Registration Dossier
Registration Dossier
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EC number: 459-300-9 | CAS number: -
Guidance on Safe Use
Administrative data
First-aid measures
Emergency measure - Inhalation: Using appropriate personal protective equipment, move
exposed subject to fresh air. If breathing is difficult or
ceases, ensure and maintain ventilation. Give oxygen as
appropriate. The exposed subject should remain warm and at
rest. Obtain medical attention in cases of known or possible
over exposure, or with symptoms including chest pain,
difficulty breathing, loss of consciousness or other adverse
effects, which may be delayed.
Emergency measure - Eyes: Wash immediately with clean and gently flowing water.
Continue for at least 15 minutes. Obtain medical attention.
Emergency measure - Skin: Using appropriate personal protective equipment, remove
contaminated clothing and flush exposed area with large
amounts of water. Obtain medical attention if skin reaction
occurs. The skin reaction may be immediate or delayed.
Emergency measure - Ingestion: Obtain medical attention.
Fire-fighting measures
Recommended extinguishing agent: Water, dry powder or foam extinguishers are recommended.
Carbon dioxide extinguishers may be ineffective.
Product arising from burning: The substance is combustible and will burn if involved in
a fire, evolving noxious fumes (eg carbon oxides and
chlorine containing compounds).
Product determined by test: N
Protective equipment: Full protective clothing and self-contained breathing
apparatus must be worn.
Fight the fire from a safe distance or protected location.
Accidental release measures
Emergency measures in case of spillage: Evacuate personnel from immediate vicinity.
Wear appropriate personal protective equipment conforming to
the relevant national or international standards, as
mentioned in section 2.3.10.
Avoid dust formation by bonding and grounding. Absorb
spillages of solutions with a suitable inert material (eg.
sand or soil). Carefully transfer the spillage to waste
containers, or use a sealed industrial vacuum machine.
Containers filled with waste material must be labelled in
the same way as the original substance containers.
Clean the spillage area with water, detergent solutions or
other soluble solvents.
Dispose of waste material in accordance with local
regulations by incineration.
Handling and storage
Handling: The substance should be stored, handled and used under
conditions of good industrial hygiene and in conformity with
any local regulations in order to avoid exposure.
Engineering controls are necessary to reduce exposure to the
substance.
When exposure cannot be prevented or adequately controlled
appropriate personal protective equipment should be worn.
Such protective equipment should conform to the appropriate
international or national standards as follows;
Chemical protective gloves to Standard EN374
Chemical protective clothing to Standard EN368
Eye protection to Standard EN166.
Furthermore, when respiratory protective equipment has to be
used, it must be capable of adequately controlling
exposure, be suitable for the purpose, and conform to the
appropriate international or national standards, such as a
dust mask conforming to EN149 FFP1.
These measures should be regarded as a minimum.
Storage: Keep in tightly closed containers or packages away from
moisture and away from sources of ignition.
Avoid prolonged storage at elevated temperatures (greater
than room temperature, which is approximately 20°C).
Packaging of the substance and or preparation: The isolated 'water damp' substance from each of the stages
of the process will be packaged in fibreboard kegs with two
internal clear anti-static plastic liners. There will be 50
kg of material per keg.
Transport information
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Marine transport (UN RTDG/IMDG)
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Air transport (UN RTDG/ICAO/IATA)
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Special provisions / remarks
- Remarks:
- Transport code: None.
Transport: Avoid crushing the containers. In the event of a spillage,
observe the warning labels on the container.
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Exposure controls / personal protection
Stability and reactivity
Danger other than fire: None known.
Chemical reaction with water: None which is hazardous.
Dust explosion: Dust Electrostatic Properties:
Minimum Ignition Energy (Cloud): 22 to 25 mJ.
Resistivity at Ambient Humidity: 3.80 E+06 ohm.m. at
Humidity 44% at 27 Deg C.
Resistivity at Low Humidity: 4.00 E+15 ohm.m. at Humidity 3%
at 24 Deg C.
Charge Relaxation Time at Ambient Humidity: 112156 s at
Humidity 44% at 27 Deg C.
Charge Relaxation Time at Low Humidity: 284181 s at Humidity
3% at 24 Deg C.
Dust Explosion Properties:
Group: A.
Pmax: 7.7 bar.
dP/dT: 484 bar/s.
Kst: 131 bar.m/s.
St Class: 1.
Limiting Oxygen Concentration: 10% v/v.
Minimum Ignition Temperature-Cloud: 590 Deg C.
Minimum Ignition Temperature-Layer: No ignition or exotherm
observed up to 400 Deg C.
Dust explosion determined by test: Y
Disposal considerations
Industry - Possibility of recovery/recycling: Recovery from minor spillages or accidental discharge is not
economically or technically feasible, and such waste
material will be disposed of by incineration. In principle,
it may be possible to recover larger spillages of
uncontaminated material for subsequent use.
Industry - Possibility of neutralisation: The dust hazard will be minimised by bonding and grounding.
The notification tests have shown that the substance is
potentially bioaccumalative as it is not readily
biodegradable and the log Pow is > 6.20.
No chemical treatment is practicable to neutralise the
hazardous environmental properties.
Industry - Possibility of destruction: controlled discharge: Not recommended.
Industry - Possibility of destruction - incineration: The substance can be disposed of by incineration by burning
under controlled conditions at a licensed waste treatment
processor in accordance with local regulations. Stack gases
must be scrubbed, because noxious fumes (eg. carbon oxides
and chlorine containing compounds) could be formed.
Industry - Possibility of destruction - water purification: The substance should not normally be discharged directly
to the sewage system or the aqueous environment. However,
adverse effects on sewage treatment systems would be
unlikely.
Industry - Possibility of destruction - other: None.
Public at large - Possibility of recovery/recycling: Not applicable.
Public at large - Possibility of neutralisation: Not applicable.
Public at large - Possibility of destruction: controlled discharge: Not applicable.
Public at large - Possibility of destruction - incineration: Not applicable.
Public at large - Possibility of destruction - water purification: Not applicable.
Public at large - Possibility of destruction - others: None.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
