Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

- General information:
Immediately remove any clothing soiled by the product.
Take affected persons out into the fresh air.
Seek immediate medical advice.

- After inhalation:
In case of unconsciousness place patient stably in side position for transportation.
Provide oxygen treatment if affected person has difficulty breathing.
If not breathing, give artificial respiration, preferably mouth to mouth.

- After skin contact:
After contact with skin, wash immediately almost 15 minutes with plenty of water.
- After eye contact:
Rinse opened eye for almost 15 minutes under running water.

- After swallowing: Rinse mouth out with water.

- Emergency equipment
Provide wash facilities for eyes and skin near work area.

Fire-fighting measures

- Suitable extinguishing agents:
Carbon dioxide, dry chemicals, foam, water spray (mist).
Use fire extinguishing methods suitable to surrounding conditions.

- For safety reasons unsuitable extinguishing agents: Water with full jet

- Special hazards caused by the substance, its products of combustion or resulting gases:
High temperatures may liberate toxic or corrosive gases. Do not breathe smoke or vapours.

- Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.

Accidental release measures

- Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
- Measures for environmental protection:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Prevent from spreading (e.g. by damming-in or oil barriers).

- Measures for cleaning/collecting:
Take up small spills with dry chemical absorbent.
Large spills may be taken up with pump or vacuum and finished off with dry chemical absorbent.
May require excavation of contaminated soil. Shovel up residues and place in a labelled sealable container for subsequent safe disposal.
Put leaking container into a labelled drum or overdrum

Handling and storage

- Handling:
- Information for safe handling:
Handle in accordance with good industrial hygiene and safety procedures.
- Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Use explosion-proof apparatus / fittings and spark-proof tools.

- Storage:
- Requirements to be met by storerooms and receptacles:
Store in dry, cool, well-ventilated area.
Mechanical ventilation is recommended.
- Information about storage in one common storage facility: Not required.
- Further information about storage conditions:
Keep container tightly sealed.

Transport information

Land transport (ADR/RID)

UN number:
1993
Shippingopen allclose all
Class:
3
Classification code:
30
Packaging group:
III
Labels:
3
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
1993
Shippingopen allclose all
Class:
3
Classification code:
30
Packaging group:
III
Labels:
3
Remarksopen allclose all

Marine transport (IMDG)

UN number:
1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S. (1-bromopentane)
Chemical name:
1-bromopentane
Class:
3
Packaging group:
III
EmS code:
F-E,S-E
Labels:
3
Remarks
Marpol II: Not determinated - Marpol III: Not regulated

Air transport ICAO/IATA

UN number:
1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S. (1-bromopentane)
Chemical name:
1-bromopentane
Class:
3
Packaging group:
III
Labels:
3
Remarks
Aircraft Passenger: 60l - Aircraft Cargo: 220l
SpecialProvisionsopen allclose all

Exposure controls / personal protection

- Additional information about design of technical facilities:
No further data; see item 7.

Ingredients with limit values that require monitoring at the workplace:
Not required.
- Additional information:
The lists valid during the making were used as basis.

- Personal protective equipment:
- General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the skin.
Avoid contact with the eyes and skin.

- Respiratory protection: Not required.

- Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/
the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be
given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
- Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
- Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
- Eye protection: Tightly sealed goggles
- Body protection: Use protective suit.

Stability and reactivity

- Thermal decomposition / conditions to be avoided:
Stable under normal conditions of use.
Keep ignition sources away - Do not smoke.

- Materials to be avoided: Reacts with oxidizing agents.
- Dangerous reactions No dangerous reactions known.

- Dangerous decomposition products:
Carbon monoxide and carbon dioxide
Hydrogen bromide

Disposal considerations

- Product:
- Recommendation
Must not be disposed together with household garbage. Do not allow
product to reach sewage system.

- Uncleaned packaging:
- Recommendation:
Disposal must be made according to official regulations.