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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
October,10 to November 04 2016
Reliability:
1 (reliable without restriction)

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2016
Report date:
2016

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
DIN 51794 (Testing of mineral oil hydrocarbons - Determination of ignition temperature)
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
ethyl 2-cyclopentylidene-3-oxobutanoate
EC Number:
812-640-5
Cas Number:
95296-11-0
Molecular formula:
C11H16O3
IUPAC Name:
ethyl 2-cyclopentylidene-3-oxobutanoate
Constituent 2
Chemical structure
Reference substance name:
ethyl 2-(cyclopent-1-en-1-yl)-3-oxobutanoate
Molecular formula:
C11H16O3
IUPAC Name:
ethyl 2-(cyclopent-1-en-1-yl)-3-oxobutanoate
Specific details on test material used for the study:
Aspect: Colourless to pale yellow liquid
Lot No: SC00018589
Purity: 93.8% (sum of the 3 peaks)
Expiration date: June 07,2020

Results and discussion

Auto-ignition temperature (liquids / gases)
Key result
Auto-ignition temperature:
390 °C
Atm. press.:
1 013 hPa

Applicant's summary and conclusion

Conclusions:
The lowest temperature giving a positive effect was 394°C. The injected volume was 100 microL, the ignition delay was 0 s. At a temperature of 389°C no ignition was observed.
Therefore, after rounding off to the next lower multiple of 5.0°C : Auto ignition temperature of Ethyl Cyclopentilidene Acetoacetate is 390°C +/- 10°C.
Executive summary:

The auto ignition temperature of Ethyl Cyclopentylidene Acetoacetate was determined in a SUR BERLIN oven, equipped with a 250 ml glass ignition vessel according to the DIN 51794.

The lowest temperature giving a positive effect was 394°C. The injected volume was 100 microL, the ignition delay was 5 s. At a temperature of 389°C no ignition was observed.

Therefore, after rounding off to the next lower multiple of 5.0°C : Auto ignition temperature of Ethyl Cyclopentylidene Acetoacetate is 390°C +/- 10°C.