Registration Dossier
Registration Dossier
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EC number: 610-150-4 | CAS number: 438193-30-7
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures:
Symptoms of poisoning may only appear several hours later.
If you feel unwell, seek medical advice (show the label where possible).
Remove contaminated or saturated clothing immediately and dispose of safely.
Inhalation:
Provide fresh air, seek medical advice if necessary.
Place patients at risk of losing consciousness in stabilized lateral position; artificial respiration as required.
Skin contact:
Wash off with plenty of water and soap immediately.
Eye contact:
Rinse immediately with plenty of water for 15 minutes and seek advice of an eye specialist.
Ingestion:
Do not induce vomiting.
Call a physician immediately.
Drink 1 or 2 glasses of water.
Most important symptoms and effects, both acute and delayed:
Indication of any immediate medical attention and special treatment needed:
Treatment of symptoms.
Symptoms of poisoning may only appear several hours later.
If you feel unwell, seek medical advice (show the label where possible).
Remove contaminated or saturated clothing immediately and dispose of safely.
Inhalation:
Provide fresh air, seek medical advice if necessary.
Place patients at risk of losing consciousness in stabilized lateral position; artificial respiration as required.
Skin contact:
Wash off with plenty of water and soap immediately.
Eye contact:
Rinse immediately with plenty of water for 15 minutes and seek advice of an eye specialist.
Ingestion:
Do not induce vomiting.
Call a physician immediately.
Drink 1 or 2 glasses of water.
Most important symptoms and effects, both acute and delayed:
Indication of any immediate medical attention and special treatment needed:
Treatment of symptoms.
Fire-fighting measures
Suitable extinguishing media:
Water spray, foam, CO2, dry powder.
Unsuitable extinguishing media:
Do not use a solid water stream as it may scatter and spread fire.
Special hazards arising from the substance or mixture:
In the case of fire, the following hazardous smoke fumes may be produced:
Oxides of phosphorus
Carbon dioxide (CO2)
Carbon monoxide
May be released in case of fire: hydrogen iodide.
Special protective equipment for fire-fighters:
Wear a self contained respiratory apparatus.
Full protective suit.
Advice for firefighters:
Contaminated extinguishing water must be treated at a suitable disposal plant in accordance with waste management laws.
In case of fire, remove the endangered barrels and bring to a safe place, if this can be done safely.
Keep out unprotected persons.
Water spray, foam, CO2, dry powder.
Unsuitable extinguishing media:
Do not use a solid water stream as it may scatter and spread fire.
Special hazards arising from the substance or mixture:
In the case of fire, the following hazardous smoke fumes may be produced:
Oxides of phosphorus
Carbon dioxide (CO2)
Carbon monoxide
May be released in case of fire: hydrogen iodide.
Special protective equipment for fire-fighters:
Wear a self contained respiratory apparatus.
Full protective suit.
Advice for firefighters:
Contaminated extinguishing water must be treated at a suitable disposal plant in accordance with waste management laws.
In case of fire, remove the endangered barrels and bring to a safe place, if this can be done safely.
Keep out unprotected persons.
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Wear personal protective equipment.
Avoid formation of dust.
Ensure sufficient ventilation.
Environmental precautions:
Do not allow to sink into ground water, sewers or into surface water.
If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and material for containment and cleaning up:
Collect up material.
Transfer into suitable containers for recovery or disposal.
Disposal according to local authority regulations.
Avoid dust formation.
Wear personal protective equipment.
Avoid formation of dust.
Ensure sufficient ventilation.
Environmental precautions:
Do not allow to sink into ground water, sewers or into surface water.
If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and material for containment and cleaning up:
Collect up material.
Transfer into suitable containers for recovery or disposal.
Disposal according to local authority regulations.
Avoid dust formation.
Handling and storage
Handling:
Precautions for safe handling:
Refill and handle product only in closed system.
Provide sufficient ventilation and exhaust at the workplace.
Ensure that apparatus and pipelines are free from leaks.
