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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
explosiveness, other
Remarks:
sensitiveness to impact and friction; effects of heating and ignition under confinement
Type of information:
experimental study
Adequacy of study:
key study
Study period:
From 03/07/2003 to 17/07/2003
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2003
Report date:
2003

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
UN Manual of Tests and Criteria: Part I: Classification procedures, test methods and criteria relating to explosives of Class 1
Qualifier:
according to guideline
Guideline:
other: AFNOR NF T 70-506
Version / remarks:
UN-MTC, part 1 type 1(b)
Qualifier:
according to guideline
Guideline:
other: AFNOR NF T 70-500
Version / remarks:
UN-MTC, part 1 type 3(a)
Qualifier:
according to guideline
Guideline:
other: AFNOR NF T 70-503
Version / remarks:
UN-MTC, part 1 type 3(b)
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
Pyrrolidine, 1-[2-[2-nitro-4-(phenylmethoxy)phenyl]ethenyl]-
Cas Number:
99474-22-3
Molecular formula:
C19H20N2O3
IUPAC Name:
Pyrrolidine, 1-[2-[2-nitro-4-(phenylmethoxy)phenyl]ethenyl]-
Test material form:
solid: particulate/powder
Details on test material:
Rèf: OP 05508666/1
Dry powder
Specific details on test material used for the study:
Rèf: OP 05508666/1
Dry powder

Results and discussion

Results of test series for explosivesopen allclose all
Key result
Test series:
UN Test series 1
Method:
UN Test 1 (b): Koenen test
Parameter:
limiting diameter (mm)
Result:
result is considered "-" (negative)
Remarks on result:
other: limiting diameter < 1 mm ; no fragment observed
Key result
Test series:
UN Test series 1
Method:
UN Test 3 (a) (ii): BAM Fallhammer
Parameter:
limiting impact energy (J)
Result:
result is considered "-" (negative)
Remarks on result:
limiting impact energy > 40 J
Key result
Test series:
UN Test series 1
Method:
UN Test 3 (b) (i): BAM friction apparatus
Parameter:
limiting load (N)
Result:
result is considered "-" (negative)
Remarks on result:
other: 0 positive tests from 30 to 353 N

Any other information on results incl. tables

- UN-MTC part 1 type 1(b): Limiting diameter < 1 mm; no fragment observed

- UN-MTC part 1 type 3(a): No positif test between 30 to 50.1 J.

- UN-MTC part 1 type 3(b): No positif tests between 30 to 353 N.

Applicant's summary and conclusion

Interpretation of results:
GHS criteria not met
Conclusions:
- UN-MTC part 1 type 1(b): Limiting diameter < 1 mm; no fragment observed
- UN-MTC part 1 type 3(a): No positif test between 30 to 50.1 J.
- UN-MTC part 1 type 3(b): No positif tests between 30 to 353 N.
Executive summary:

The sensitiveness to impact and friction; effects of heating and ignition under confinement of the test item has been assessed in accordance with the UN-MTC part1. The following results had been obtained:

- UN-MTC part 1 type 1(b): Limiting diameter < 1 mm; no fragment observed

- UN-MTC part 1 type 3(a): No positif test between 30 to 50.1 J.

- UN-MTC part 1 type 3(b): No positif tests between 30 to 353 N.

Considering the negative results, the test item should be considered as not explosive.