Registration Dossier
Registration Dossier
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EC number: 244-218-6 | CAS number: 21115-77-5
Guidance on Safe Use
Guidance on Safe Use
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Administrative data
First-aid measures
In case of inhalation:
Move affected person into fresh air, keep warm and allow to rest.
In case of skin (or hair) contact:
Wash immediately with water and soap. Remove contaminated, saturated clothing immediately. In case of skin irritation, consult a physician.
In case of eye contact:
Flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist if problems persist.
In case of ingestion:
Rinse mouth immediately and drink plenty of water and seek medical advice. Induce vomiting when the affected person is not unconscious.
If there is a risk of loss of consciousness, place and transport affected person in the recovery position. No administration in cases of unconsciousness or cramps.
Move affected person into fresh air, keep warm and allow to rest.
In case of skin (or hair) contact:
Wash immediately with water and soap. Remove contaminated, saturated clothing immediately. In case of skin irritation, consult a physician.
In case of eye contact:
Flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist if problems persist.
In case of ingestion:
Rinse mouth immediately and drink plenty of water and seek medical advice. Induce vomiting when the affected person is not unconscious.
If there is a risk of loss of consciousness, place and transport affected person in the recovery position. No administration in cases of unconsciousness or cramps.
Fire-fighting measures
Suitable extinguishing media:
Dry extinguishing powder; carbon dioxide (CO2); water spray jet; alcohol resistant foam.
Unsuitable extinguishing media:
Full water jet.
Special hazards arising from the substance:
In case of fire may be liberated: carbon monoxide (CO), toxic pyrolysis products.
Advice for fire-fighters:
Wear a self-contained breathing apparatus and chemical protective clothing.
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Keep containers cool by spaying with water if exposed to fire.
Dry extinguishing powder; carbon dioxide (CO2); water spray jet; alcohol resistant foam.
Unsuitable extinguishing media:
Full water jet.
Special hazards arising from the substance:
In case of fire may be liberated: carbon monoxide (CO), toxic pyrolysis products.
Advice for fire-fighters:
Wear a self-contained breathing apparatus and chemical protective clothing.
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Keep containers cool by spaying with water if exposed to fire.
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
for non-emergency personnel:
Provide adequate ventilation.
Avoid contact with skin, eyes and clothing.
Wear protective gloves/protective clothing/eye protection/face protection.
Remove all sources of ignition, avoid heat and sparks.
for emergency responders:
In case of large amounts wear a self-contained breathing apparatus and chemical protective clothing. No further precautions.
Environmental precautions:
Do not allow to enter drains/surface water/ground-water.
Do not allow to enter into soil/subsoil.
In case of entry into waterways, soil or drains, inform the responsible authorities.
Treat the recovered material as prescribed in the section on waste disposal.
Methods and material for containment and cleaning up:
For large amount: dike spillage. Pump off product.
For residues: Pick up with suitable absorbent material
Suitable material for taking up: universal binder.
for non-emergency personnel:
Provide adequate ventilation.
Avoid contact with skin, eyes and clothing.
Wear protective gloves/protective clothing/eye protection/face protection.
Remove all sources of ignition, avoid heat and sparks.
for emergency responders:
In case of large amounts wear a self-contained breathing apparatus and chemical protective clothing. No further precautions.
Environmental precautions:
Do not allow to enter drains/surface water/ground-water.
Do not allow to enter into soil/subsoil.
In case of entry into waterways, soil or drains, inform the responsible authorities.
Treat the recovered material as prescribed in the section on waste disposal.
Methods and material for containment and cleaning up:
For large amount: dike spillage. Pump off product.
For residues: Pick up with suitable absorbent material
Suitable material for taking up: universal binder.
Handling and storage
Precautions for safe handling:
Use only in well-ventilated areas.
It is recommended to design all work processes always so that the following is excluded:
Inhalation, skin contact, eye contact.
Only use the material in places where open light, fire and other flammable sources can be kept away.
Conditions for safe storage, including any incompatibilities
Store in the original container under protective gas (nitrogen).
Keep container tightly closed. Keep in a cool, dry, well-ventilated place.
Floor should be solvent-resistant, closed, sealed and not adsorbent.
Use only in well-ventilated areas.
It is recommended to design all work processes always so that the following is excluded:
Inhalation, skin contact, eye contact.
Only use the material in places where open light, fire and other flammable sources can be kept away.
Conditions for safe storage, including any incompatibilities
Store in the original container under protective gas (nitrogen).
Keep container tightly closed. Keep in a cool, dry, well-ventilated place.