Do not ventilate into the open.
Trained personnel must be used.
Advice on protection against fire and explosion:
General rules of fire prevention should be observed.
Storage:
Conditions for safe storage, including any incompatibilities:
Keep tightly sealed in original packing.
Use shatterproof containers.
Secure container from falling down.
Keep in a dry, cool and well-ventilated place.
Further information:
Keep containers tightly closed in a dry, cool and well-ventilated place.
Advice on common storage:
No special precautions required.
German storage class
10-13 Combustible / non-combustible liquids and solids not assigned to other storage classes.
Precautions for safe handling:
Refill and handle product only in closed system.
Provide sufficient ventilation and exhaust at the workplace.
Ensure that apparatus and pipelines are free from leaks.
Do not ventilate into the open.
Trained personnel must be used.
Advice on protection against fire and explosion:
General rules of fire prevention should be observed.
Storage:
Conditions for safe storage, including any incompatibilities:
Keep tightly sealed in original packing.
Use shatterproof containers.
Secure container from falling down.
Keep in a dry, cool and well-ventilated place.
Further information:
Keep containers tightly closed in a dry, cool and well-ventilated place.
Advice on common storage:
No special precautions required.
German storage class
10-13 Combustible / non-combustible liquids and solids not assigned to other storage classes.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ([trans-4-(1E)-1-Propenylcyclohexyl]methyl-triphenylphosphonium-iodide)
- Chemical name:
- ([trans-4-(1E)-1-Propenylcyclohexyl]methyl-triphenylphosphonium-iodide)
- Language:
- English
- Labels:
- 9
Special provisions / remarks
- Special provisions:
- Tunnel Restriction Code (ADR): (E)
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ([trans-4-(1E)-1-Propenylcyclohexyl]methyl-triphenylphosphonium-iodide)
- Chemical name:
- ([trans-4-(1E)-1-Propenylcyclohexyl]methyl-triphenylphosphonium-iodide)
- Language:
- English
- Labels:
- 9
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ([trans-4-(1E)-1-Propenylcyclohexyl]methyl-triphenylphosphonium-iodide)
- Chemical name:
- [trans-4-(1E)-1-Propenylcyclohexyl]methyl-triphenylphosphonium-iodide
- Labels:
- 9
- Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ([trans-4-(1E)-1-Propenylcyclohexyl]methyl-triphenylphosphonium-iodide)
- Chemical name:
- [trans-4-(1E)-1-Propenylcyclohexyl]methyl-triphenylphosphonium-iodide
- Labels:
- 9
Special provisions / remarks
- Remarks:
- IATA_C: ERG-Code 9L
IATA_P: ERG-Code 9L
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Control parameters:
Engineering measures:
Refill and handle product only in closed system.
Do not add wastewater to a biological wastewater treatment plant.
Provide for installation of emergency shower and eye bath.
Ensure suitable suction/aeration at the work place and with operational machinery.
In case product dust is released:
Exhaust ventilation equipped with filters.
All precautionary measures indicated have to be observed.
Exposure controls:
Minimization of emissions by means of suitable technical measures such as flanges and valves with low leakage rates, recirculation of vapours.
The substance must be handled under strictly controlled conditions in accordance with Article 17/18 of the REACH Regulation.
Personal protective equipment:
Respiratory protection:
Accidental release measures:
In the case of respirable dust, use self-contained breathing apparatus.
Note time limit for wearing respiratory protective equipment.
Hand protection:
No protective glove type has been specified for use with this product.
The glove listed is only a preliminary recommendation issued by Kächele-Cama Latex GmbH, Am Kreuzacker 9, D-36124 Eichenzell, www.kcl.de, which firm offers such protective gloves.
The glove must be changed immediately if any changes in it occur (e.g. swelling, wear).
Accidental release measures:
Recommendation: Butoject 898.
Eye protection:
Safety glasses with side-shields conforming to EN166.
