Reaction productReaction product of 1,1´-Methylenebis(4-substituted cyclohexane), [2-(substitutedmethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate and [3-prop-2-substituted-2,2-bis(prop-2-enoyloxymethyl)propyl] prop-2-enoate

Auto flammability

Administrative data

Endpoint:

auto-flammability

Type of information:

experimental study

Adequacy of study:

key study

Study period:

03 January 2012- 19 March 2012

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

other: The study has been performed according to the appropriate guidelines and according to the principles of GLP.

Data source

Reference

Reference Type:

study report

Title:

Unnamed

Year:

2012

Report date:

2012

Materials and methods

Test guideline

Test guideline 1

Qualifier:

according to guideline

Guideline:

EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))

Version / remarks:

(2008)

Deviations:

no

Test guideline 2

Qualifier:

according to guideline

Guideline:

other: DIN Guide 51794: "Determining the Ignition Temperature of Petroleum Products" (2003)

Deviations:

no

Test guideline 3

Qualifier:

according to guideline

Guideline:

other: IEC standard 79-4: "Electrical Apparatus for Explosive Gas Atmospheres, Part 4, Method of Test for Ignition Temperature" ( 1975)

Deviations:

no

GLP compliance:

yes (incl. QA statement)

Test material

Test material information

Constituent 1

Details on test material:

- Physical state: Clear colourless/slightly yellow, sticky resin
- Stability under test conditions: Stable
- Storage condition of test material: At room temperature protected from light
-Stability at higher temperatures: Maximum 1 month at 50°C
- General information: Avoid heat, direct sunlight, acid and base

Results and discussion

Auto-ignition temperature (liquids / gases)

Auto-ignition temperature:

460 °C

Atm. press.:

1 015.9 - 1 024.5 hPa

Remarks on result:

other: The lowest temperature at which ignition of the test substance occurred was 461°C. This temperature was rounded off to the nearest multiple of 5°C.

Any other information on results incl. tables

With each test a minimum auto-ignition temperature was obtained. The maximum deviation between the three values was < 20°C.

 

Table    Main study –auto-ignition temperature of the test substance

 

Test	Volume [μl]	Auto-ignition temperature [°C]	Ignition delay [s]	Colour of the flame	Minimum auto-ignition temperature [°C]
1	70	494	12	orange/blue	466
	150	479	20	orange/blue
	250	474	16	orange/blue
	500	466	14	orange/blue
	1000	469	18	orange/blue
2	120	488	13	orange/blue	461
	600	461	17	orange/blue
	900	467	17	orange/blue
3	100	491	17	orange/blue	464
	650	464	23	orange/blue
	800	465	19	orange/blue

 

 

Applicant's summary and conclusion

Conclusions:

The test substance is auto-ignitable with an auto-ignition temperature of 460°C at 1015.9 – 1024.5 hPa.