Dihydrogen hexahydroxyplatinate, compound with 2-aminoethanol (1:2)

Guidance on Safe Use

First-aid measures

Description of first aid measures

First aid personnel should pay attention to their own safety. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). Immediately remove contaminated clothing.

If inhaled: Keep patient calm, remove to fresh air, seek medical attention. Immediately administer a corticosteroid from a controlled/metered dose inhaler.

On skin contact: Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.

On contact with eyes: Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

On ingestion: Do not induce vomiting. Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.

Most important symptoms and effects, both acute and delayed

Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11.

Indication of any immediate medical attention and special treatment needed

Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

Fire-fighting measures

Extinguishing media

Additional information: Use extinguishing measures to suit surroundings.

Special hazards arising from the substance or mixture

metal oxides, nitrous gases, amine derivatives

The substances/groups of substances mentioned can be released if the product is involved in a fire.

Advice for fire-fighters

Special protective equipment: Wear self-contained breathing apparatus and chemical-protective clothing.

Further information: Product itself is non-combustible; fire extinguishing method of surrounding areas must be considered. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

Do not breathe vapour/spray. Avoid contact with the skin, eyes and clothing. Use personal protective clothing. Information regarding personal protective measures see, section 8.

Environmental precautions

Do not discharge into drains/surface waters/groundwater. Contain contaminated water/firefighting water.

Methods and material for containment and cleaning up

Avoid aerosol formation. Dike spillage. Correctly dispose of recovered product immediately. Do not discharge into drains/surface waters/groundwater. Reclaim for processing if possible.

Reference to other sections

Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.

Handling and storage

Precautions for safe handling

Avoid inhalation of mists/vapours. Avoid contact with the skin, eyes and clothing. Processing machines must be fitted with local exhaust ventilation.

Protection against fire and explosion:

The product does not contribute to the spreading of flames, nor is it self combustible, not explosive.

Conditions for safe storage, including any incompatibilities

Suitable materials for containers: High density polyethylene (HDPE)

Further information on storage conditions: Containers should be stored tightly sealed in a dry place.

Protect from temperatures below: 5 °C

The product can crystallize below the limit temperature.

Protect from temperatures above: 90 °C

With longer exceeding of the indicated temperature packagings may be damaged.

Specific end use(s)

For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

UN3266

Shipping information

Proper shipping name and description:

CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (contains DIHYDROGEN HEXAHYDROXYPLATINATE / 2-AMINOETHANOL COMPLEX(1:2)) SOLUTION

Chemical name:

Dihydrogen hexahydroxyplatinate, compound with 2-aminoethanol

Special provisions / remarks

Remarks:

Environmental hazards: yes
Special precautions for user: Tunnel code E

Inland waterway transport (UN RTDG/ADN(R))

UN number:

UN3266

Shipping information

Proper shipping name and description:

CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (contains DIHYDROGEN HEXAHYDROXYPLATINATE / 2-AMINOETHANOL COMPLEX(1:2)) SOLUTION

Chemical name:

Dihydrogen hexahydroxyplatinate, compound with 2-aminoethanol

Special provisions / remarks

Remarks:

Environmental hazards: yes
Special precautions for user: None known
Transport in inland waterway vessel: Not evaluated

Marine transport (UN RTDG/IMDG)

UN number:

UN 3266

Shipping information

Proper shipping name and description:

CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (contains DIHYDROGEN HEXAHYDROXYPLATINATE / 2-AMINOETHANOL COMPLEX(1:2)) SOLUTION

Chemical name:

Dihydrogen hexahydroxyplatinate, compound with 2-aminoethanol

Marine pollutant

Special provisions / remarks

Remarks:

Environmental hazards: yes
Special precautions for user: None known

Air transport (UN RTDG/ICAO/IATA)

UN number:

UN 3266

Shipping information

Proper shipping name and description:

CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (contains DIHYDROGEN HEXAHYDROXYPLATINATE / 2-AMINOETHANOL COMPLEX(1:2)) SOLUTION

Chemical name:

Dihydrogen hexahydroxyplatinate, compound with 2-aminoethanol

Special provisions / remarks

Remarks:

Environmental hazards: No Mark as dangerous for the environment is needed
Special precautions for user: None known

Additional transport information

Additional information

Special provisions / remarks / other:

Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Regulation: Not evaluated
Shipment approved: Not evaluated
Pollution name: Not evaluated
Pollution category: Not evaluated
Ship Type: Not evaluated

Exposure controls / personal protection

Control parameters

Components with occupational exposure limits:

141-43-5: 2-aminoethanol; ethanolamine

      TWA value 2.5 mg/m3; 1 ppm (OEL (EU))

      indicative

      STEL value 7.6 mg/m3; 3 ppm (OEL (EU))

      indicative

      Skin Designation  (OEL (EU))

      The substance can be absorbed through the skin.

68133-90-4: Dihydrogen hexahydroxyplatinate, compound with 2-aminoethanol (1:2)

Exposure controls

Personal protective equipment

Respiratory protection:

Respiratory protection in case of vapour/aerosol release. Combination filter for gases/vapours of organic, inorganic, acid inorganic, alkaline compounds and toxic particles (e. g. EN 14387 Type ABEK-P3)

Hand protection:

Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and other

Eye protection:

Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.

Body protection:

Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

General safety and hygiene measures

Store work clothing separately. Hands and/or face should be washed before breaks and at the end of the shift.

Stability and reactivity

Reactivity

No hazardous reactions if stored and handled as prescribed/indicated.

Corrosion to metals: Corrosive effect on metals.

Chemical stability

The product is chemically stable.

Possibility of hazardous reactions

Evolution of heat under influence of acids.

The product is chemically stable.

Conditions to avoid

Temperature: > 90 °C

Avoid drying-out. Avoid freezing. Avoid heat.

Incompatible materials

Substances to avoid: acids, strong oxidizing agents, strong reducing agents

Hazardous decomposition products

Possible thermal decomposition products: nitrous gases, metallic oxides, amines

Disposal considerations

Waste treatment methods

Dispose of in accordance with national, state and local regulations.

Used catalysts may have different hazardous properties than the original products.

Contact specialized companies about recycling.

Contaminated packaging:

Dispose of in accordance with national, state and local regulations.

Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product.