Registration Dossier

Administrative data

First-aid measures

Description of first aid measures

General information
Remove contaminated clothing immediately and dispose of safely.

After contact with skin
In case of contact with skin wash off immediately with soap and water

After contact with eyes
In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice

After ingestion
Summon a doctor immediately.

Most important symptoms and effects, both acute and delayed

Symptoms
No additional symptoms are known except those derived from the labelling (see section 2).

Indication of any immediate medical attention and special treatment needed

Treatment
If swallowed, flush stomach.

Fire-fighting measures

Suitable extinguishing media
water mist
foam
dry powder
carbon dioxide

Extinguishing media that must not be used for safety reasons
Not applicable

Special hazards arising from the substance or mixture
In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO)
Carbon dioxide (CO2)
Phosphorus oxides (eg Phosphorus pentoxide)

Advice for firefighters

Special protective equipment for firefighting
Use self-contained breathing apparatus
In case of fire, use acid-resistant equipment / personal protective equipment.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

Wear personal protective equipment. Unprotected persons must be kept away.
Avoid any contact with the product.

Environmental precautions

Do not allow entry to drains,water courses or soil

Methods and material for containment and cleaning up

Pick up with absorbent material (eg sand, kieselgur, acid binder, universal binder, sawdust).
Dispose of contaminated material as prescribed

Handling and storage

Precautions for safe handling

Hygiene measures
Remove soiled or soaked clothing immediately.
Clean skin thoroughly after work; apply skin cream.

Advice on protection against fire and explosion
No special measures necessary

Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers
Keep only in the original container

Further information on storage conditions
Protect from atmospheric moisture and water

Specific end use(s)

No further recommendations.

Transport information

Land transport (ADR/RID)

UN number:
3265
Proper shipping name and description:
Corrosive liquid, acidic, organic, n.o.s.
Chemical name:
PHOSPHORIC ACID MONOMETHYL ESTER
Phosphoric acid
Language:
English
Class:
8
Classification code:
C3
Packaging group:
III
Labels:
corrosive
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3265
Proper shipping name and description:
Corrosive liquid, acidic, organic, n.o.s.
Chemical name:
PHOSPHORIC ACID MONOMETHYL ESTER
Phosphoric acid
Language:
English
Class:
8
Classification code:
C3
Packaging group:
III
Labels:
corrosive
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3265
Proper shipping name and description:
Corrosive liquid, acidic, organic, n.o.s.
Chemical name:
PHOSPHORIC ACID MONOMETHYL ESTER
Phosphoric acid
Class:
8
Packaging group:
III
EmS code:
F-A S-B
Labels:
corrosive
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3265
Proper shipping name and description:
Corrosive liquid, acidic, organic, n.o.s.
Chemical name:
PHOSPHORIC ACID MONOMETHYL ESTER
Phosphoric acid
Class:
8
Packaging group:
III
Labels:
corrosive
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

General protective measures
Avoid contact with eyes and skin

Hand protection : Nitrile rubber gloves.
Minimum breakthrough time / gloves : > 120 min
Minimum thickness / gloves 0,35 mm
Butyl rubber gloves.
Minimum breakthrough time / gloves : > 120 min
Minimum thickness / gloves 0,5 mm

These types of protective gloves are offered by various manufacturers. Please note the manufacturers´ detailed statements, especially about the minimum thickness and the minimum breakthrough time. Consider also the particular working conditions under which the gloves are being used.

Eye protection : safety glasses

Body protection : acid-proof protective clothing

Stability and reactivity

Reactivity

Reactions with strong alkalies.
Exothermic reaction.

Chemical stability

Stable.

Possibility of hazardous reactions

Reactions with strong alkalies.
Exothermic reaction.

Conditions to avoid

None known.

Incompatible materials

Avoid contact with alkaline materials.

Hazardous decomposition products

Flammable gases/vapours

Disposal considerations

Waste treatment methods

Product
In accordance with local authority regulations, take to special waste incineration plant

Uncleaned packaging
Uncontaminated packaging may be taken for recycling