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Physical & Chemical properties

Auto flammability

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
From December 2015 to 2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Version / remarks:
2008
Deviations:
no
Qualifier:
according to guideline
Guideline:
DIN 51794 (Testing of mineral oil hydrocarbons - Determination of ignition temperature)
Version / remarks:
2003
Deviations:
no
Qualifier:
according to guideline
Guideline:
IEC 60079-4 (Electrical apparatus for explosive gas atmospheres. Part 4: Method of test for ignition temperature)
Version / remarks:
1975
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Key result
Auto-ignition temperature:
175 °C
Atm. press.:
> 1 006.9 - < 1 013.4 hPa

Preliminary test:

The auto-ignition temperature was estimated to be 225°C.

Main study:

 Test  Volume of sample (µl)  Auto-ignition temperature (°C)  Minimum auto-ignition temperature (°C)

1

70 226  179 
150 201
300 190 
600  179 
800 182 
2 250  187 178 
500 178 
900  185 
3 350   186 181 
700   181
1000   192

The all the test, the ignition delay was inferior to 2 minutes and the color of the flame observed was blue.

The deviation between the values obtained in the three tests was lower than 10°C. According to the guidelines, no further testing was required.

The lowest temperature at which inginition occured was 178°C. This temperature was rounded down to the nearest multiple of 5°C giving an auto-ignition temperature of 175°C.

Conclusions:
The auto-ignition temperature of the test item is 175°C at1006.9 to 1013.4 hPa.
Executive summary:

The auto-ignition temperature was determined according to recognized guidelines (Eu method A.15, DIN 51794 and IEC 60079.4) and under GLP.

No deviation from the guidelines was observed during the test.

The behaviour of the test item was studied in a preliminary test. Then a main study, consiting of 3 tests was performed.

The auto-ignition temperature of the test item is 175°C at 1006.9 hPa to 1013.4hPa.

Description of key information

The auto-ignition temperature was determined according to recognized guidelines (EU method A.15, DIN 51794 and IEC 60079.4) and under GLP.

No deviation from the guidelines was observed during the test.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
175 °C

Additional information