Registration Dossier
Registration Dossier
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 813-789-9 | CAS number: 152873-67-1
Boiling point
Administrative data
- Endpoint:
- boiling point
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 2018-07-11 to 2018-10-22
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 018
- Report date:
- 2018
Materials and methods
Test guidelineopen allclose all
- Qualifier:
- equivalent or similar to guideline
- Guideline:
- OECD Guideline 103 (Boiling point/boiling range)
- Qualifier:
- equivalent or similar to guideline
- Guideline:
- EU Method A.2 (Boiling Temperature)
- Qualifier:
- equivalent or similar to guideline
- Guideline:
- EPA OPPTS 830.7220 (Boiling Point / Boiling Range)
- GLP compliance:
- no
- Type of method:
- method according to Siwoloboff
Test material
- Reference substance name:
- (2Z)-2-fluoro-3-(morpholin-4-yl)prop-2-enal
- EC Number:
- 813-789-9
- Cas Number:
- 152873-67-1
- Molecular formula:
- C7H10FNO2
- IUPAC Name:
- (2Z)-2-fluoro-3-(morpholin-4-yl)prop-2-enal
- Test material form:
- solid
Constituent 1
- Specific details on test material used for the study:
- Name: (2Z)-2-Fluor-3-(morpholin-4-yl)acrylaldehyd (FMA)
Lot Number: BXR82PT
CAS No.: 152873-67-1
Sponsor No. 2950024288
Aggregate State at Room Temperature: Solid
Colour: Brown
Expiry Date: November 01, 2018
Storage Conditions at Test Facility: At 20 °C ± 5 °C, in the dark
Results and discussion
Boiling point
- Key result
- Atm. press.:
- 99.08 kPa
- Decomposition:
- yes
- Decomp. temp.:
- ca. 220 °C
- Remarks on result:
- other: colour changing to black was observed
Applicant's summary and conclusion
- Conclusions:
- A decomposition process at approximately 220 °C is assumed. A clear normal boiling point, as defined in the guideline with a current stream of bubbles evolving from the capillary, was not observed.
In conclusion, for (2Z)-2-Fluor-3-(morpholin-4-yl)acrylaldehyd (FMA) no boiling point according to the criteria described in the guideline could be observed up to 400 °C. The atmospheric pressure was 99.08 kPa. - Executive summary:
Title:
(2Z)-2-Fluor-3-(morpholin-4-yl)acrylaldehyd (FMA): Determination of the Boiling Point
Purpose:
The purpose of this study was to evaluate the boiling point of (2Z)-2-Fluor-3-(morpholin-4-yl)acrylaldehyd (FMA) by the capillary method using an electronic controlled heating system.
Guidelines/Recommendations
This study was based on the procedures indicated by the following internationally accepted methods:
-Commission Regulation (EC) No.440/2008 laying down test methods pursuant to Regulation (EC) No.1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (originally published as Council Regulation (EC) No.440/2008, corrigendum according to Official Journal of the European Union (EN) dated June 3, 2008, L 143/55), Annex, Part A, A.2.: “Boiling Temperature”, Official Journal of the European Union, L 142, Volume 51, 31 May 2008
-Organization for Economic Co-operation and Development (OECD), Guidelines for Testing of Chemicals, Guideline No.103, “Boiling Point”, adopted July 27, 1995
-Product Properties Test Guideline OPPTS 830.7220 of the United States Environment Protection Agency (EPA), August 1996
Results:
The determination of the boiling point was performed by visual judgement using the capillary. At about 200 °C to 265 in the preliminary tests, the colour changing to black was observed and the test item melted. To confirm the results from the preliminary tests, the test was performed three times with the new sample and with the heating rate of 0.5 °C/min; start temperatures were: 215 °C, 220 °C and 225 °C and end temperature was 265°C. Due to this observation, a decomposition process at approximately 220 °C is assumed. A clear normal boiling point, as defined in the guideline with a current stream of bubbles evolving from the capillary, was not observed.
Conclusion: In conclusion, for (2Z)-2-Fluor-3-(morpholin-4-yl)acrylaldehyd (FMA) no boiling point according to the criteria described in the guideline could be observed up to 400 °C. The atmospheric pressure was 99.08 kPa. This study is classified acceptable and satisfies the guideline requirements for boiling point studies.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
