(3E)-dec-3-en-2-one

Guidance on Safe Use

First-aid measures

- General advice:

When administering first aid, ensure that you are wearing the appropriate personal protective equipment according to the incident, injury and surroundings.

- Following inhalation:

Remove to fresh air. Do not attempt to rescue the victim unless proper respiratory protection is worn. If the victim has difficulty breathing or tightness of the chest, is dizzy, vomiting, or unresponsive, give 100% oxygen with rescue breathing or Cardio-Pulmonary Resuscitation as required and transport to the nearest medical facility.

- Following skin contact:

Remove contaminated clothing. Immediately flush skin with large amounts of water for at least 15 minutes, and follow by washing with soap and water if available. If redness, swelling, pain and/or blisters occur, transport to the nearest medical

facility for additional treatment. When using high pressure equipment, injection of product under the skin can occur. If high pressure injuries occur, the casualty should be sent immediately to a hospital. Do not wait for symptoms to develop. Obtain medical attention even in the absence of apparent wounds.

- Following eye contact:

Flush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention.

- Following ingestion:

If swallowed, do not induce vomiting: transport to nearest medical facility for additional treatment. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. If any of the following delayed signs and symptoms appear within the next 6 hours, transport to the nearest medical facility: fever greater than 101° F (38.3°C), shortness of breath, chest congestion or continued coughing or wheezing.

- Most important symptoms and effects: If material enters lungs, signs and symptoms may include coughing, choking, wheezing, difficulty in breathing, chest congestion, shortness of breath, and/or fever. The onset of respiratory symptoms may be delayed for several hours after exposure. Skin irritation signs and symptoms may include a burning sensation, redness, swelling, and/or blisters. Defatting dermatitis signs and symptoms may include a burning sensation and/or a dried/cracked appearance. Ingestion may result in nausea, vomiting and/or diarrhoea. Local necrosis is evidenced by delayed onset of pain and tissue damage a few hours following injection.

Fire-fighting measures

- Suitable extinguishing media:

Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only.

- Unsuitable extinguishing media:

Do not use water in a jet.

- Special hazards arising from the substance or mixture:

Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide may be evolved if incomplete combustion occurs. Unidentified organic and inorganic compounds.

- Advice for fire fighter: Proper protective equipment including chemical resistant gloves are to be worn; chemical resistant suit is indicated if large contact with spilled product is expected. Self-Contained Breathing Apparatus must be worn when approaching a fire in a confined space. Select fire fighter's clothing approved to relevant Standards (e.g. Europe: EN469).

- Specific extinguishing methods: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Accidental release measures

- Personal precautions:

6.1.1 For non emergency personnel: Avoid contact with skin and eyes.

6.1.2 For emergency responders: Avoid contact with skin and eyes.

- Environmental precautions:

Use appropriate containment to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. Local authorities should be advised if significant spillages cannot be contained.

- Methods and material for containment and cleaning up: Slippery when spilt. Avoid accidents, clean up immediately. Prevent from spreading by making a barrier with sand, earth or other containment material. Reclaim liquid directly or in an absorbent. Soak up residue with an absorbent such as clay, sand or other suitable material and dispose of properly.

Handling and storage

- Precautions for safe handling:

Use local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Use the information in this data sheet as i put to a risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material.

Advice on safe handling : Avoid prolonged or repeated contact with skin. Avoid inhaling vapour and/or mists. When handling product in drums, safety footwear should be worn and proper handling equipment should be used. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires.

Product Transfer : This material has the potential to be a static accumulator. Proper grounding and bonding procedures should be used during all bulk transfer operations.

- Conditions for safe storage, including any incompatibilities:

Other data : Keep container tightly closed and in a cool, well-ventilated place. Use properly labeled and closable containers. Must be stored in a diked (bunded) area. Store at ambient temperature. Refer to section 15 for any additional specific legislation covering the packaging and storage of this product. The storage of this product may be subject to the Control of Pollution (Oil Storage) (England) Regulations. Further guidance may be obtained from the local environmental agency office.

Packaging material : Suitable material: For containers or container linings, use mild steel or high density polyethylene.

Unsuitable material: PVC.

Container Advice : Polyethylene containers should not be exposed to high temperatures because of possible risk of distortion.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

3082

Shipping

Labels:

9

SpecialProvisions

Shipping

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

3082

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

Chemical name:

3-decen-2-one

Labels:

9

Marine pollutant

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

3082

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.

Chemical name:

3-decen-2-one

Labels:

9

Remarks

SpecialProvisions

Exposure controls / personal protection

Engineering measuresThe level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Adequate ventilation to control airborne concentrations. Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated.

General Information: Define procedures for safe handling and maintenance of controls. Educate and train workers in the hazards and control measures relevant to normal activities associated with this product. Ensure appropriate selection, testing and maintenance of equipment used to control exposure, e.g. personal protective equipment, local exhaust ventilation. Drain down system prior to equipment break-in or maintenance. Retain drain downs in sealed storage pending disposal or subsequent recycle. Always observe good personal hygiene measures, such as washing hands after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. Do not ingest. If swallowed then seek immediate medical assistance

3. Hand protection: Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection. PVC, neoprene or nitrile rubber gloves Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. For continuous contact we recommend gloves with breakthrough time of more than 240 minutes with preference for > 480 minutes where suitable gloves can be identified. For short-term/splash protection we recommend the same, but recognize that suitable gloves offering this level of protection may not be available and in this case a lower breakthrough time maybe acceptable so long as appropriate maintenance and replacement regimes are followed. Glove thickness is not a good predictor of glove resistance to a chemical as it is dependent on the exact composition of the glove material. Glove thickness should be typically greater than 0.35 mm depending on the glove make and model.

4. Feet protection: not specified

5. Body protection: Wear chemical resistant gloves/gauntlets and boots. Where risk of splashing, also wear an apron.

6. Eye protection: If material is handled such that it could be splashed into eyes, protective eyewear is recommended. Approved to EU Standard EN166.

7. Respiratory protection: No respiratory protection is ordinarily required under normal

conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid breathing of material. If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. Select a filter suitable for combined particulate/organic gases and vapours [Type A/Type P boiling point > 65°C (149°F)] meeting EN14387 and EN143.

Environmental exposure controls:

Take appropriate measures to fulfill the requirements of relevant environmental protection legislation. Avoid contamination of the environment. If necessary, prevent undissolved material from being discharged to waste water. Waste water should be treated in a municipal or industrial waste water treatment plant before discharge to surface water. Local guidelines on emission limits for volatile substances must be observed for the discharge of exhaust air containing vapour.

Stability and reactivity

1. Reactivity

: The product does not pose any further reactivity hazards

2. Chemical stability

: Stable. No hazardous reaction is expected when handled and stored according to provisions

3. Possibility of hazardous reactions

: Reacts with strong oxidising agents.

4. Conditions to avoid

: Extremes of temperature and direct sunlight.

5. Incompatible materials

: Strong oxidising agents.

6. Hazardous decomposition products: Hazardous decomposition products are not expected to form during normal storage.

Disposal considerations

Product : Recover or recycle if possible.

It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations. Do not dispose into the environment, in drains or in water courses Contaminated packaging : Dispose in accordance with prevailing regulations, preferably to a recognized collector or contractor. The competence of the collector or contractor should be established beforehand. Disposal should be in accordance with applicable regional, national, and local laws and regulations.

Waste Code : 13 01 10

Disposal should be in accordance with applicable regional, national, and local laws and regulations. Classification of waste is always the responsibility of the end

user.