Product residues and uncleaned empty containers should be packaged, sealed, labelled, and disposed of or recycled according to relevant national and local regulations. Where large quantities are concerned, consult the supplier. When uncleaned empty containers are passed on, the recipient must be warned of any possible hazard that may be caused by residues. For disposal within the EC, the appropriate code according to the European Waste List (EWL) should be used. It is among the tasks of the polluter to assign the waste to waste codes specific to industrial sectors and processes according to the European Waste List (EWL).
Hazardous waste:
The classification of the product may meet the criteria for a hazardous waste.
Packaging
Methods of disposal:
The generation of waste should be avoided or minimised wherever possible. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible.
Special precautions:
This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.