Registration Dossier

Administrative data

First-aid measures

If inhaled:
Move to fresh air. Seek medical attention if you feel unwell or if exposure prolonged. In case of irritation of the respiratory system or mucous membranes, seek medical attention.

On skin contact:
Wash with plenty of soap and water. Do not use organic solvents. Get medical attention if irritation
occurs.

On contact with eyes:
Rinse immediately with plenty of water for at least 10 minutes taking care to wash under the eyelids. If irritation persists, seek medical attention.

On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention.

Notes to physician:
Treatment: Treat symptomatically.

Fire-fighting measures

Suitable extinguishing media:
water spray, carbon dioxide, foam, dry powder

Unsuitable extinguishing media for safety reasons:
water jet

Combustion products:
Carbon and nitrogen oxides.

Exposure hazards:
Do not release chemically contaminated water into drains, soil or surface water. Sufficient measures must be taken to retain the water used for extinguishing. Dispose of contaminated water and soil according to local regulations.

Special protective equipment:
Full protective clothing. Wear a self-contained breathing apparatus.

Accidental release measures

Personal precautions:
Do not breathe vapours/dust. Sources of ignition should be kept well clear. Avoid contact with the skin, eyes and clothing.
Environmental precautions:
Prevent entry into sewage systems, ground and surface waters.
Methods for cleaning-up or taking-up:
Take up mechanically and collect in suitable container (adequately labelled) for disposal. Collect waste in suitable containers, which can be labeled and sealed.
Avoid raising dust.
Additional information:
None under normal storage conditions.

Handling and storage

Handling
Handle and open container with care.
Avoid dust formation and ignition sources. Ensure good local exhaust ventilation. Do not eat, drink or smoke at the workplace. Close containers immediately after use.
Protection against fire and explosion:
Avoid creating dusty conditions. Risk of explosion if an air-dust mixture forms. Inert container or use a system otherwise designed to prevent or contain an explosion - seek expert advice.
Storage requirements:
Keep away from food and drink.
Keep container tightly closed in a dry, cool and well-ventilated place.
Temperature tolerance:
Protect from temperatures above: 40 °C

Transport information

Land transport (ADR/RID)

UN number:
UN 1325
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Class:
4.1
Classification code:
40
Packaging group:
II
Labels:
4.1
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Marine transport (IMDG)

UN number:
UN 1325
Proper shipping name and description:
FLAMMABLE SOLID, ORGANIC, N.O.S.
Chemical name:
Manganese, ((2,2',2''-(nitrilotris(2,1-ethanediyl(nitrilo-.kappa.N)methylidyne))tris(phenolato-.kappa.O))(3-))-
Class:
4.1
Packaging group:
II
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Air transport ICAO/IATA

UN number:
UN 1325
Proper shipping name and description:
FLAMMABLE SOLID, ORGANIC, N.O.S.
Chemical name:
Manganese, ((2,2',2''-(nitrilotris(2,1-ethanediyl(nitrilo-.kappa.N)methylidyne))tris(phenolato-.kappa.O))(3-))-
Class:
4.1
Packaging group:
II
Labels:
4.1
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Exposure controls / personal protection

Exposure limit values
Not tested

Technical measures/precautions:
No special technical protective measures required.

Respiratory protection:
Dustmask.

Hand protection:
Protective gloves.

Eye protection:
Safety glasses with side-shields.

Skin and body protection:
Working clothes.
Closed footwear.

Stability and reactivity

Decomposition temperature:
90 - 350 °C (with air (Grewer))

Conditions to avoid:
Avoid electro-static discharge.

Materials to avoid:
strong acids, strong bases, strong oxidizing agents

Disposal considerations

Waste from residue/unused products:
Residual chemical should be disposed by incineration or by other modes of disposal in compliance with local legislation.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product. Dispose of in accordance with national, state and local regulations. Clean packaging material should be subjected to waste management schemes (recovery recycling, reuse) according to local legislation.