Floor should be solvent-resistant, closed, sealed and not adsorbent.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 3082
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Trimethylcyclododecatriene)
- Chemical name:
- 1,5,10-Trimethyl-1,5,9-cyclododecatriene
- Language:
- English
- Labels:
- 9
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 3082
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Trimethylcyclododecatriene)
- Chemical name:
- 1,5,10-Trimethyl-1,5,9-cyclododecatriene
- Language:
- English
- Labels:
- 9
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 3082
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Trimethylcyclododecatriene)
- Chemical name:
- 1,5,10-Trimethyl-1,5,9-cyclododecatriene
- Labels:
- 9
- Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 3082
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Trimethylcyclododecatriene)
- Chemical name:
- 1,5,10-Trimethyl-1,5,9-cyclododecatriene
- Labels:
- 9
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Personal protective equipment:
Eye / face protection:
Suitable eye protection: Eye glasses with side protection (according to EN 166).
Skin protection:
Hand protection:
- By long-term hand contact:
Suitable gloves type (recommended protective index 6, corresponding >480 min of permeation time according to EN 374):
Butyl caoutchouc (butyl rubber), 0.7 mm coating thickness
- By short-term hand contact
Suitable gloves type (recommended at least protective index 2, corresponding >30 min of permeation time according to EN 374):
CR (polychloroprene, chloroprene rubber) 0.5 mm coating thickness.
Supplementary note:
The specifications are based on literature and information of glove manufacturer or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the determined permeation time.
For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.
- Other: Suitable protective clothing:
For the protection against direct skin contact, body protective clothing is essential (in addition to the usual working clothes).
Wash contaminated clothing prior to re-use.
Respiratory protection:
Respiratory protection necessary if insufficient ventilation.
Self-contained respirator (DIN EN 133) or container device with compressed air (DIN EN 137).
Filtering device (full mask or mouthpiece) with filter A (EN 14387).
Environmental exposure controls:
Do not allow to enter drains/surface water/ground-water.
Do not allow to enter into soil/subsoil.
Eye / face protection:
Suitable eye protection: Eye glasses with side protection (according to EN 166).
Skin protection:
Hand protection:
- By long-term hand contact:
Suitable gloves type (recommended protective index 6, corresponding >480 min of permeation time according to EN 374):
Butyl caoutchouc (butyl rubber), 0.7 mm coating thickness
- By short-term hand contact
Suitable gloves type (recommended at least protective index 2, corresponding >30 min of permeation time according to EN 374):
CR (polychloroprene, chloroprene rubber) 0.5 mm coating thickness.
Supplementary note:
The specifications are based on literature and information of glove manufacturer or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the determined permeation time.
For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.
- Other: Suitable protective clothing:
For the protection against direct skin contact, body protective clothing is essential (in addition to the usual working clothes).
Wash contaminated clothing prior to re-use.
Respiratory protection:
Respiratory protection necessary if insufficient ventilation.
Self-contained respirator (DIN EN 133) or container device with compressed air (DIN EN 137).
Filtering device (full mask or mouthpiece) with filter A (EN 14387).
Environmental exposure controls:
Do not allow to enter drains/surface water/ground-water.
Do not allow to enter into soil/subsoil.
Stability and reactivity
Reactivity
Stable at room temperature in closed containers under normal storage and handling conditions.
Chemical stability
In contact with air/oxygen formation of peroxide possible.
Possibility of hazardous reactions
In contact with air/oxygen formation of peroxide possible.
Stable under normal conditions.
Conditions to avoid
Excess heat, strong oxidants.
Incompatible materials
Strong oxidants, air/oxygen.
Hazardous decomposition products
Carbon monoxide, carbon dioxide, organic decomposition products.
Stable at room temperature in closed containers under normal storage and handling conditions.
Chemical stability
In contact with air/oxygen formation of peroxide possible.
Possibility of hazardous reactions
In contact with air/oxygen formation of peroxide possible.
Stable under normal conditions.
Conditions to avoid
Excess heat, strong oxidants.
Incompatible materials
Strong oxidants, air/oxygen.
Hazardous decomposition products
Carbon monoxide, carbon dioxide, organic decomposition products.
Disposal considerations
Waste treatment methods
Dispose of waste according to applicable local, state, and federal regulations.
Waste code:
07 06 00
Waste name:
Wastes from the manufacture, formulation, supply and use (MFSU) of acids of fats, grease, soaps, detergents, disinfectants and cosmetics.
Appropriate disposal / packaging:
Contaminated packing must be completely emptied and can be re-used following proper cleaning.
Dispose of waste according to applicable local, state, and federal regulations.
Waste code:
07 06 00
Waste name:
Wastes from the manufacture, formulation, supply and use (MFSU) of acids of fats, grease, soaps, detergents, disinfectants and cosmetics.
Appropriate disposal / packaging:
Contaminated packing must be completely emptied and can be re-used following proper cleaning.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
