Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

General advice :
Move out of dangerous area.
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.

If inhaled :
If unconscious, place in recovery position and seek medical advice.
If symptoms persist, call a physician.
In case of skin contact :
If skin irritation persists, call a physician.
If on skin, rinse well with water.
If on clothes, remove clothes.

In case of eye contact :
Small amounts splashed into eyes can cause irreversible tissue damage and blindness.
In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.

If swallowed :
Keep respiratory tract clear.
Do NOT induce vomiting.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Take victim immediately to hospital.

Most important symptoms and effects, both acute and delayed :
None known.

Fire-fighting measures

Suitable extinguishing media :
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media :
High volume water jet

Specific hazards during firefighting :
Do not allow run-off from fire fighting to enter drains or water courses.

Hazardous combustion products :
No hazardous combustion products are known

Specific extinguishing methods :
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local
regulations.

Special protective equipment for firefighters :
Wear self-contained breathing apparatus for firefighting if necessary.

Accidental release measures

Personal precautions, protective equipment and emergency procedures :
Use personal protective equipment.
Evacuate personnel to safe areas.
Ensure adequate ventilation.
In case of inadequate ventilation wear respiratory protection.

Environmental precautions :
Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform respective authorities.

Methods and materials for containment and cleaning up :
Neutralise with acid.
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.

Handling and storage

Advice on protection against fire and explosion :
Normal measures for preventive fire protection.

Advice on safe handling :
Do not breathe vapours/dust.
Avoid contact with skin and eyes.
Smoking, eating and drinking should be prohibited in the application area.
To avoid spills during handling keep bottle on a metal tray.
Dispose of rinse water in accordance with local and national regulations.

Conditions for safe storage :
Keep container tightly closed in a dry and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Electrical installations / working materials must comply with the technological safety standards.

Materials to avoid :
Keep away from strong acids.

Further information on storage stability :
No decomposition if stored and applied as directed.

Transport information

Land transport (ADR/RID)

UN number:
UN3082
Shippingopen allclose all
Class:
9
Classification code:
M6
Packaging group:
III
Labels:
9 + environmental label
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Chemical name:
Trimethylolpropane poly(oxypropylene) triamine
Class:
9
Packaging group:
III
EmS code:
F-A, S-F
Labels:
9 + environmental label
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Chemical name:
Trimethylolpropane poly(oxypropylene) triamine
Class:
9
Packaging group:
III
Labels:
9 + environmental label
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Stability and reactivity

Disposal considerations