1-Cyclohexene-1-carboxylic acid, 4-(acetylamino)-5-azido-3-(1-ethylpropoxy)-, ethyl ester, (3R,4R,5S)-

Guidance on Safe Use

First-aid measures

General advice:
- Do not leave the victim unattended.

 

If inhaled:
- Move to fresh air.
- If unconscious, place in recovery position and seek medical advice.
- If symptoms persist, call a physician.

 

In case of skin contact:
- If on skin, rinse well with water.

 

In case of eye contact:
- Flush eyes with water as a precaution.
- Remove contact lenses.
- Protect unharmed eye.
- Keep eye wide open while rinsing.
- If eye irritation persists, consult a specialist.

 

If swallowed:
- Keep respiratory tract clear.
- Do not give milk or alcoholic beverages.
- Never give anything by mouth to an unconscious person.
- If symptoms persist, call a physician.
- Rinse mouth with water.

 

Most important symptoms and effects, both acute and delayed
- None known.

 

Indication of any immediate medical attention and special treatment needed
- Treatment: The first aid procedure should be established in consultation with the doctor responsible for industrial medicine.

Fire-fighting measures

Suitable extinguishing media:
- Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

 

Unsuitable extinguishing media:
- High volume water jet

 

Special hazards arising from the substance or mixture
- Specific hazards during firefighting: No information available.
- Hazardous combustion products: In case of fire hazardous decomposition products may be produced such as: Carbon monoxide, Nitrogen oxides (NOx)

 

Advice for firefighters
- Special protective equipment for firefighters: Wear self-contained breathing apparatus for firefighting if necessary.
- Further information: Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding  environment.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:
- Avoid dust formation.

 

Environmental precautions:
- Prevent further leakage or spillage if safe to do so.
- Local authorities should be advised if significant spillages cannot be contained.

 

Methods and material for containment and cleaning up:
- Keep in suitable, closed containers for disposal.

Handling and storage

Precautions for safe handling
Advice on safe handling:
- Smoking, eating and drinking should be prohibited in the application area.
- Dispose of rinse water in accordance with local and national regulations.

 

Advice on protection against fire and explosion:
- Provide appropriate exhaust ventilation at places where dust is formed.

 

Hygiene measures:
- Wash hands before breaks and at the end of workday.

 

Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers:
- Keep container tightly closed in a dry and well-ventilated place. Electrical installations / working materials must comply with the technological safety standards.

 

Further information on storage conditions:
- See label, package insert or internal guidelines

 

Storage class (TRGS 510):
- 13, Non Combustible Solids

 

Storage temperature:
- Protected from heat and light
- Protect from moisture.

 

Further information on storage stability:
- Keep in a dry place.
- No decomposition if stored and applied as directed.

 

Packaging material:
- Suitable material: Stainless steel, Polyethylene bag in metal drum, glass

Transport information

Shipping

SpecialProvisions

Shipping

Remarks

Marine transport (UN RTDG/IMDG)

Shipping

Remarks

Air transport (UN RTDG/ICAO/IATA)

Shipping

Special provisions / remarks

Remarks:

Not dangerous goods in the meaning of ADR/RID, ADN, IMDG-Code, ICAO/IATA-DGR

SpecialProvisions

Exposure controls / personal protection

Personal protective equipment
Eye protection:
- Eye wash bottle with pure water
- Tightly fitting safety goggles
- Use eye protection according to EN 166.

 

Hand protection
- In case of contact through splashing:
Material : Nitrile rubber
Break through time : > 30 min
Glove thickness : > 0,11 mm

- In case of full contact:
Material : butyl-rubber
Break through time : > 480 min
Glove thickness : > 0,4 mm

- Remarks: The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it. This recommendation is only valid for the product mentioned in the safety data sheet and provided by us and for the application specified by us. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. The suitability for a specific workplace should be discussed with the producers of the protective gloves.

 

Skin and body protection:
- Dust impervious protective suit
- Choose body protection according to the amount and concentration of the dangerous substance at the work place.

Stability and reactivity

Reactivity
- No dangerous reaction known under conditions of normal use.

 

Chemical stability
- Decomposes on heating.
- No decomposition if stored normally.
- Stable under normal conditions.

 

Possibility of hazardous reactions
- Hazardous reactions: Exothermic reaction with acids. No decomposition if stored and applied as directed. Dust may form explosive mixture in air.

 

Conditions to avoid
- Do not expose to temperatures above: 160 °C

 

Incompatible materials
- Materials to avoid: Strong oxidizing agents, Acids, Heavy metals, Heavy metal salts

 

Hazardous decomposition products
- In case of fire hazardous decomposition products may be produced such as: Carbon oxides

Disposal considerations

Waste treatment methods
Product:
- Do not contaminate ponds, waterways or ditches with chemical or used container.
- Send to a licensed waste management company.

 

Contaminated packaging:
- Empty remaining contents.
- Dispose of as unused product.
- Empty containers should be taken to an approved waste handling site for recycling or disposal.
- Do not re-use empty containers.