Registration Dossier
Registration Dossier
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EC number: 262-679-1 | CAS number: 61260-55-7
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
Pay attention to self-protection.
Remove victims from hazardous area. Immediately remove soiled or soaked clothing and remove it to a safe distance. Keep victim warm, in a stabilized position and covered.
Do not leave victims unattended.
If the casualty is unconscious: Place the victim in the recovery position.
Inhalation
Potential for exposure by inhalation if dusts or smoke are generated.
Move victims into fresh air.
With labored breathing: Provide with oxygen. Consult a doctor.
If the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician immediately.
Skin contact
Wash off affected area immediately with plenty of water.
Continue decontamination with polyethylene glycol 400 after initial rinsing with water and then wash with water and soap.
If symptoms persist, consult a physician for treatment.
Eye contact
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
Consult an ophthalmologist immediately if the symptoms persist.
When dealing with caustic substances, notify emergency physician immediately (key words: burns in eye).
Ingestion
Rinse out mouth.
Immediately give large quantities of water to drink.
Consult a physician immediately.
When dealing with caustic substances, notify emergency physician immediately.
Indication of any immediate medical attention and special treatment needed
The initial focus is only on the local action, possibly characterized by a progressive tissue irritation; caustic substances result in quickly progressing deep tissue damage.
In the eye, caustic dusts or smoke cause, depending on the intensity of exposure, severe irritation, destruction, and ablation of the epithelium of the conjunctiva and cornea, corneal clouding, edema and ulcerations.
Danger! Possible loss of eyesight!
Superficial irritations and damage up to ulcerations and scarring develop on the skin.
After accidental absorption in the body, the pathology and clinical findings are dependent on the kinetics of the substance (quantity of absorbed substance, the absorption time, and the effectiveness of early elimination measures (first aid)/ excretion - metabolism).
A specific action of the substance is unknown.
Fire-fighting measures
Suitable extinguishing media
water spray, foam, dry powder
Unsuitable extinguishing media
high volume water jet
Special hazards arising from the substance or mixture
In case of fire cool endangered containers with water.
Hazardous fumes in fires, specific to the product:
nitrogen oxides (NOx)
Special protective equipment for fire-fighters
In case of fire: wear a self contained respiratory apparatus
Wear suitable protective clothing.
Advice for firefighters
Water used to extinguish fire should not enter drainage systems, soil, or stretches of water Ensure there are sufficient retaining facilities for water used to extinguish fire. Contaminated fire-extinguishing water must be disposed of in accordance with the regulations issued by the appropriate local authorities.
Fire residues should be disposed of in accordance with the regulations.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear personal protective equipment
Avoid dust formation.
Environmental precautions
Prevent product from entering drains.
Do not allow entrance in sewage water, soil or stretches of water.
Methods and material for containment and cleaning up
Use mechanical handling equipment.
Fill into marked, sealable containers.
Handling and storage
Handling
Precautions for safe handling
Avoid contact with skin and eyes.
If possible, use material transfer/filling, metering and blending plants that are closed.
Wear personal protective equipment
Advice on protection against fire and explosion
Take precautionary measures against static discharges.
Storage
Conditions for safe storage, including any incompatibilities
Keep container tightly closed.
Protect from moisture.
German storage class
8A - combustible corrosive substances
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 3259
Shipping information
- Proper shipping name and description:
- AMINES, SOLID, CORROSIVE, N.O.S. (Hexamethylene-bis-triacetondiamine)
- Chemical name:
- N,N'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine
- Language:
- English
- Labels:
- 8
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 3259
Shipping information
- Proper shipping name and description:
- AMINES, SOLID, CORROSIVE, N.O.S. (Hexamethylene-bis-triacetondiamine)
- Chemical name:
- N,N'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine
- Language:
- English
- Labels:
- 8
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 3259
Shipping information
- Proper shipping name and description:
- AMINES, SOLID, CORROSIVE, N.O.S. (Hexamethylene-bis-triacetondiamine)
- Chemical name:
- N,N'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine
- Labels:
- 8
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 3259
Shipping information
- Proper shipping name and description:
- AMINES, SOLID, CORROSIVE, N.O.S. (Hexamethylene-bis-triacetondiamine)
- Chemical name:
- N,N'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine
- Labels:
- 8
Remarksopen allclose all
Additional transport information
Additional information
- Special provisions / remarks / other:
- IATA_C: ERG-Code 8L
IATA_P: ERG-Code 8L
IMDG: Keep separate from acids.
Combination traffic :
Labelling of containers / shipping units following main product run as per sea or air transport regulations.
Exposure controls / personal protection
Control parameters
CAS-No. 61260-55-7 EC-No. 262-679-1
Control parameters 10 mg/m3 MAK(TRGS 900)
type of exposition Inhalable fraction.
Remarks General dust limiting value(s):
Control parameters 3 mg/m3 MAK(TRGS 900)
type of exposition as alveolar accessible part
Remarks General dust limiting value(s):
Other information
Suitable measuring processes are:
E: inhalable fraction
BIA method 7284
A: respirable dust fraction
BIA method 6068
Engineering measures
If possible, use material transfer/filling, metering and blending plants that are closed.
Personal protective equipment
Respiratory protection
If dust occurs: Nose and mouth mask with P2 particle filter
Note time limit for wearing respiratory protective equipment.
Hand protection
Brief contact only:
suitable protective gloves
Recommendation:
Glove material nitrile rubber
Material thickness 0,4 mm
Break through time > 480 min
Method DIN EN 374
Eye protection
close-fitting protective goggles (e.g. closed goggles)
Skin and body protection
suitable protective clothing - Use disposable clothing if appropriate.
Hygiene measures
Avoid contact with skin and eyes.
Do not breathe dust.
No eating, drinking, smoking, or snuffing tobacco at work. Wash face and/or hands before break and end of work.
Take off clothing and shoes contaminated with product. Clean before reuse.
Protective measures
The personal protective equipment used must meet the requirements of directive 89/686/EEC and amendments (CE certification).
Stability and reactivity
Possibility of hazardous reactions
Reacts violently with acids.
Disposal considerations
Product
With respect to local regulations, e.g. dispose of to suitable waste incineration plant.
No waste key number as per the European Waste Types List can be assigned to this product, since such classification is based on the (as yet undetermined) use to which the product is put by the consumer.
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
Uncleaned packaging
Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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