Accidental release measures:
Close-fitting protective goggles (e.g. closed goggles)
Skin and body protection:
Long sleeved clothing.
Accidental release measures:
One-way protective suit (dust-sealed).
Hygiene measures:
Remove contaminated or saturated clothing.
Provide adequate ventilation.
Avoid contact with skin and eyes.
No eating, drinking, smoking, or snuffing tobacco at work.
Wash face and/or hands before break and end of work.
Protective measures:
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates.
Risk assessment and risk monitoring of all work places required.
Health, Safety and Emergency Management System recommended.
Written approval necessary in case of non-routine jobs, e.g. maintenance activities.
Regular safety training is a must.
All precautionary measures indicated have to be observed.
Environmental exposure controls:
See ACCIDENTAL RELEASE MEASURES.
Engineering measures:
Refill and handle product only in closed system.
Do not add wastewater to a biological wastewater treatment plant.
Provide for installation of emergency shower and eye bath.
Ensure suitable suction/aeration at the work place and with operational machinery.
In case product dust is released:
Exhaust ventilation equipped with filters.
All precautionary measures indicated have to be observed.
Exposure controls:
Minimization of emissions by means of suitable technical measures such as flanges and valves with low leakage rates, recirculation of vapours.
The substance must be handled under strictly controlled conditions in accordance with Article 17/18 of the REACH Regulation.
Personal protective equipment:
Respiratory protection:
Accidental release measures:
In the case of respirable dust, use self-contained breathing apparatus.
Note time limit for wearing respiratory protective equipment.
Hand protection:
No protective glove type has been specified for use with this product.
The glove listed is only a preliminary recommendation issued by Kächele-Cama Latex GmbH, Am Kreuzacker 9, D-36124 Eichenzell, www.kcl.de, which firm offers such protective gloves.
The glove must be changed immediately if any changes in it occur (e.g. swelling, wear).
Accidental release measures:
Recommendation: Butoject 898.
Eye protection:
Safety glasses with side-shields conforming to EN166.
Accidental release measures:
Close-fitting protective goggles (e.g. closed goggles)
Skin and body protection:
Long sleeved clothing.
Accidental release measures:
One-way protective suit (dust-sealed).
Hygiene measures:
Remove contaminated or saturated clothing.
Provide adequate ventilation.
Avoid contact with skin and eyes.
No eating, drinking, smoking, or snuffing tobacco at work.
Wash face and/or hands before break and end of work.
Protective measures:
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates.
Risk assessment and risk monitoring of all work places required.
Health, Safety and Emergency Management System recommended.
Written approval necessary in case of non-routine jobs, e.g. maintenance activities.
Regular safety training is a must.
All precautionary measures indicated have to be observed.
Environmental exposure controls:
See ACCIDENTAL RELEASE MEASURES.
Stability and reactivity
Possibility of hazardous reactions:
Reaction with alkalis.
Conditions to avoid:
No decomposition if used as directed.
Incompatible materials:
Strong alkalis
Hazardous decomposition products:
No hazardous decomposition products known.
In case of fire hazardous decomposition products may be produced such as: Carbon oxides, hydrogen iodide.
Reaction with alkalis.
Conditions to avoid:
No decomposition if used as directed.
Incompatible materials:
Strong alkalis
Hazardous decomposition products:
No hazardous decomposition products known.
In case of fire hazardous decomposition products may be produced such as: Carbon oxides, hydrogen iodide.
Disposal considerations
Product:
Strictly controlled conditions during disposal or treatment to air, wastewater and waste.
Do not add wastewater to a biological wastewater treatment plant.
Bring used exhaust air filter for incineration.
Disposal according to local authority regulations.
Uncleaned packaging:
Dispose of as unused product.
Strictly controlled conditions during disposal or treatment to air, wastewater and waste.
Do not add wastewater to a biological wastewater treatment plant.
Bring used exhaust air filter for incineration.
Disposal according to local authority regulations.
Uncleaned packaging:
Dispose of as unused product.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
